4.8 Review

Challenges and Advances in Rechargeable Batteries for Extreme-Condition Applications

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Summary: Layered lithium-rich cathode materials with high theoretical specific capacity have regained interest due to the increasing reliance on high-energy-density lithium-ion batteries. Research progress on the structure characterization and reaction mechanisms of these materials has been reviewed, focusing on both cationic and anionic redox reactions. The future development of lithium-rich cathode materials for next-generation lithium-ion batteries faces opportunities and challenges.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Review Chemistry, Physical

Interfacial challenges towards stable Li metal anode

Zheng Luo et al.

Summary: Rechargeable Li metal batteries had a glory moment in the 1980s, but were soon suspended due to safety concerns. However, with the increasing demands for high energy devices, Li metal anodes are now experiencing a revival. Despite significant progress, efficiency and safety issues continue to plague current Li metal anodes, highlighting the importance of understanding the interfacial chemistry and kinetics for practical applications.

NANO ENERGY (2021)

Review Chemistry, Multidisciplinary

Promoting Rechargeable Batteries Operated at Low Temperature

Xiaoli Dong et al.

Summary: Building rechargeable batteries for subzero temperature application poses challenges due to factors such as material properties, electrolyte behavior, electrode reactions, and interfacial resistance. Optimizing electrolyte and electrode materials to enhance performance, along with understanding and reducing interfacial resistance, are key strategies to develop high-energy-density batteries for low-temperature use.

ACCOUNTS OF CHEMICAL RESEARCH (2021)

Article Chemistry, Multidisciplinary

2D Molecular Sheets of Hydrogen-Bonded Organic Frameworks for Ultrastable Sodium-Ion Storage

Yunling Wu et al.

Summary: Research has shown that designing and introducing multisite hydrogen bonding within HOFs can overcome the issue of weak hydrogen bonds dissociating, resulting in excellent electrochemical performance of the prepared 2D molecular sheets with long cycle life. Theoretical simulations indicate that the activation barrier for Na+ ion diffusion within the organic frameworks is low, contributing to the exceptional electrochemical performance.

ADVANCED MATERIALS (2021)

Review Chemistry, Multidisciplinary

Review on Li Deposition in Working Batteries: From Nucleation to Early Growth

Xiao-Ru Chen et al.

Summary: Lithium metal as a promising alternative anode material for high-energy-density batteries is crucial in the new era of advanced energy storage. Understanding the deposition mechanism from nucleation to early growth is essential for improving battery performance and dendrite-free deposition behavior. Various models have been proposed to enhance the insight into the lithium deposition process, opening up new possibilities for practical lithium metal batteries.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

Deeply Cycled Sodium Metal Anodes at Low Temperature and in Lean Electrolyte Conditions

Xiaofei Hu et al.

Summary: A composite electrolyte consisting of ether and ionic liquid was proposed to address dendrite growth of metallic sodium anode at low temperatures, enabling stable cycling with high reversible capacity. This electrolyte also demonstrated high capacity retention for full cells and sodium-carbon dioxide batteries at various temperatures.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Energy & Fuels

Poly(benzobisthiazole-dione) Frameworks for Highly Reversible Sodium- and Potassium-Ion Storage

Mochun Zhang et al.

Summary: The search for electrode materials for highly reversible electrochemical sodium/potassium-ion storage in batteries is crucial. Organic electrode materials have potential due to their functional diversity and tunability, but their long-term cyclability remains a challenge. This study reports a quinone-based polymer as a promising cathode material for sodium/potassium-ion storage, showing excellent cycle performances.

ENERGY & FUELS (2021)

Review Chemistry, Physical

A review of composite polymer-ceramic electrolytes for lithium batteries

Xingwen Yu et al.

Summary: All-solid-state lithium batteries are gaining attention, with solid polymer electrolytes and solid ceramic electrolytes as two major research categories. Solid composite electrolytes that combine the advantages of these materials can greatly enhance battery performance compared to using polymer or ceramic electrolytes alone.

