4.7 Article

Biomimetic materials in oil/water separation: Focusing on switchable wettabilities and applications

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Article Chemistry, Physical

Multi-layer superhydrophobic nickel foam (NF) composite for highly efficient water-in-oil emulsion separation

Yi Wang et al.

Summary: A superhydrophobic nickel foam composite was prepared using simple immersion method, further laminated into multi-layer composite for efficient water-in-oil emulsion separation. The material shows excellent chemical stability and mechanical durability, allowing for reusability in emulsion separation.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2021)

Article Engineering, Chemical

Wettability Switchable Membranes for Separating Both Oil-in-water and water-in-oil emulsions

Xi Zhang et al.

Summary: The study demonstrates the potential of separation membranes with switchable wettability in efficiently treating both oil-in-water and water-in-oil emulsions. By using a simple co-deposition method of tannic acid and diethylenetriamine, commercial polypropylene membranes are endowed with switchable surface wettability that can cyclically translate between hydrophilicity and hydrophobicity through water/ethanol treatments without losing surface wettability. Density functional theory simulations and UV-vis spectra analysis were used to illustrate the chemical mechanism behind this hydrophilicity-hydrophobicity translation.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Engineering, Chemical

A superwettable functionalized-fabric with pH-sensitivity for controlled oil/water, organic solvents separation, and selective oil collection from water-rich system

Mengnan Qu et al.

Summary: A multifunctional superwetting fabric has been developed in this article, which can efficiently separate various oil-water mixtures through a special preparation method, showing extensive application prospects.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

Article Engineering, Chemical

Smart light responsive polypropylene membrane switching reversibly between hydrophobicity and hydrophilicity for oily water separation

Zhen Chen et al.

Summary: This study presents a method for rapid transition of wetting properties on smart membrane surfaces through alternate UV and visible light irradiation, achieving the switch between hydrophilicity and hydrophobicity, and exhibiting exceptional physical and chemical stabilities.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Engineering, Chemical

Robust superhydrophilic and underwater superoleophobic membrane optimized by Cu doping modified metal-organic frameworks for oil-water separation and water purification

Meng Zhu et al.

Summary: This study successfully prepared superhydrophilic and underwater superoleophobic stainless steel mesh for efficient oil-water separation and organic matter degradation. The fabricated meshes maintained excellent oil-water separation efficiency under extreme conditions, and could degrade dye pollutants under visible light, improving solar energy utilization. This research lays the foundation for preparing super wetting membranes for oil-water separation and organic matter degradation in actual complex oily wastewater.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Engineering, Chemical

Superhydrophilic/superoleophobic shell powder coating as a versatile platform for both oil/water and oil/oil separation

Jingwei Lu et al.

Summary: A superhydrophilic/superoleophobic shell powder coating was developed for advanced separation membrane, effectively separating oil/water mixtures and oil/oil mixtures by utilizing selective wetting behavior towards oils with different polarities. This promising approach presents a high separation efficiency for various oil mixtures.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Engineering, Chemical

Durable and super-hydrophilic/underwater super-oleophobic two-dimensional MXene composite lamellar membrane with photocatalytic self-cleaning property for efficient oil/water separation in harsh environments

Jiaxin Hu et al.

Summary: This study presents a facile strategy to fabricate a two-dimensional MXene-based composite membrane with excellent permeation flux and separation efficiency, along with outstanding anti-fouling resistance and durability, even in harsh conditions, maintaining highly efficient oil/water separation performance.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Engineering, Chemical

In situ biomineralization-constructed superhydrophilic and underwater superoleophobic PVDF-TiO2 membranes for superior antifouling separation of oil-in-water emulsions

Wei Deng et al.

Summary: The in situ biomineralization method was used to fabricate PVDF-TiO2 membranes with superhydrophilic and underwater superoleophobic properties, which showed excellent antifouling performance and high rejection of oil during crossflow filtration of oil-in-water emulsions. The superior performance of the membrane was attributed to the durable and super-wetting TiO2 coatings, as well as the relatively smooth surface structure that prevented oil trapping.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Engineering, Chemical

Ultrafast preparation of hydrophobic ZIF-67/copper mesh via electrodeposition and hydrophobization for oil/water separation and dyes adsorption

Peizhang Zhou et al.

