Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 61, Pages 12235-12238Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc03601a
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Funding
- Major Basic Research Development Program [2011CB808706]
- National Natural Science Foundation of China (NSFC) [21372242, 21472214, 21421091]
- NSFC
- Research Grants Council of Hong Kong Joint Research Scheme [21361162001]
- Chinese Academy of Sciences
- Technology Commission of Shanghai Municipality
- Croucher Foundation of Hong Kong
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Palladium-catalyzed asymmetric intermolecular Mizoroki-Heck reaction for the construction of a chiral quaternary carbon center is developed, affording 2,2-disubstituted 2,5-dihydrofurans in high yield with excellent enantioselectivity. The products are easily converted into the corresponding butenolides with retention of enantioselectivity.
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