ENERGY STORAGE MATERIALS (2021)

Article Chemistry, Physical

Strategies to Boost Ionic Conductivity and Interface Compatibility of Inorganic- Organic Solid Composite Electrolytes

Xiaoqi Zhu et al.

Summary: All-solid-state electrolytes, particularly inorganic-organic solid composite electrolytes, have great potential in high energy batteries due to their safety assurance. However, poor ionic conductivity and unstable electrode-electrolyte interface pose challenges in their development. Strategies to improve ionic conductivity and interface compatibility include tuning filler properties, surface decoration, and utilizing additives, as well as designing multilayered electrolytes and blending polymers with different molecular weights and functional groups. This review aims to provide insights and guidance for the design of all-solid-state lithium metal batteries.

ENERGY STORAGE MATERIALS (2021)

Article Chemistry, Physical

Effect of continuous pressures on electrochemical performance of Si anodes

J. Cui et al.

Summary: The large volume change of Si anodes during lithiation and delithiation cycles leads to capacity fading due to powder pulverization and loss of electrical contact. Applying 0.6 MPa pressure can reduce interfacial resistance, improve specific capacity, Coulombic efficiency, and cycle stability. However, excessive pressures may lead to overcharge, short circuit, and uneven lithium deposition.

MATERIALS TODAY ENERGY (2021)

Review Chemistry, Multidisciplinary

Recent Advances in Silicon-Based Electrodes: From Fundamental Research toward Practical Applications

Mingzheng Ge et al.

Summary: This article presents the latest developments in the rational design of Si-based electrodes and their potential applications, while discussing the challenges and potential solutions. Si-based anode materials will play a key role in meeting the demands for higher energy density in the coming decades.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

Realizing an All-Round Hydrogel Electrolyte toward Environmentally Adaptive Dendrite-Free Aqueous Zn-MnO2 Batteries

Minfeng Chen et al.

Summary: A all-round hydrogel electrolyte was developed using cotton, tetraethyl orthosilicate, and glycerol, exhibiting high ionic conductivity and excellent mechanical properties.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

Thermoregulating Separators Based on Phase-Change Materials for Safe Lithium-Ion Batteries

Zhifang Liu et al.

Summary: This study presents a novel design for a thermoregulating separator using a phase-change material (PCM) that can effectively mitigate the issue of overheating in lithium-ion batteries (LIBs).

ADVANCED MATERIALS (2021)

Review Chemistry, Physical

A review of current collectors for lithium-ion batteries

Pengcheng Zhu et al.

Summary: This review article presents six types of materials for current collectors, including Al, Cu, Ni, Ti, stainless steel and carbonaceous materials, and compares them based on five aspects of electrochemical stability, electrical conductivity, mechanical property, density, and sustainability. The effects of three different structures of foil, mesh, and foam as well as two treatments of chemical etching and coating are also discussed, highlighting future opportunities for next-generation lithium-ion batteries.

JOURNAL OF POWER SOURCES (2021)

Review Green & Sustainable Science & Technology

Mitigation strategies for Li-ion battery thermal runaway: A review

Bin Xu et al.

Summary: This article reviews safety strategies for Li-ion batteries, including various methods like positive temperature coefficient thermistors, current interrupt devices, passive protection designs in battery packages, and battery management systems. The trigger conditions, protection mechanisms, drawbacks, and applications of representative strategies are discussed, as well as potential future risk mitigation approaches.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2021)

Article Chemistry, Multidisciplinary

In Situ Polymerization Permeated Three-Dimensional Li+-Percolated Porous Oxide Ceramic Framework Boosting All Solid-State Lithium Metal Battery

Yiyuan Yan et al.

Summary: The integrated strategy proposed in this study can guide the preparation of highly conductive solid electrolytes and compatible interface designs to enhance the performance of practical high-energy-density all solid-state lithium metal batteries.

ADVANCED SCIENCE (2021)

Review Chemistry, Multidisciplinary

A Decade of Progress on Solid-State Electrolytes for Secondary Batteries: Advances and Contributions

Ouwei Sheng et al.

