4.8 Article

Construction of Negative Electrostatic Pore Environments in a Scalable, Stable and Low-Cost Metal-organic Framework for One-Step Ethylene Purification from Ternary Mixtures

Related references

Note: Only part of the references are listed.
Article Chemistry, Multidisciplinary

Engineering Pore Environments of Sulfate-Pillared Metal-Organic Framework for Efficient C2H2/CO2 Separation with Record Selectivity

Xing Liu et al.

Summary: In this study, a novel sulfate-pillared MOF adsorbent (SOFOUR-TEPE-Zn) using the TEPE ligand with dense electronegative pore surfaces is reported for acetylene/carbon dioxide (C2H2/CO2) separation. Compared to the prototype SOFOUR-1-Zn, SOFOUR-TEPE-Zn shows a higher C2H2 uptake and reduced CO2 uptake, leading to a high C2H2/CO2 selectivity. Dynamic breakthrough experiments confirm its application feasibility and good cyclability at various flow rates. The pressure swing adsorption processes reveal a high gas recovery rate and production of high purity C2H2.

ADVANCED MATERIALS (2023)

Article Biochemical Research Methods

High-yield, green and scalable methods for producing MOF-303 for water harvesting from desert air

Zhiling Zheng et al.

Summary: This article presents a detailed protocol for the green, water-based preparation of MOF-303 on both gram and kilogram scales, showing high yield and quality. It also demonstrates that the synthetic procedure can produce MOF within a short period of time.

NATURE PROTOCOLS (2023)

Article Chemistry, Multidisciplinary

Confining Water Nanotubes in a Cu10O13-Based Metal-Organic Framework for Propylene/Propane Separation with Record-High Selectivity

Qiubing Dong et al.

Summary: Researchers reported a continuous water nanotube confined in a Cu(10)O(13)(-) based metal-organic framework (MOF) that can selectively adsorb C3H6 over C3H8 with a record-high selectivity of 1570 among all the porous materials. The high selectivity is attributed to the initial expansion and subsequent contraction of the confined water nanotubes caused by C3H6 adsorption rather than C3H8. The water nanotubes can be easily recovered by soaking the MOF in water, ensuring long-term use.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023)

Review Chemistry, Multidisciplinary

Molecular Mechanisms behind Acetylene Adsorption and Selectivity in Functional Porous Materials

Xue Han et al.

Summary: Since its first industrial production in the 1890s, acetylene has been crucial in manufacturing various materials. With the development of functional porous materials, such as metal-organic frameworks and decorated zeolites, there is a growing interest in developing new technologies to improve the safety, energy efficiency, and carbon footprint of acetylene processes. This Minireview explores the applications of these advanced porous materials in acetylene purification and storage, discusses the challenges in developing solid sorbent-based separation technologies, and identifies areas for future research efforts.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

Article Multidisciplinary Sciences

Programmed fluorine binding engineering in anion-pillared metal-organic framework for record trace acetylene capture from ethylene

Xiao-Wen Gu et al.

Summary: Researchers have designed a new porous adsorbent, ZJU-300a, with enhanced C2H2 affinity using programmed fluorine binding engineering. The adsorbent shows high C2H2 uptake and selectivity, making it suitable for C2H2/C2H4 separation.

SCIENCE ADVANCES (2023)

Review Chemistry, Multidisciplinary

Reticular Chemistry for Highly Porous Metal-Organic Frameworks: The Chemistry and Applications

Zhijie Chen et al.

Summary: This article summarizes recent progress in the synthesis and application of highly porous metal-organic frameworks (MOFs) inspired by reticular chemistry. The authors first introduce the synthesis of NU-1500 and NU-1501 using reticular chemistry and discuss their potential applications in storing clean energy gases such as hydrogen and methane. They then present the rational synthesis of highly porous and stable Zr-MOFs based on edge-transitive nets, and provide an overview of the potential applications of these MOFs, including water capture, catalysis, gas storage, etc. Overall, this Account provides valuable insights and inspiration for the development of next-generation highly porous materials for energy and environment-related applications.

ACCOUNTS OF CHEMICAL RESEARCH (2022)

Article Chemistry, Multidisciplinary

Immobilization of Lewis Basic Sites into a Stable Ethane-Selective MOF Enabling One-Step Separation of Ethylene from a Ternary Mixture

Xiao-Wen Gu et al.

