4.7 Article

Red-light-driven photocatalytic hydrogen evolution using a ruthenium quaterpyridine complex

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 45, Pages 9261-9264

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc02124c

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Funding

  1. CNRS
  2. UPMC (University Pierre et Marie Curie)
  3. French Ministry of Research, ANR [Switch-2010-Blan-712]
  4. French Ministry of Research, ANR E-storic [14-CE05-0002]
  5. Fonds de Recherche du Quebec - Nature et Technologies (FRQNT)
  6. Natural Sciences and Engineering Research Council (NSERC) of Canada
  7. FRQNT
  8. NSERC
  9. chemistry department of University of Montreal
  10. MITACS Globalink Research Award - Sorbonne Universite

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A high-temperature, microwave synthesis of [Ru(qpy)(3)](2+) (qpy = 4,4':2',2 '':4 '',4 '''-quaterpyridine) affords the photosensitiser in quantitative yield. The complex produces H-2 photocatalytically in a range extending from the UV region of the spectrum to the red with greater efficiency when compared to [Ru(bpy)(3)](2+).

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