4.7 Article

Oxidative inactivation of NiFeSe hydrogenase

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 75, Pages 14223-14226

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc05930e

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We propose a resolution to the paradox that spectroscopic studies of NiFeSe hydrogenase have not revealed any major signal attributable to Ni-III states formed upon reaction with O-2, despite the fact that two inactive states are formed upon either aerobic or anaerobic oxidation.

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