Summary: This study introduces Lewis basic sites into a C2H6-selective MOF for efficient purification of C2H4 from ternary mixtures, demonstrating high C2H2 and C2H6 uptakes and selectivities. The amino-functionalized UiO-67-(NH2)(2) shows exceptional performance by providing suitable pore confinement and functional surfaces decorated with amino groups for stronger interactions with C2H2 and C2H6. Breakthrough experiments with C2H2/C2H6/C2H4 mixtures under dry and wet conditions confirm the remarkable C2H4 productivity of UiO-67-(NH2)(2).

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Article Chemistry, Multidisciplinary

Metal-Organic Framework Based Hydrogen-Bonding Nanotrap for Efficient Acetylene Storage and Separation

Yingxiang Ye et al.

Summary: This study introduces a novel strategy to promote the separation of C2H2/CO2 mixtures by regulating a hydrogen-bonding nanotrap on the pore surface of three isostructural metal-organic frameworks. Among them, MIL-160 demonstrates an ultrahigh C2H2 storage capacity and superior C2H2/CO2 selectivity due to its multiple hydrogen-bonding interaction with C2H2.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Article Chemistry, Multidisciplinary

Adsorption in Reversed Order of C2 Hydrocarbons on an Ultramicroporous Fluorinated Metal-Organic Framework

Lingzhi Yang et al.

Summary: This study reports an ultramicroporous fluorinated metal-organic framework Zn-FBA that exhibits a reversed adsorption order for C-2 hydrocarbons and shows high selectivity in separating C2H6 and C2H4.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Article Chemistry, Multidisciplinary

One-Step C2H4 Purification from Ternary C2H6/C2H4/C2H2 Mixtures by a Robust Metal-Organic Framework with Customized Pore Environment

Gang-Ding Wang et al.

Summary: This study reports a robust metal-organic framework (MOF) with methyl-decorated nonpolar pores that achieves one-step purification of C2H4 from binary and ternary C2H6/C2H4/C2H2 mixtures. The MOF exhibits high C2H6 and C2H2 uptakes and surpasses all previously reported MOFs in terms of C2H6/C2H4 selectivity for C2H4 purification. The presence of methyl groups in the pores enhances the adsorption capacity for C2H2 and C2H6 compared to C2H4.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Article Chemistry, Physical

Insights into the Ultra-High Volumetric Capacity in a Robust Metal-Organic Framework for Efficient C2H2/CO2 Separation

Yi-Ming Gu et al.

Summary: This study reports the development of a stable and low-cost adsorbent, MIL-160(Al), with a high acetylene volumetric capacity and selectivity. By combining experimental and theoretical methods, the synergistic interactions driven by the hydrogen bonding of C2H2-MOF and the electrostatic interactions between C2H molecules in the nanoscale pores were revealed.

CHEMISTRY OF MATERIALS (2022)

Article Chemistry, Multidisciplinary

Tunable acetylene sorption by flexible catenated metal-organic frameworks

Mickaele Bonneau et al.

Summary: This study successfully controlled the gas uptake and release pressures of acetylene by decorating the ligands of a metal-organic framework, achieving safe storage of acetylene. The new materials exhibited excellent acetylene storage performance under practical pressure ranges.

NATURE CHEMISTRY (2022)

Article Chemistry, Physical

Trace removal of benzene vapour using double-walled metal-dipyrazolate frameworks

Tao He et al.

Summary: Porous physisorbents are attractive candidates for the removal of volatile organic compounds. In this study, a double-walled metal-organic framework demonstrated high affinity and adsorption capacity towards benzene at low pressures. The findings provide insights into the development of recyclable physisorbents for environmental remediation.

NATURE MATERIALS (2022)

Article Chemistry, Multidisciplinary

Broadly Tunable Atmospheric Water Harvesting in Multivariate Metal-Organic Frameworks

Zhiling Zheng et al.

Summary: A new series of multivariate MOF-303-based water harvesting frameworks with greater tunability has been developed, along with a high-yielding and scalable synthesis method. The framework maintains its crystallinity, porosity, and water-harvesting performance.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Article Chemistry, Multidisciplinary

One-Step Ethylene Purification from Ternary Mixtures in a Metal-Organic Framework with Customized Pore Chemistry and Shape

Qi Ding et al.