Summary: Homogeneous hydrophobic ZIF-67 decorated copper mesh was prepared using ultrafast electrodeposition and subsequent hydrophobization, showing high separation efficiency of over 98% and almost no decline after several cycles.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

Article Engineering, Chemical

Graphene-bentonite supported free-standing, flexible membrane with switchable wettability for selective oil-water separation

Pratik S. Dhumal et al.

Summary: The novel SBG composite membrane successfully achieved selective separation of oil and water with high efficiency, recyclability, and ease of preparation.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

Article Acoustics

Ultrasonic assisted rapid preparation of superhydrophobic stainless steel surface and its application in oil/water separation

Zongbo Zhang et al.

Summary: Superhydrophobic surfaces were successfully prepared on stainless steel using a rapid ultrasonic-assisted chemical etching method and low-cost fluorine-free modification treatment, showing a high water contact angle of 163.21 degrees. The ultrasonic cavitation effect enhanced the etching process, resulting in hierarchical micro-structures and improved surface wettability uniformity. The samples exhibited excellent oil/water separation performance and remarkable mechanical stability.

ULTRASONICS SONOCHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Preparation and Application of Superhydrophobic Copper Mesh by Chemical Etching and In-situ Growth

Qilei Tong et al.

Summary: This study developed a superhydrophobic copper mesh for efficient oil-water separation by utilizing chemical etching and in-situ growth methods. The copper mesh exhibited a water contact angle of over 160 degrees and maintained a separation efficiency of above 98% after multiple experiments. Optimized concentrations of FeCl3 and SA contributed to the best separation results.

FRONTIERS IN CHEMISTRY (2021)

Review Engineering, Multidisciplinary

Engineered Hybrid Materials with Smart Surfaces for Effective Mitigation of Petroleum-Originated Pollutants

Nisar Ali et al.

Summary: The generation and release of hydrocarbon-contaminated industrial waste-water effluents are major environmental concerns. Smart polymeric nanostructured materials with wettability properties have shown excellent performance in separating oil-water emulsions.

ENGINEERING (2021)

Article Materials Science, Multidisciplinary

pH-responsive smart superwetting Fe foam for efficient in situ on-demand oil/water separation

Shuyi Li et al.

Summary: The Fe foam with switchable wettability fabricated through modification showed advantages in separating oil/water mixtures effectively. It could operate in superhydrophobic/superoleophilic mode to separate heavy oil from water in air, and in superhydrophilic/underwater superoleophobic mode to remove water while preventing light oil from passing after alkaline treatments. The smart Fe foam maintained high separation efficiency for various oil/water mixtures even after ten cycles, and also offered non-contact, remote control for oil-water separation with good mechanical durability, long-term stability, and heat resistance.

JOURNAL OF MATERIALS SCIENCE (2021)

Article Materials Science, Multidisciplinary

High-yield production of carbon nanotubes from waste polyethylene and fabrication of graphene-carbon nanotube aerogels with excellent adsorption capacity

Zhong Huang et al.

Summary: In this study, a protectant was introduced for the first time to create efficient catalysts for the pyrolysis of waste plastics into carbon nanotubes, achieving a high yield; the resulting CNTs showed high adsorption capacity for methylene blue and could be used for wastewater treatment. Furthermore, the graphene-CNT aerogel prepared by combining CNTs with graphene oxide demonstrated excellent adsorption capabilities for oil/water separation.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2021)

Article Engineering, Chemical

Robust bio-inspired superhydrophilic and underwater superoleophobic membranes for simultaneously fast water and oil recovery

Riri Liu et al.

Summary: A stable and uniform bio-inspired coating with superhydrophilicity and underwater superoleophobicity was achieved on a non-woven fabric substrate through rapid co-deposition of dopamine and polyethylenimine. The co-deposition conditions, particularly the concentration of ammonium persulfate and coating duration, played a crucial role in determining the hydrophilicity and underwater oleophobicity of the coated fabric membranes. This study provides a facile and cost-effective strategy for constructing superhydrophilic and underwater superoleophobic interfaces for sustainable treatment of oily wastewater.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Engineering, Chemical

Magnetically driven superhydrophobic/superoleophilic graphene-based polyurethane sponge for highly efficient oil/water separation and demulsification

Azam Jamsaz et al.

Summary: A novel magnetic, superhydrophobic/superoleophilic and flame-retardant sponge material was developed in this study, showing efficient oil collection and excellent sorption performance, representing a promising new approach for remediation of oil spills in water.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

Article Nanoscience & Nanotechnology

Hygro-responsive, Photo-decomposed Superoleophobic/Superhydrophilic Coating for On-Demand Oil-Water Separation

Wenting Kong et al.

