Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 68, Pages 13260-13263Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc04723d
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Aliphatic 1,2-aminofluorides undergo extremely fast substitution reactions under the influence of lanthanum tris(hexamethyldisilazide). The substitution proceeds via an in situ generated aziridinium ion intermediate, which subsequently undergoes ring opening by addition of a nucleophile, yielding various beta-substituted amines.
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