4.7 Article

A mild carbon-boron bond formation from diaryliodonium salts

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 74, Pages 14068-14071

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc04944j

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Funding

  1. MINECO [CTQ2014-56474R, CTQ2013-43395P, SEV-2013-0319]
  2. RedINTECAT [CTQ2014-52974-REDC]
  3. ICREA Funding Source: Custom

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The directmetal-free borylation of diaryliodonium salts with diboron reagents is now demonstrated to be a feasible process toward formation of aryl boronic esters without any additive or catalysts, and it can be extended to a two-step C-C coupling of both aryl groups of the initial diaryliodonium reagent.

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