4.7 Article

Atmospheric mercury speciation and concentration at the urban and industrial sites in Taiwan over a three-year period

Journal

ATMOSPHERIC ENVIRONMENT
Volume 313, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.atmosenv.2023.120070

Keywords

Gaseous mercury; Particulate mercury; Iron-steel plant; Cement works; Long-range transport

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This study found significantly higher concentrations of total mercury in the dry season compared to the wet season in urban and industrial areas in Taiwan. Total gaseous mercury was the main component in the air, accounting for over 90% of the total mercury. Extreme mercury concentrations were observed near cement works and iron-steel plants, indicating their strong contribution to ambient air mercury concentrations.
Mercury (Hg) is a toxic metal known to be detrimental to human health and wildlife survival due to its serious toxicity to the central nervous system. In this study, measurements of atmospheric mercury in Taiwan over three years suggested significantly higher total Hg concentrations (p < 0.001) during the dry season compared with the wet season for both urban and industrial sites, indicating that precipitation played a role through scavenging Hg. Total gaseous mercury (TGM) was the main component in air accounting for >90% of the total Hg, which included particulate mercury (Hg-p). Furthermore, extreme Hg concentrations were observed at sites near cement works (TGM: 18 ng m(-3); Hg-p: 913 pg m(-3)) and iron-steel plants (TGM: 24.3 ng m(-3); Hg-p: 871 pg m(-3)), indicating a strong role for these two stationary emission sources to Hg concentrations in ambient air. This study contributes to improved understanding of atmospheric mercury speciation and concentrations near iron-steel plants and cement works.

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