Summary: Compared to traditional liquid batteries, all-solid-state batteries (ASSBs) show great potential for enhancing safety in electric vehicles while maintaining operational durability and range. Solid-state electrolytes (SSEs) play a crucial role in ASSBs, requiring high ionic conductivity and compatibility with electrodes. Recent efforts have focused on advancing SSE technology, particularly with metal anode-oriented SSEs with high energy density.

ADVANCED FUNCTIONAL MATERIALS (2021)

Review Chemistry, Physical

A Review of Existing and Emerging Methods for Lithium Detection and Characterization in Li-Ion and Li-Metal Batteries

Partha P. Paul et al.

Summary: This review discusses various approaches used to detect and characterize the formation of Li in batteries, each technique has its unique advantages and limitations towards solving part of the puzzle of battery degradation. Multimodal characterization holds promise for addressing concerns in the implementation of the next generation of batteries in the transportation sector.

ADVANCED ENERGY MATERIALS (2021)

Review Chemistry, Multidisciplinary

Wide Working Temperature Range Rechargeable Lithium-Sulfur Batteries: A Critical Review

Zhenfang Zhou et al.

Summary: Lithium sulfur batteries, with their ultrahigh theoretical gravimetric energy density and low cost and environmental friendliness, are being further developed to operate at a wide range of temperatures. Challenges in material performance, electrolytes, lithium metal anodes, and the impact of thermal changes are key areas for future research directions in enabling lithium sulfur batteries to function effectively in extreme temperature conditions.

ADVANCED FUNCTIONAL MATERIALS (2021)

Review Chemistry, Multidisciplinary

Frontiers in Theoretical Analysis of Solid Electrolyte Interphase Formation Mechanism

Norio Takenaka et al.

Summary: SEI is an ion conductive yet electron-insulating layer on battery electrodes, impacting the safety, power, and lifetime of batteries. Traditional theoretical calculations and experimental approaches have limitations in revealing intermediate steps of SEI growth, but recent multiscale simulation methods have made a significant breakthrough.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

Highly Reversible Aqueous Zinc Batteries enabled by Zincophilic-Zincophobic Interfacial Layers and Interrupted Hydrogen-Bond Electrolytes

Longsheng Cao et al.

Summary: By using a eutectic electrolyte with tin chloride additive, a zincophilic/zincophobic Sn/Zn-5(OH)(8)Cl-2•H2O bilayer interphase is formed, overcoming the challenges of Zn dendritic growth and poor low-temperature performance in aqueous Zn batteries. The eutectic electrolyte enables high Coulombic efficiency and steady charge/discharge performance at low temperatures, showing great potential for practical applications.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Engineering, Environmental

High performance of low-temperature electrolyte for lithium-ion batteries using mixed additives

Weixia Lv et al.

Summary: In this study, both the solvent and lithium salt were modified to enhance the low temperature performance of the electrolyte. The mixed additives of BA + EC + LBF were found to improve the capacity and voltage platform of the batteries at low temperatures by forming a thin LiF film on the cathode surface.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Chemistry, Physical

Unlocking the Electrochemical-Mechanical Coupling Behaviors of Dendrite Growth and Crack Propagation in All-Solid-State Batteries

Chunhao Yuan et al.

Summary: A new electrochemical-mechanical model was established to directly couple dendrite growth and crack propagation in solid-state lithium metal batteries. It was found that high lithiation rates and low electrolyte conductivity could accelerate electrochemical failure. The model provides insights for designing robust and safe batteries.

ADVANCED ENERGY MATERIALS (2021)

Review Chemistry, Multidisciplinary

Electrolyte Design for Lithium Metal Anode-Based Batteries Toward Extreme Temperature Application

Dan Luo et al.