Summary: A hygro-responsive superoleophobic/superhydrophilic coating was successfully fabricated, showing superior selective superwettability under different conditions and efficient separation of oil-water mixtures with a separation efficiency of over 99%. Additionally, the long-chain perfluoroalkyl substances on the coating could be decomposed by UV irradiation, reducing harm to the environment and human beings.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Engineering, Environmental

A multifunctional graphene composite coating with switchable wettability

Hanpeng Gao et al.

Summary: The multifunctional graphene composite coating (MGCC) with switchable wettability, fabricated by simple methods, shows potential advantages in oil-water separation, droplet manipulation, metal corrosion resistance, and anti-icing and deicing abilities.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Chemistry, Physical

Mussel-inspired pH-responsive copper foam with switchable wettability for bidirectional oil-water separation

Weiwei Sui et al.

Summary: The study has developed a material with pH responsiveness through dopamine coating and silver particle construction, which can efficiently achieve bidirectional oil-water separation.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2021)

Article Engineering, Environmental

Freely switchable super-hydrophobicity and super-hydrophilicity of sponge-like poly(vinylidene fluoride) porous fibers for highly efficient oil/ water separation

Xiao-lei Liao et al.

Summary: The study demonstrates the high oil/water separation ability and super-hydrophilicity of PVDF porous fibrous membranes, showing potential for application in wastewater treatment.

JOURNAL OF HAZARDOUS MATERIALS (2021)

Article Engineering, Environmental

A facile and green route to fabricate fiber-reinforced membrane for removing oil from water and extracting water under slick oil

Kaili Jin et al.

Summary: In the preparation of membranes for oil-water mixture separation, a green tactic-water vapor induced phase inversion was proposed to fabricate nonwoven fabric-based cotton/PA6/PAN membranes with high strength and superhydrophilic/underwater superoleophobic properties, effectively reducing organic wastewater production. These membranes not only exhibit excellent separation performance, but can also extract water from oil-water mixtures.

JOURNAL OF HAZARDOUS MATERIALS (2021)

Article Environmental Sciences

Superhydrophobic-superoleophilic biochar-based foam for high-efficiency and repeatable oil-water separation

Haonan Duan et al.

Summary: Efficient and environmentally friendly oil-water separation methods are key to solving leakage accidents during oil production and transportation. The development of a high-performance oil absorbent through the loading of ball-milled biochar and octadecylamine on the skeleton of melamine foam is reported in this work. The modified foam shows high oil absorption capacity, recyclability, and stability in a wide pH range.

SCIENCE OF THE TOTAL ENVIRONMENT (2021)

Article Engineering, Chemical

An anti-oil-fouling and robust superhydrophilic MnCo2O4 coated stainless steel mesh for ultrafast oil/water mixtures separation

Yuezhong Zhang et al.

Summary: The development of a novel superhydrophilic/underwater superoleophobic oil/water separation membrane with ultra-high flux and high separation efficiency is important for treating oily wastewater. The MnCo2O4 coated stainless steel mesh shows excellent superhydrophilicity/underwater superoleophobicity, oil/water separation performance, anti-oil-fouling property, and recycling stability, making it a promising solution for oil/water separation applications.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

Article Engineering, Environmental

Amphiphilic wood powders with dual superlyophobicity enabled the switchable separation of oil-in-water and water-in-oil emulsion with high flux

Zai-Yin Hu et al.

Summary: Materials with dual superlyophobicity, such as wood powders, show promise in switchable separation of oil-in-water and water-in-oil emulsions due to their unique fibrous structure and superior wetting properties, achieving a separation efficiency as high as 99.9992%.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2021)

Article Chemistry, Physical

Inverse desert beetle-like ZIF-8/PAN composite nanofibrous membrane for highly efficient separation of oil-in-water emulsions

Haoyu Li et al.

Summary: Inspired by the water-collection ability of desert beetles, an inverse desert beetle-like membrane was constructed to effectively separate highly emulsified oily wastewater, demonstrating superior oil capture and reducing membrane blocking.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Engineering, Chemical

Bio-inspired membrane with adaptable wettability for smart oil/water separation

Lin Li et al.