Summary: In this study, a metal-organic framework Zn(ad)(int) was reported for the one-step purification of C2H4 from ternary mixtures. The material utilizes dense heterocyclic rings and accessible uncoordinated O atoms as binding sites, achieving high selectivity for C2H6 and C2H2 separation and excellent gas capacity. Breakthrough experiments demonstrate that polymer-grade C2H4 can be separated with a record productivity.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Article Multidisciplinary Sciences

Discrimination of xylene isomers in a stacked coordination polymer

Liangying Li et al.

Summary: This study reports a stacked one-dimensional coordination polymer that achieves the separation of xylene isomers through temperature-controlled adsorption behavior. This material exhibits high flexibility and stability, as well as high selectivity and fast kinetics, allowing for complete separation of the isomers under industrial settings.

SCIENCE (2022)

Article Multidisciplinary Sciences

Synergistic binding sites in a hybrid ultramicroporous material for one-step ethylene purification from ternary C2 hydrocarbon mixtures

Peixin Zhang et al.

Summary: In this study, we report a hybrid ultramicroporous material with the ability to selectively recognize C2H4, which enables efficient separation of C2H2/C2H4/C2H6 hydrocarbon mixtures. Dynamic breakthrough experiments confirm the direct production of high-purity C2H4 under ambient conditions.

SCIENCE ADVANCES (2022)

Article Chemistry, Multidisciplinary

Boosting Ethane/Ethylene Separation by MOFs through the Amino-Functionalization of Pores

Gang-Ding Wang et al.

Summary: The introduction of amino groups has significantly improved the adsorption selectivity of metal-organic framework materials for ethane and ethylene, achieving higher separation performance.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Article Chemistry, Multidisciplinary

A Metal-Organic Framework with Nonpolar Pore Surfaces for the One-Step Acquisition of C2H4 from a C2H4 and C2H6 Mixture

Zhengyi Di et al.

Summary: This study presents a highly stable metal-organic framework with a unique pore structure for the one-step separation of high-purity ethylene from ethylene and ethane mixtures.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Article Multidisciplinary Sciences

Negative electrostatic potentials in a Hofmann-type metal-organic framework for efficient acetylene separation

Yuan Liu et al.

Summary: In this study, an electrostatic potential compatible strategy based on a nitroprusside-based metalorganic framework was demonstrated for efficient acetylene separation. By adjusting the electrostatic potential in one-dimensional channels, the framework exhibited preferential recognition of acetylene, resulting in improved selectivity and productivity.

NATURE COMMUNICATIONS (2022)

Article Multidisciplinary Sciences

Ultramicroporous material based parallel and extended paraffin nano-trap for benchmark olefin purification

Peixin Zhang et al.

Summary: In this study, a highly selective and productive ultramicroporous material (PCP-IPA) was developed for the direct extraction of high-purity olefins from olefin/paraffin mixtures.

NATURE COMMUNICATIONS (2022)

Article Chemistry, Multidisciplinary

Guest-molecule-induced self-adaptive pore engineering facilitates purification of ethylene from ternary mixture

Yutong Wang et al.

Summary: This study reports a cobalt metal-organic framework, UPC-66, with a self-adaptive pore structure. The pore size of activated UPC-66-a can undergo synchronous dynamic transformation with temperature, pressure, and guest molecules. Experimental results show that UPC-66 can effectively separate polymer-grade ethylene from multicomponent mixtures.
Article Multidisciplinary Sciences

Aluminum formate, Al(HCOO)3: An earth-abundant, scalable, and highly selective material for CO2 capture

Hayden A. Evans et al.

Summary: Experimental and computational studies reveal that the metal-organic framework ALF exhibits excellent CO2 adsorption capacities and outstanding CO2/N2 selectivity, making it a promising material for CO2 removal from dried CO2-containing gas streams at elevated temperatures.

SCIENCE ADVANCES (2022)

Review Chemistry, Multidisciplinary

Construction and application of base-stable MOFs: a critical review

Kecheng Wang et al.

Summary: Metal-organic frameworks (MOFs) are porous crystalline materials made up of organic ligands and metal ions/clusters. Their unique advantages have attracted increasing attention in recent years, showing great potential in various applications. In alkaline operational environments, the stability of MOFs against bases is crucial for achieving high performance and long cycling life. Therefore, the development of base-stable MOFs has become a critical research direction in this field.

