☆ 4.8 Article

Reconstructing Hydrogen Bond Network Enables High Voltage Aqueous Zinc-Ion Supercapacitors

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

Related references

Note: Only part of the references are listed.

Article Chemistry, Multidisciplinary

Dilute Aqueous Hybrid Electrolyte with Regulated Core-Shell-Solvation Structure Endows Safe and Low-Cost Potassium-Ion Energy Storage Devices

Jianchao Chen et al.

Summary: High-concentration water-in-salt (WIS) electrolytes with a wider electrochemical stability window (ESW) can enable safe and high-energy aqueous potassium-ion energy storage devices for grid-scale applications. However, the dependence on highly concentrated salts raises concerns about cost and sustainability. This study demonstrates an aqueous low-concentration-based potassium-ion hybrid electrolyte with a regulated core-shell-solvation structure, providing an expanded ESW and nonflammable property.

ADVANCED FUNCTIONAL MATERIALS (2023)

Add to Collection

Article Chemistry, Multidisciplinary

An Anti-Freezing Hydrogel Electrolyte for Flexible Zinc-Ion Batteries Operating at-70 degrees C

Ying Shi et al.

Summary: An anti-freezing hydrogel electrolyte based on zinc tetrafluoroborate (Zn(BF4)(2)) and polyacrylamide (PAM) is developed, which inhibits the formation of ice crystal lattice in the hydrogel electrolyte at low temperatures and maintains good flexibility and high ionic conductivity. It can be used as the electrolyte for anti-freezing flexible zinc-ion batteries.

ADVANCED FUNCTIONAL MATERIALS (2023)

Add to Collection

Article Chemistry, Applied

Upcycling of phosphogypsum waste for efficient zinc-ion batteries

Huanwen Wang et al.

Summary: In this work, phosphogypsum (PG), an industrial byproduct, is used as a multifunctional protective layer to prevent zinc dendrite growth and achieve uniform zinc deposition. The Zn@PG anode shows high Coulombic efficiency and long-time stability, providing a low-cost solution for practical metal batteries and high-value utilization of phosphogypsum waste.

JOURNAL OF ENERGY CHEMISTRY (2023)

Add to Collection

Article Materials Science, Multidisciplinary

Progress and perspective on multi-dimensional structured carbon nanomaterials for cathodes in aqueous zinc-based energy storage

Wenjie Fan et al.

Summary: This manuscript discusses the progress and future prospects of multi-dimensional structured nanocarbons for cathodes in Zinc-based energy devices, starting from typical cathodic electrochemistry. Aqueous zinc-based devices are considered as a promising candidate for next-generation energy storage due to their high safety, economic benefits, and environmental friendliness. However, the widespread application of AZD cathodes still faces challenges such as inferior energy density and cycling life. This manuscript focuses on the key design parameters for AZD cathodes, highlighting the diverse functions of well-designed carbon architectures. It also presents emerging opportunities to guide future endeavors towards high-performance AZD cathodes.

MATERIALS RESEARCH LETTERS (2023)

Add to Collection

Article Nanoscience & Nanotechnology

Novel Nonstoichiometric Niobium Oxide Anode Material with Rich Oxygen Vacancies for Advanced Lithium-Ion Capacitors

Chang Liu et al.

Summary: In this study, ultrathin carbon-confined Nb12O29 materials with rich oxygen vacancies were designed and synthesized to address the low conductivity and instability issues of traditional Nb-based oxides. The oxygen vacancies regulated the electronic structure and improved the electronic conductivity and Li+ diffusion performance, while the carbon coating enhanced the structural stability and electronic conductivity of the Nb12O29 material. The as-prepared Nb12O29-x@C exhibited high reversible capacity, excellent high-rate performance, and durable cycling life. Furthermore, the lithium storage mechanism and structural stability of Nb12O29-x@C were investigated. When applied as the anode of lithium-ion capacitors, the Nb12O29-x@C materials demonstrated high energy density within a wide voltage window, indicating their practical application potential.

ACS APPLIED MATERIALS & INTERFACES (2023)

Add to Collection

Article Chemistry, Multidisciplinary

Nano-scaled hydrophobic confinement of aqueous electrolyte by a nonionic amphiphilic polymer for long-lasting and wide-temperature Zn-based energy storage

Ben Niu et al.