JOURNAL OF MEMBRANE SCIENCE (2020)

Article Chemistry, Applied

Cellulosic sponges with pH responsive wettability for efficient oil-water separation

Lijie Li et al.

CARBOHYDRATE POLYMERS (2020)

Article Chemistry, Physical

Low-salt dyeing of cotton fabric grafted with pH-responsive cationic polymer of polyelectrolyte 2-(N,N-dimethylamino)ethyl methacrylate

Weiwei Dong et al.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2020)

Article Nanoscience & Nanotechnology

Multifunctional TiO2-Based Superoleophobic/Superhydrophilic Coating for Oil-Water Separation and Oil Purification

Feiran Li et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Green & Sustainable Science & Technology

Fabrication of recyclable multi-responsive magnetic nanoparticles for emulsified oil-water separation

Ting Lu et al.

JOURNAL OF CLEANER PRODUCTION (2020)

Article Chemistry, Multidisciplinary

Bio-Inspired Biomass-Derived Carbon Aerogels with Superior Mechanical Property for Oil-Water Separation

Tao Chen et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

Article Environmental Sciences

Laser-structured superhydrophobic/superoleophilic aluminum surfaces for efficient oil/water separation

Lie Chen et al.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2020)

Article Green & Sustainable Science & Technology

Environmental effect for a complex green supply-chain management to control waste: A sustainable approach

Jihed Jemai et al.

JOURNAL OF CLEANER PRODUCTION (2020)

Article Nanoscience & Nanotechnology

Durable Underwater Superoleophobic Coatings via Dispersed Micro Particle-Induced Hierarchical Structures Inspired by Pomfret Skin

Chuqian Wang et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Nanoscience & Nanotechnology

Simple Preparation Method for Hydrophilic/Oleophobic Coatings

Jinhui Li et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Review Green & Sustainable Science & Technology

Recent development of super -wettable materials and their applications in oil -water separation

Yuying Deng et al.

JOURNAL OF CLEANER PRODUCTION (2020)

Article Engineering, Chemical

Engineering highly effective nanofibrous membranes to demulsify surfactant-stabilized oil-in-water emulsions

Xiaofei You et al.

JOURNAL OF MEMBRANE SCIENCE (2020)

Article Chemistry, Applied

UV and thermal dual responsive coatings with high adhesion and mechanical robust properties

Weihong Hu et al.

PROGRESS IN ORGANIC COATINGS (2020)

Article Materials Science, Multidisciplinary

Thermoresponsive Polyurethane Sponges with Temperature-Controlled Superwettability for Oil/Water Separation

Peng Yi et al.

ACS APPLIED POLYMER MATERIALS (2020)

Article Materials Science, Coatings & Films

Hydrogen-bonded methylcellulose/poly(acrylic acid) complex membrane for oil-water separation

Dafaalla M. D. Babiker et al.

SURFACE & COATINGS TECHNOLOGY (2019)

Review Chemistry, Multidisciplinary

Recent advances of CO2-responsive materials in separations

Ziqi Yang et al.

JOURNAL OF CO2 UTILIZATION (2019)

Article Nanoscience & Nanotechnology

Design of a Janus F-TiO2@PPS Porous Membrane with Asymmetric Wettability for Switchable Oil/Water Separation

Chao Yang et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

Article Engineering, Environmental

Developing superhydrophobic rock wool for high-viscosity oil/water separation

Wentao Hao et al.

CHEMICAL ENGINEERING JOURNAL (2019)

Review Engineering, Environmental

Membrane-based separation for oily wastewater: A practical perspective

Henry J. Tanudjaja et al.

WATER RESEARCH (2019)

Article Chemistry, Physical

Smart carbon foams with switchable wettability for fast oil recovery

Yuheng Xu et al.

CARBON (2019)

Article Engineering, Environmental

Controllable preparation of multiple superantiwetting surfaces: From dual to quadruple superlyophobicity

Lu Tie et al.

CHEMICAL ENGINEERING JOURNAL (2019)

Article Engineering, Environmental

Surfaces with controllable super-wettability and applications for smart oil-water separation

Yunlu Pan et al.

CHEMICAL ENGINEERING JOURNAL (2019)

Article Engineering, Chemical

Efficient oil/water separation by superhydrophobic CuxS coated on copper mesh

Maryam Khosravi et al.