CHEMICAL SOCIETY REVIEWS (2022)

Review Chemistry, Multidisciplinary

Power of Infrared and Raman Spectroscopies to Characterize Metal-Organic Frameworks and Investigate Their Interaction with Guest Molecules

Konstantin Hadjiivanov et al.

Summary: Metal-organic frameworks (MOFs) with various functionalities and porous structures are suitable for a wide range of applications. Vibrational spectroscopy (IR and Raman) plays a crucial role in characterizing MOF materials and studying their interaction with gases, highlighting both advantages and limitations of the technique. By combining IR and Raman spectroscopies with other techniques, the structure, properties, and reactivity of MOFs can be explicitly established.

CHEMICAL REVIEWS (2021)

Article Chemistry, Multidisciplinary

Pore Engineering for One-Step Ethylene Purification from a Three-Component Hydrocarbon Mixture

Baoyong Zhu et al.

Summary: This study presents three new isostructural porous coordination networks that can produce high-purity ethylene through one separation step, by selectively adsorbing acetylene and ethane while having low affinity for ethylene. Hindered by the similar properties of C2 hydrocarbons, the networks achieved this through fine-tuned dual cage structures and specific interactions within the cages.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Multidisciplinary

Precise Pore Space Partitions Combined with High-Density Hydrogen-Bonding Acceptors within Metal-Organic Frameworks for Highly Efficient Acetylene Storage and Separation

Ying-Ying Xue et al.

Summary: A moderate pore size distribution around 5.0-7.5 angstrom is critical for acetylene adsorbents, while high-density H-bonding acceptors can provide a good combination of high C2H2/CO2 adsorption selectivity and high C2H2 uptake capacity.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Nanospace Engineering of Metal-Organic Frameworks through Dynamic Spacer Installation of Multifunctionalities for Efficient Separation of Ethane from Ethane/Ethylene Mixtures

Cheng-Xia Chen et al.

Summary: A dynamic spacer installation (DSI) strategy was used to construct a series of multifunctional metal-organic frameworks (MOFs) for ethane/ethylene separation, with increased ethane adsorption capacity and enhanced ethane/ethylene selectivity. The DSI approach showed promising results for the rational design of multifunctional MOFs in challenging tasks.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

One-step Ethylene Purification from an Acetylene/Ethylene/Ethane Ternary Mixture by Cyclopentadiene Cobalt-Functionalized Metal-Organic Frameworks

Yutong Wang et al.

Summary: A new modification method using stable ftw topological Zr-MOF platform has been developed to purify ethylene from a mixture of hydrocarbon gases. The introduction of functional groups in UPC-612 and UPC-613 materials has increased host-guest interactions, leading to efficient separation of C2H2/C2H4/C2H6.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Multidisciplinary Sciences

A scalable metal-organic framework as a durable physisorbent for carbon dioxide capture

Jian-Bin Lin et al.

Summary: Zinc-based CALF-20 demonstrates high efficiency and cost-effectiveness in CO2 capture, with the ability to resist water interference, low regeneration cost, and strong durability.

SCIENCE (2021)

Article Multidisciplinary Sciences

Evolution of water structures in metal-organic frameworks for improved atmospheric water harvesting

Nikita Hanikel et al.

Summary: By conducting single-crystal x-ray diffraction experiments and density functional theory calculations, we deciphered the water-filling mechanism in the state-of-the-art water-harvesting metal-organic framework MOF-303. The evolution of water structures led us to modify the pores and precisely modulate the binding strength of water molecules, resulting in higher water productivity and tunability of regeneration temperature and enthalpy without compromising capacity and stability.

SCIENCE (2021)

Article Energy & Fuels

Isotherm, Kinetic, Process Modeling, and Techno-Economic Analysis of a Diamine-Appended Metal-Organic Framework for CO2 Capture Using Fixed Bed Contactors

Ryan Hughes et al.

Summary: The study developed dual-site Sips and linear driving force models for energy-efficient carbon capture, highlighting the importance of heat removal for maximizing capture performance. Investigation into different bed cooling methods revealed that adsorbent-based TSA processes are projected to be more cost-effective than MEA systems with 85% heat recovery.

ENERGY & FUELS (2021)

Article Chemistry, Multidisciplinary

High-Throughput Discovery of Ni(IN)2 for Ethane/Ethylene Separation

Minjung Kang et al.