Summary: The use of a polymer additive with hydrophilic and hydrophobic units can create a localized hydrophilic environment and hydrophobic layer, suppressing water-related side reactions and direct corrosion of the metal, thereby improving the electrochemical stability of aqueous Zn-ion devices.

ENERGY & ENVIRONMENTAL SCIENCE (2023)

Add to Collection

Article Electrochemistry

Electrochemical Characteristics of Zn-Ion Hybrid Supercapacitors Based on Aqueous Solution of Different Electrolytes

J. Eskusson et al.

Summary: The electrochemical behavior of Zn cations in various aqueous electrolytes (ZnSO4, Zn(BF4)(2), zinc di[bis(trifluoromethylsulfonyl)imide], Zn(TFSI)(2), and zinc trifluoromethanesulfonate, Zn(OTf)(2)) has been studied and compared with Zn(ClO4)(2) electrolyte using different methods. The specific energy characteristics of the electrolytes decrease in the order of Zn(ClO4)(2) >= Zn(BF4)(2) > Zn(OTf)(2) > Zn(TFSI)(2) > ZnSO4 at moderate specific power values (10 kW kg(-1)). The stability of the Zn-ion hybrid supercapacitor cells under study is very good for Zn(OTf)(2), Zn(ClO4)(2), and ZnSO4, as tested by long-term constant current charge/discharge method (up to 10000 cycles).

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2022)

Add to Collection

Article Green & Sustainable Science & Technology

Flexible Quasi-Solid-State High-Performance Aqueous Zinc Ion Hybrid Supercapacitor with Water-in-Salt Hydrogel Electrolyte and N/P-Dual Doped Graphene Hydrogel Electrodes

Yongqi Deng et al.

Summary: A new hybrid water-in-salt hydrogel electrolyte has been developed to expand the voltage window of ZHSCs, achieving high energy density and excellent cycling stability. Additionally, a flexible quasi-solid-state ZHSC using this electrolyte shows high performance and potential for wearable applications.

ADVANCED SUSTAINABLE SYSTEMS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

A Binary Hydrate-Melt Electrolyte with Acetate-Oriented Cross-Linking Solvation Shells for Stable Zinc Anodes

Min Yang et al.

Summary: This study presents a binary hydrate-melt electrolyte as a solution to improve the cycling performance of zinc-ion batteries with metal zinc anodes. By adjusting the solvation structure of zinc ions, the side reactions on the anodes can be effectively suppressed, leading to higher coulombic efficiency. Experimental results demonstrate that the use of this electrolyte can achieve better cycling performance.

ADVANCED MATERIALS (2022)

Add to Collection

Review Multidisciplinary Sciences

From room temperature to harsh temperature applications: Fundamentals and perspectives on electrolytes in zinc metal batteries

Sailin Liu et al.

Summary: This review examines the failure mechanism of rechargeable zinc metal batteries under temperature influence, presents current electrolyte strategies for improving battery performance in harsh temperatures, and offers perspectives on their industrial application.

SCIENCE ADVANCES (2022)

Add to Collection

Article Chemistry, Physical

Electrolyte/electrode interfacial electrochemical behaviors and optimization strategies in aqueous zinc-ion batteries

Miao Zhou et al.

Summary: Aqueous zinc-ion batteries (ZIBs) are a promising alternative for large-scale energy storage due to their environmental friendliness, low cost, and safety. However, the understanding of the electrolyte/electrode interfacial electrochemical behaviors, which significantly affect the performance of ZIBs, is still in the early stage. This review focuses on the characteristics and formation mechanism of the electrode/electrolyte interface (EEI) and discusses the various ionic electrochemical behaviors at EEI and interfacial optimization strategies. Practical considerations and future perspectives for manipulating EEI in aqueous ZIBs are also proposed.

ENERGY STORAGE MATERIALS (2022)

Add to Collection

Article Nanoscience & Nanotechnology

Water-Locked Eutectic Electrolyte Enables Long-Cycling Aqueous Sodium-Ion Batteries

Tingting Liu et al.

