4.7 Article

Carbon dioxide-enhanced photosynthesis of methane and hydrogen from carbon dioxide and water over Pt-promoted polyaniline-TiO2 nanocomposites

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 71, Pages 13654-13657

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc05113d

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Funding

  1. National Basic Research Program of China [2013CB933102]
  2. NSF of China [21433008]
  3. Program for Innovative Research Team in Chinese Universities [IRT_14R31]
  4. China Postdoctoral Science Foundation [2015M570555]
  5. Hubei Key Laboratory for Processing and Application of Catalytic Materials [ch201407]

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The combination of polyaniline with TiO2 significantly enhanced the photocatalytic reduction of CO2 with H2O owing to the increased CO2 chemisorption and the facilitated separation of photogenerated electron-hole pairs. We discovered that CO2 played a unique role in enhancing the electron- hole separation and the photocatalytic activity for polyaniline- containing catalysts.

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