Summary: Ni(IN)2 has been identified as a promising adsorbent for selective C2H6 adsorption, exhibiting high selectivity and recyclability for C2H4 production. Process-level simulations show it to be one of the top-performing materials for ethane/ethylene separation in the study's conditions.

ADVANCED SCIENCE (2021)

Article Chemistry, Multidisciplinary

Dense Packing of Acetylene in a Stable and Low-Cost Metal-Organic Framework for Efficient C2H2/CO2 Separation

Jiyan Pei et al.

Summary: CAU-10-H is a stable, low-cost, and easily scaled-up aluminum MOF that demonstrates exceptional performance in C2H2/CO2 separation, achieving a balance between high storage density and separation factor.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Low-Valent Metal Ions as MOF Pillars: A New Route Toward Stable and Multifunctional MOFs

R. Eric Sikma et al.

Summary: PCM-102 is a new type of organophosphine metal-organic framework with unique pockets composed of offset trans-oriented P(III) donors, which can undergo single-crystal to single-crystal transformations upon addition of M(I) salts and show improved stability and gas uptake properties with the addition of Lewis acids. The Ag(I) analogue can also be easily obtained via a one-pot peri-synthetic route.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Multidisciplinary

Scalable Room-Temperature Synthesis of Highly Robust Ethane-Selective Metal-Organic Frameworks for Efficient Ethylene Purification

Shubo Geng et al.

Summary: The study introduced two new C2H6-selective MOF adsorbents with high stability and selectivity, which can effectively separate ethylene from ethane even in high humidity conditions. The scalable synthesis method and potential industrial applications make them promising for practical use in industrial settings.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Multidisciplinary

Efficient C2H2/CO2 Separation in Ultramicroporous Metal-Organic Frameworks with Record C2H2 Storage Density

Wei Gong et al.

Summary: This study demonstrates efficient C2H2 adsorption and C2H2/CO2 separation by introducing preselected amino and hydroxy functionalities into metal-organic frameworks, surpassing benchmark materials and showing promising industrial potential.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Multidisciplinary Sciences

Orthogonal-array dynamic molecular sieving of propylene/propane mixtures

Heng Zeng et al.

Summary: Metal-organic frameworks (MOFs) are known for their precise control of structures and functions on a molecular level, but designing local flexibility in the MOF framework for dynamic molecular sieving remains challenging. A newly reported MOF material, JNU-3a, features one-dimension channels with embedded molecular pockets that can selectively adsorb propylene and propane under different pressures, showcasing the potential of dynamic molecular sieving.

NATURE (2021)

Article Multidisciplinary Sciences

Efficient ethylene purification by a robust ethane-trapping porous organic cage

Kongzhao Su et al.

Summary: The study presents a porous organic cage based on truncated octahedral calix[4]resorcinarene that can efficiently separate high-purity ethylene from ethane/ethylene mixtures.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Multidisciplinary

Breaking the trade-off between selectivity and adsorption capacity for gas separation

Naveen Kumar et al.

Summary: A systematic crystal engineering study has successfully tuned the pore size and chemistry of hybrid ultramicroporous materials for effective C2H2/CO2 separation, with SIFSIX-21-Ni exhibiting exceptional separation selectivity and high adsorption capacity.
Article Chemistry, Multidisciplinary

Pore-Space-Partition-Enabled Exceptional Ethane Uptake and Ethane-Selective Ethane-Ethylene Separation

Huajun Yang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Multidisciplinary Sciences

Control of zeolite pore interior for chemoselective alkyne/olefin separations

Yuchao Chai et al.

SCIENCE (2020)

Article Multidisciplinary Sciences

A robust Th-azole framework for highly efficient purification of C2H4 from a C2H4/C2H2/C2H6 mixture

Zhenzhen Xu et al.

NATURE COMMUNICATIONS (2020)

Article Chemistry, Multidisciplinary

A Robust Ethane-Trapping Metal-Organic Framework with a High Capacity for Ethylene Purification

Omid T. Qazvini et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Review Chemistry, Multidisciplinary

Porous metal-organic frameworks as emerging sorbents for clean air

Xue Han et al.