Summary: This study presents a hydrated eutectic electrolyte with a water-locked effect, which strengthens the O-H bond of water via weak hydrogen bonding, leading to improved rechargeability and stability of aqueous sodium batteries.

ACS APPLIED MATERIALS & INTERFACES (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Strongly Coupled Interfacial Engineering Inspired by Robotic Arms Enable High-Performance Sodium-Ion Capacitors

Zirui Song et al.

Summary: In this study, a strong interfacial coupling effect was achieved by grafting functional groups with high affinity to V atoms onto carbon nanotubes, resulting in enhanced conductivity and durability of the VS4-CNT heterostructure. The assembled sodium-ion capacitor exhibited excellent energy density and reversibility, thanks to the interfacial coupling effect and the synergistic soft-rigid integrated solid-electrolyte interphase film.

ADVANCED FUNCTIONAL MATERIALS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Intercalation of organics into layered structures enables superior interface compatibility and fast charge diffusion for dendrite-free Zn anodes

Huili Peng et al.

Summary: By intercalating n-butylamine into monodisperse hexagonal nanoplates of alpha-ZrP, the compatibility with hydrophobic polymers is improved, resulting in a dense and robust artificial layer on the zinc anode. This reduces direct exposure to electrolytes and suppresses side reactions, leading to improved electrochemical performance.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Synergistic Manipulation of Zn2+ Ion Flux and Desolvation Effect Enabled by Anodic Growth of a 3D ZnF2 Matrix for Long-Lifespan and Dendrite-Free Zn Metal Anodes

Yang Yang et al.

Summary: The study successfully developed a Zn@ZnF2 electrode with a multi-functional protective layer by designing a 3D interconnected ZnF2 matrix on the surface of Zn foil. This electrode exhibits stable zinc deposition kinetics and good plating/stripping reversibility, showing potential for practical application in various battery systems.

ADVANCED MATERIALS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Electrolyte Design for In Situ Construction of Highly Zn 2+ ‐Conductive Solid Electrolyte Interphase to Enable High‐Performance Aqueous Zn‐Ion Batteries under Practical Conditions

Xiaohui Zeng et al.

ADVANCED MATERIALS (2021)

Add to Collection

Article Materials Science, Multidisciplinary

Fabricating low-temperature-tolerant and durable Zn-ion capacitors via modulation of co-solvent molecular interaction and cation solvation

Fuyun Li et al.

Summary: Low-temperature-tolerant and durable Zn-ion hybrid supercapacitors (ZHSCs) were fabricated by modulating a co-solvent water/ethylene glycol electrolyte. The electrolyte with ZnSO4/water/ethylene glycol (65%) composition showed high ionic conductivity at low temperatures and effectively prevented dendrite formation in the Zn anode. These ZHSCs demonstrated long-term cyclability and operation at sub-zero temperatures as low as -40 degrees C, making them potentially valuable in next-generation electrochemical energy storage devices.

SCIENCE CHINA-MATERIALS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Design of a Solid Electrolyte Interphase for Aqueous Zn Batteries

Dan Li et al.

Summary: A low-concentration aqueous Zn(OTF)(2)-Zn(NO3)(2) electrolyte was designed to form a robust inorganic ZnF2-Zn-5(CO3)(2)(OH)(6)-organic bilayer SEI, allowing high Coulombic efficiency and energy density. The study achieved a high CE of 99.8% for 200 h in Ti parallel to Zn cells, and a high energy density of 168 Wh kg(-1) with 96.5% retention for 700 cycles in Zn parallel to MnO2 cells with a low Zn/MnO2 capacity ratio of 2:1.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Add to Collection

Article Chemistry, Physical

Alkali Ions Pre-Intercalated Layered MnO2 Nanosheet for Zinc-Ions Storage

Liyuan Liu et al.

Summary: By pre-intercalating alkali ions and water crystals into layered delta-MnO2, ultra-thin nanosheets of K0.27MnO2∙0.54H2O (KMO) and Na0.55Mn2O4∙1.5H2O were prepared, which act as pillars to stabilize the structures and enable rapid cation diffusion in the KMO structure, leading to high power capability and good cycling stability. The charge storage mechanism of KMO in an aqueous Zn-ion battery involves (de)intercalation of H3O+ with further dissolution-precipitation of Zn-4(OH)6(SO4)∙5H2O solid product on the KMO surface, as revealed by electrochemical quartz crystal microbalance measurements and in-operando X-ray diffraction techniques.

