4.7 Article

Rh(III)-Catalyzed Direct ortho Alkylation of Carbazoles with Nitroalkenes

Journal

ADVANCED SYNTHESIS & CATALYSIS
Volume -, Issue -, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202300677

Keywords

carbazole; nitroalkene; alkylation; rhodium; C-H activation

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The Rh(III)-catalyzed ortho alkylation of N-pyridylcarbazoles with nitroalkenes has been developed for the synthesis of a wide range of 2-(2nitroalkyl)carbazoles. Aromatic and aliphatic nitroalkenes both successfully participated in this alkylation reaction. The protocol also worked well with an indoline based substrate. Derivatization of the representative nitroalkane product was described.
The Rh(III)-catalyzed ortho alkylation of N-pyridylcarbazoles with nitroalkenes has been developed, furnishing a wide range of 2-(2nitroalkyl)carbazoles. Both aromatic and aliphatic nitroalkenes participated in this alkylation reaction successfully. This protocol also proceeded well with an indoline based substrate. Derivatization of the representative nitroalkane product was described.

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