NATURE REVIEWS CHEMISTRY (2019)

Article Nanoscience & Nanotechnology

Enhancement of Ethane Selectivity in Ethane-Ethylene Mixtures by Perfluoro Groups in Zr-Based Metal-Organic Frameworks

Joao Pires et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

Article Chemistry, Multidisciplinary

Designing Open Metal Sites in Metal Organic Frameworks for Paraffin/Olefin Separations

Mona H. Mohamed et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Multidisciplinary

Cage-Interconnected Metal-Organic Framework with Tailored Apertures for Efficient C2H6/C2H4 Separation under Humid Conditions

Heng Zeng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Review Chemistry, Multidisciplinary

Stable Metal-Organic Frameworks: Design, Synthesis, and Applications

Shuai Yuan et al.

ADVANCED MATERIALS (2018)

Review Chemistry, Multidisciplinary

Metal-Organic Frameworks for Separation

Xiang Zhao et al.

ADVANCED MATERIALS (2018)

Article Chemistry, Multidisciplinary

Aqueous production of spherical Zr-MOF beads via continuous-flow spray-drying

Ceren Avci-Camur et al.

GREEN CHEMISTRY (2018)

Article Multidisciplinary Sciences

Practical water production from desert air

Farhad Fathieh et al.

SCIENCE ADVANCES (2018)

Article Chemistry, Multidisciplinary

Boosting Ethane/Ethylene Separation within Isoreticular Ultramicroporous Metal-Organic Frameworks

Rui-Biao Lin et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Chemistry, Multidisciplinary

Metal Acetylacetonates as a Source of Metals for Aqueous Synthesis of Metal-Organic Frameworks

Ceren Avci-Camur et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2018)

Article Multidisciplinary Sciences

Ethane/ethylene separation in a metal-organic framework with iron-peroxo sites

Libo Li et al.

SCIENCE (2018)

Article Multidisciplinary Sciences

Control of zeolite framework flexibility and pore topology for separation of ethane and ethylene

Pablo J. Bereciartua et al.

SCIENCE (2017)

Article Multidisciplinary Sciences

Controlling guest conformation for efficient purification of butadiene

Pei-Qin Liao et al.

SCIENCE (2017)

Article Engineering, Multidisciplinary

New Trends in Olefin Production

Ismael Amghizar et al.

ENGINEERING (2017)

Editorial Material Multidisciplinary Sciences

Seven chemical separations to change the world

David S. Sholl et al.

NATURE (2016)

Article Multidisciplinary Sciences

A metal-organic framework-based splitter for separating propylene from propane

A. Cadiau et al.

SCIENCE (2016)

Article Chemistry, Physical

Characterization of adsorbed water in MIL-53(Al) by FTIR spectroscopy and ab-initio calculations

J. M. Salazar et al.

JOURNAL OF CHEMICAL PHYSICS (2015)

Article Multidisciplinary Sciences

Efficient purification of ethene by an ethane-trapping metal-organic framework

Pei-Qin Liao et al.

NATURE COMMUNICATIONS (2015)

Review Chemistry, Multidisciplinary

Structuring of metal-organic frameworks at the mesoscopic/macroscopic scale

Shuhei Furukawa et al.

CHEMICAL SOCIETY REVIEWS (2014)

Article Chemistry, Multidisciplinary

Introduction of π-Complexation into Porous Aromatic Framework for Highly Selective Adsorption of Ethylene over Ethane

Baiyan Li et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Review Multidisciplinary Sciences

The Chemistry and Applications of Metal-Organic Frameworks

Hiroyasu Furukawa et al.

SCIENCE (2013)

Article Chemistry, Multidisciplinary

High Propene/Propane Selectivity in Isostructural Metal-Organic Frameworks with High Densities of Open Metal Sites

Youn-Sang Bae et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

Article Chemistry, Multidisciplinary

CO2 capture from gas stream by zeolite 13X using a dual-column temperature/vacuum swing adsorption

Fengsheng Su et al.

ENERGY & ENVIRONMENTAL SCIENCE (2012)

Article Chemistry, Multidisciplinary

Ethane/Ethene Separation Turned on Its Head: Selective Ethane Adsorption on the Metal-Organic Framework ZIF-7 through a Gate-Opening Mechanism

Canan Gucuyener et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

Review Chemistry, Multidisciplinary

Selective gas adsorption and separation in metal-organic frameworks

Jian-Rong Li et al.

CHEMICAL SOCIETY REVIEWS (2009)

Article Chemistry, Multidisciplinary

A rationale for the large breathing of the porous aluminum terephthalate (MIL-53) upon hydration

T Loiseau et al.

CHEMISTRY-A EUROPEAN JOURNAL (2004)