ADVANCED ENERGY MATERIALS (2021)

Add to Collection

Article Chemistry, Physical

A Thin and Uniform Fluoride-Based Artificial Interphase for the Zinc Metal Anode Enabling Reversible Zn/MnO2 Batteries

Jin Han et al.

Summary: By developing an artificial ZnF2 layer on the surface of Zn metal anode, researchers have successfully addressed the limitation of zinc batteries' lifespan. This artificial layer suppresses dendrite growth and facilitates zinc insertion and transport through an interstitial diffusion mechanism. This improvement has been demonstrated by the long-term cycling and high capacity retention achieved by zinc-zincF2/MnO2 full cells.

ACS ENERGY LETTERS (2021)

Add to Collection

Review Electrochemistry

Zinc-Ion Hybrid Supercapacitors: Progress and Future Perspective

Xuefei Gong et al.

Summary: This review summarizes the recent advancements achieved in zinc-ion hybrid supercapacitors (ZIHSCs), including discussions on cathode, anode, electrolyte, and approaches adoptable to improve electrochemical performance with encouragement for more in-situ characterization methods. Future developments are envisioned for ZIHSCs to have higher active materials utilization rate, power output, and more functionality in assembly.

BATTERIES & SUPERCAPS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Boosting Li3V2(PO4)3 cathode stability using a concentrated aqueous electrolyte for high-voltage zinc batteries

Cuixia Li et al.

Summary: The study demonstrates that using a concentrated aqueous electrolyte based on Zn and Li salts can significantly address the capacity decay and voltage drop issues of the Li3V2(PO4)(3) cathode, resulting in a high output voltage and long lifespan for the Zn//Li3V2(PO4)(3) battery. Structural and spectroscopic characterizations show that the battery operates through Li+ (de)intercalation into the cathode and Zn2+ plating/stripping at the anode.

CHEMICAL COMMUNICATIONS (2021)

Add to Collection

Review Materials Science, Multidisciplinary

Recent progress and future prospects of sodium-ion capacitors

Rui Jia et al.

SCIENCE CHINA-MATERIALS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Highly Reversible Zn Anode Enabled by Controllable Formation of Nucleation Sites for Zn-Based Batteries

Pengcheng Liang et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

Add to Collection

Review Chemistry, Multidisciplinary

New Concepts in Electrolytes

Matthew Li et al.

CHEMICAL REVIEWS (2020)

Add to Collection

Article Chemistry, Physical

Reversible Electrochemical Interface of Mg Metal and Conventional Electrolyte Enabled by Intermediate Adsorption

Hui Wang et al.

ACS ENERGY LETTERS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Constructing a Super-Saturated Electrolyte Front Surface for Stable Rechargeable Aqueous Zinc Batteries

Huijun Yang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Add to Collection

Review Chemistry, Physical

Recent advances in zinc anodes for high-performance aqueous Zn-ion batteries

Hao Jia et al.

NANO ENERGY (2020)

Add to Collection

Article Energy & Fuels

Electrolyte design for LiF-rich solid-electrolyte interfaces to enable high-performance microsized alloy anodes for batteries

Ji Chen et al.

NATURE ENERGY (2020)

Add to Collection

Article Chemistry, Physical

Molecular crowding electrolytes for high-voltage aqueous batteries

Jing Xie et al.

NATURE MATERIALS (2020)

Add to Collection

Article Chemistry, Physical

Scalable synthesis of 2D hydrogen-substituted graphdiyne on Zn substrate for high-yield N2 fixation

Qi Yang et al.

NANO ENERGY (2020)

Add to Collection

Article Chemistry, Physical

Electrolyte solvation structure manipulation enables safe and stable aqueous sodium ion batteries

Huaisheng Ao et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Add to Collection

Article Chemistry, Multidisciplinary

High-Energy Rechargeable Metallic Lithium Battery at-70°C Enabled by a Cosolvent Electrolyte

Xiaoli Dong et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Toward High-Performance Hybrid Zn-Based Batteries via Deeply Understanding Their Mechanism and Using Electrolyte Additive

Junnan Hao et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

A Highly Reversible Zn Anode with Intrinsically Safe Organic Electrolyte for Long-Cycle-Life Batteries

Ahmad Naveed et al.

