4.8 Article

Design Strategies for Diradical Boron/Nitrogen Doped Carbon-Based Materials

Related references

Note: Only part of the references are listed.
Article Chemistry, Multidisciplinary

Diradical B/N-Doped Polycyclic Hydrocarbons

Jiaxiang Guo et al.

Summary: We report the synthesis of B/N-type organic diradicaloids with atom-precise control over open-shell nature through quinoidal pi-extension of a B/N-heterocycle. These diradicaloids exhibit modulated (anti)aromaticity and enhanced diradical characters compared with all-carbon analogues, and display intriguing properties such as magnetic activities and highly red-shifted absorptions.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

Review Chemistry, Multidisciplinary

Polycyclic Hydrocarbons from [4n]Annulenes: Correlation versus Hybridization Forces in the Formation of Diradicaloids

Sergio Moles Quintero et al.

Summary: This article provides conceptual connections between [4n] Huckel antiaromaticity, disjoint orbitals, correlation energy, pro-aromaticity and diradical character for a variety of extended pi-conjugated systems, including nanographenes and polycyclic aromatic radicals. Understanding these structure-property relationships is beneficial for establishing design guidelines for diradicaloids.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Article Materials Science, Multidisciplinary

Establishing design strategies for emissive materials with an inverted singlet-triplet energy gap (INVEST): a computational perspective on how symmetry rules the interplay between triplet harvesting and light emission

Gaetano Ricci et al.

Summary: The inversion of the lowest singlet and triplet excited state energy gaps can be achieved by introducing symmetry, which is significant for enhancing the performance of organic light-emitting diodes.

JOURNAL OF MATERIALS CHEMISTRY C (2022)

Article Chemistry, Multidisciplinary

A Stable Triplet-Ground-State Conjugated Diradical Based on a Diindenopyrazine Skeleton

Zi-Yuan Wang et al.

Summary: High-spin conjugated radicals have great potential in magnetic materials and organic spintronics, but their poor stability remains a challenge in obtaining them. Researchers have successfully synthesized a stable triplet conjugated diradical, m-DIP, with significant aromatic character and specific spin distribution characteristics.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Review Chemistry, Multidisciplinary

Persistent and Stable Organic Radicals: Design, Synthesis, and Applications

Z. X. Chen et al.

Summary: The study of open-shell radicals has made significant progress, showing that persistent and stable radicals can be prepared through rational design and appropriate chemical constructions. These materials exhibit unique physicochemical properties that open up new possibilities in the fields of magnetism, electronics, optoelectronics, and biology.
Review Chemistry, Multidisciplinary

Synthetic Tailoring of Graphene Nanostructures with Zigzag-Edged Topologies: Progress and Perspectives

Junzhi Liu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Review Chemistry, Multidisciplinary

Quinodimethanes Incorporated in Non-Benzenoid Aromatic or Antiaromatic Frameworks

Yoshito Tobe

TOPICS IN CURRENT CHEMISTRY (2018)

Article Chemistry, Multidisciplinary

Thiophene and its sulfur inhibit indenoindenodibenzothiophene diradicals from low-energy lying thermal triplets

Justin J. Dressler et al.

NATURE CHEMISTRY (2018)

Article Chemistry, Physical

A Review on the Origin of Synthetic Metal Radical: Singlet Open-Shell Radical Ground State?

Yuda Li et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2017)

Article Chemistry, Multidisciplinary

Boron-Stabilized Planar Neutral π-Radicals with Well-Balanced Ambipolar Charge-Transport Properties

Tomokatsu Kushida et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Review Chemistry, Multidisciplinary

Heterocyclic Quinodimethanes

Xueliang Shi et al.

TOPICS IN CURRENT CHEMISTRY (2017)

Article Chemistry, Physical

Theoretical Rationalization of the Singlet-Triplet Gap in OLEDs Materials: Impact of Charge-Transfer Character

M. Moral et al.

JOURNAL OF CHEMICAL THEORY AND COMPUTATION (2015)

Review Chemistry, Multidisciplinary

Diradicals

Manabu Abe

CHEMICAL REVIEWS (2013)

Article Chemistry, Physical

Diradical Character View of Singlet Fission

Takuya Minami et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2012)

Review Chemistry, Multidisciplinary

Molecular spintronics

Stefano Sanvito

CHEMICAL SOCIETY REVIEWS (2011)