SEPARATION AND PURIFICATION TECHNOLOGY (2019)

Article Nanoscience & Nanotechnology

CO2 -Responsive Cellulose Nanofibers Aerogels for Switchable Oil- Water Separation

Yingzhan Li et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

Article Nanoscience & Nanotechnology

Separation Mechanism and Construction of Surfaces with Special Wettability for Oil/Water Separation

Chaolang Chen et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

Article Materials Science, Multidisciplinary

Facile preparation of a smart membrane with ammonia-responsive wettability transition for controllable oil/water separation

Xi Chen et al.

JOURNAL OF MATERIALS SCIENCE (2018)

Review Mechanics

Numerical Models of Surface Tension

Stephane Popinet

ANNUAL REVIEW OF FLUID MECHANICS, VOL 50 (2018)

Article Chemistry, Multidisciplinary

Stable Superhydrophobic Ceramic-Based Carbon Nanotube Composite Desalination Membranes

Yingchao Dong et al.

NANO LETTERS (2018)

Review Chemistry, Physical

Produced water treatment by membranes: A review from a colloidal perspective

J. M. Dickhout et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2017)

Article Engineering, Chemical

Dual pH- and ammonia-vapor-responsive electrospun nanofibrous membranes for oil-water separations

Wenjing Ma et al.

JOURNAL OF MEMBRANE SCIENCE (2017)

Review Chemistry, Physical

Smart responsive materials for water purification: an overview

Kingshuk Dutta et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

Article Engineering, Environmental

Superhydrophobic copper coating: Switchable wettability, on-demand oil-water separation, and antifouling

Wenwen Yang et al.

CHEMICAL ENGINEERING JOURNAL (2017)

Article Chemistry, Multidisciplinary

Improved Interfacial Floatability of Superhydrophobic/Superhydrophilic Janus Sheet Inspired by Lotus Leaf

Yuyan Zhao et al.

ADVANCED FUNCTIONAL MATERIALS (2017)

Article Chemistry, Physical

Durability evaluation of superhydrophobic copper foams for long-term oil-water separation

Haiyan Zhu et al.

APPLIED SURFACE SCIENCE (2017)

Article Chemistry, Physical

Thermo-responsive PVDF/PSMA composite membranes with micro/nanoscale hierarchical structures for oil/water emulsion separation

Xiaoyu Yuan et al.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2017)

Article Engineering, Environmental

A magnetic superhydrophilic/oleophobic sponge for continuous oil-water separation

Chunping Su et al.

CHEMICAL ENGINEERING JOURNAL (2017)

Review Chemistry, Multidisciplinary

CO2-responsive polymeric materials: synthesis, self-assembly, and functional applications

Ali Darabi et al.

CHEMICAL SOCIETY REVIEWS (2016)

Article Chemistry, Physical

Bio-inspired durable, superhydrophobic magnetic particles for oil/water separation

Liang Zhang et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2016)

Article Chemistry, Multidisciplinary

Scalable Seashell-Based Chemical Vapor Deposition Growth of Three-Dimensional Graphene Foams for Oil-Water Separation

Liurong Shi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Article Chemistry, Multidisciplinary

A Superamphiphobic Coating with an Ammonia-Triggered Transition to Superhydrophilic and Superoleophobic for Oil-Water Separation

Zhiguang Xu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Physical

Robust superhydrophobic TiO2@fabrics for UV shielding, self-cleaning and oil-water separation

J. Y. Huang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2015)

Article Nanoscience & Nanotechnology

Self-Driven One-Step Oil Removal from Oil Spill on Water via Selective-Wettability Steel Mesh

Jinlong Song et al.

ACS APPLIED MATERIALS & INTERFACES (2014)

Review Engineering, Chemical

Wetting phenomenon in membrane contactors - Causes and prevention

Sanaz Mosadegh-Sedghi et al.

JOURNAL OF MEMBRANE SCIENCE (2014)

Article Chemistry, Multidisciplinary

Wetting Transitions in Underwater Oleophobic Surface of Brass

Vahid Hejazi et al.

ADVANCED MATERIALS (2012)

Article Dentistry, Oral Surgery & Medicine

Inhibition of Biofilm Formation using Newly Developed Coating Materials with Self-cleaning Properties

Ayako Okada et al.

DENTAL MATERIALS JOURNAL (2008)

Article Chemistry, Physical

Superhydrophobic states

A Lafuma et al.

NATURE MATERIALS (2003)

Article Chemistry, Physical

Separation of oil from water by dissolved air flotation

AA Al-Shamrani et al.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2002)