4.7 Article

Modulation of sulfur partial pressure in sulfurization to significantly improve the photoelectrochemical performance over the Cu2ZnSnS4 photocathode

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 74, Pages 14057-14059

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc04812e

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Funding

  1. National Basic Research Program of China (973 Program) [2014CB239301]
  2. Natural Science Foundation of Tianjin [15JCYBJC17400]
  3. Peiyang Young Researcher Program of Tianjin University [2015XRX-0019]

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Cu2ZnSnS4 photocathodes with excellent photoelectrochemical properties were fabricated via a facile method of adjusting the sulfur partial pressure in a semi-closed system, which achieved a maximum photocurrent-density of 1.8 mA cm(-2) under irradiation of a solar simulator which is 9-fold larger than that synthesized in an open system.

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