ADVANCED MATERIALS (2019)

Add to Collection

Article Multidisciplinary Sciences

Zinc anode-compatible in-situ solid electrolyte interphase via cation solvation modulation

Huayu Qiu et al.

NATURE COMMUNICATIONS (2019)

Add to Collection

Review Chemistry, Physical

Multivalent metal ion hybrid capacitors: a review with a focus on zinc-ion hybrid capacitors

Liubing Dong et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Add to Collection

Review Chemistry, Physical

Recent progress and perspectives on aqueous Zn-based rechargeable batteries with mild aqueous electrolytes

Xiaohui Zeng et al.

ENERGY STORAGE MATERIALS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Long-life and deeply rechargeable aqueous Zn anodes enabled by a multifunctional brightener-inspired interphase

Zhiming Zhao et al.

ENERGY & ENVIRONMENTAL SCIENCE (2019)

Add to Collection

Article Chemistry, Physical

A low-cost water-in-salt electrolyte for a 2.3 V high-rate carbon-based supercapacitor

Xudong Bu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Safe and high-rate supercapacitors based on an acetonitrile/water in salt hybrid electrolyte

Qingyun Dou et al.

ENERGY & ENVIRONMENTAL SCIENCE (2018)

Add to Collection

Review Chemistry, Physical

Progress and future prospects of high-voltage and high-safety electrolytes in advanced lithium batteries: from liquid to solid electrolytes

Shimou Chen et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

Add to Collection

Article Chemistry, Multidisciplinary

A ZnCl2 water-in-salt electrolyte for a reversible Zn metal anode

Chong Zhang et al.

CHEMICAL COMMUNICATIONS (2018)

Add to Collection

Article Chemistry, Physical

Extremely safe, high-rate and ultralong-life zinc-ion hybrid supercapacitors

Liubing Dong et al.

ENERGY STORAGE MATERIALS (2018)

Add to Collection

Article Chemistry, Multidisciplinary

How Solid-Electrolyte Interphase Forms in Aqueous Electrolytes

Liumin Suo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Add to Collection

Article Chemistry, Physical

Water-in-Salt Electrolyte Makes Aqueous Sodium-Ion Battery Safe, Green, and Long-Lasting

Liumin Suo et al.

ADVANCED ENERGY MATERIALS (2017)

Add to Collection

Article Chemistry, Physical

A High-Voltage Aqueous Electrolyte for Sodium-Ion Batteries

Ruben-Simon Kuehnel et al.

ACS ENERGY LETTERS (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Advanced High-Voltage Aqueous Lithium-Ion Battery Enabled by Water-in-Bisalt Electrolyte

Liumin Suo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Add to Collection

Article Energy & Fuels

Hydrate-melt electrolytes for high-energy-density aqueous batteries

Yuki Yamada et al.

NATURE ENERGY (2016)

Add to Collection

Article Multidisciplinary Sciences

Water-in-salt electrolyte enables high-voltage aqueous lithium-ion chemistries

Liumin Suo et al.

SCIENCE (2015)

Add to Collection

Article Physics, Applied

Raman scattering measurements on a floating water bridge

R. C. Ponterio et al.

JOURNAL OF PHYSICS D-APPLIED PHYSICS (2010)

Add to Collection

Review Chemistry, Multidisciplinary

Recent advances in rechargeable battery materials: a chemist's perspective

M. Rosa Palacin

CHEMICAL SOCIETY REVIEWS (2009)

Add to Collection

Article Chemistry, Physical

Solvation sheath of Li+ in nonaqueous electrolytes and its implication of graphite/electrolyte interface chemistry

Kang Xu et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2007)

Add to Collection

Article Chemistry, Physical

Signatures of the hydrogen bonding in the infrared bands of water

JB Brubach et al.

JOURNAL OF CHEMICAL PHYSICS (2005)

Add to Collection

© Peeref 2019-2024. All rights reserved.