Summary: Lithium anode-based batteries (LBs) are in high demand due to their high theoretical capacity and low reduction potential of metallic lithium. However, they face challenges in extreme temperature conditions, requiring electrolyte design strategies to improve performance. Research on extreme temperature electrolyte design for practical applications is essential for the deployment of LBs in various critical areas.

ADVANCED SCIENCE (2021)

Article Chemistry, Multidisciplinary

Concentrated Electrolytes Widen the Operating Temperature Range of Lithium-Ion Batteries

Jianhui Wang et al.

Summary: The use of concentrated electrolytes can expand the operating temperature range of Lithium-ion batteries, improving their stability. Research shows that concentrated electrolytes can enable stable charge-discharge cycling in a wide temperature range from -20 to 100 degrees Celsius, reducing challenges at high temperatures.

ADVANCED SCIENCE (2021)

Article Chemistry, Physical

Cocktail therapy towards high temperature/high voltage lithium metal battery via solvation sheath structure tuning

Tianle Zheng et al.

Summary: By manipulating the solvation structure in the ADFN electrolyte solution, a stable SEI layer rich in inorganic species was generated to inhibit the continuous consumption of electrolyte solvent and suppress lithium dendrite growth. This innovative strategy provides fundamental insights into ADN solvation and offers a simple way to optimize Li-ion electrolyte for wide-temperature and high voltage applications, leading to improved cyclic stability and electrochemical performance.

ENERGY STORAGE MATERIALS (2021)

Article Chemistry, Multidisciplinary

Porous polyimide framework based on perylene and triazine for reversible potassium-ion storage

Jialing Wu et al.

Summary: Porous polyimide frameworks (PIFs) based on perylene and triazine have been identified as a promising anode material for potassium-ion batteries, offering high reversible specific capacity, good rate performance, and long cycling stability.

MATERIALS CHEMISTRY FRONTIERS (2021)

Review Chemistry, Physical

Alternative anodes for low temperature lithium-ion batteries

Gearoid A. Collins et al.

Summary: This comprehensive review explores the factors influencing the performance of Li-ion batteries at low temperatures, outlines the shortcomings of current technologies, and discusses recent findings in the field with a focus on alternative anode materials. Various approaches to improving the performance of Li-ion batteries at low temperatures are analyzed in-depth, offering diverse solutions for enhancing their performance.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Review Chemistry, Multidisciplinary

Electrochemical energy storage devices working in extreme conditions

Mingzhe Chen et al.

Summary: The energy storage system (ESS) revolution has expanded the uses of ESSs, but working under extreme conditions poses challenges that require exploring new approaches.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Article Electrochemistry

The Impact of Different Substituents in Fluorinated Cyclic Carbonates in the Performance of High Voltage Lithium-Ion Battery Electrolyte

Meinan He et al.

Summary: The study investigated a series of electrolytes containing various fluorinated cyclic carbonates as the SEI former, and found that the electrolyte with DFEC/FEMC exhibited excellent cycling performance and stability for high voltage lithium-ion batteries.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2021)

Review Chemistry, Multidisciplinary

Electro-chemo-mechanics of lithium in solid state lithium metal batteries

Yongfu Tang et al.

Summary: This review discusses the current status of solid state lithium metal batteries and the challenges they face, summarizing issues related to lithium dendrite penetration through SSEs, detrimental interfacial reactions, and proposing possible mitigation strategies.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Article Engineering, Chemical

Engineering C-N Moieties in Branched Nitrogen-Doped Graphite Tubular Foam toward Stable Li+-Storage at Low Temperature

Fei Lu et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2020)

Article Chemistry, Physical

Air-Stable and Dendrite-Free Lithium Metal Anodes Enabled by a Hybrid Interphase of C60 and Mg

Qingshuai Xu et al.

ADVANCED ENERGY MATERIALS (2020)

Review Chemistry, Physical

Fundamentals and Challenges of Lithium Ion Batteries at Temperatures between-40 and 60 °C

Junbo Hou et al.

ADVANCED ENERGY MATERIALS (2020)

Review Nanoscience & Nanotechnology

Design strategies for nonaqueous multivalent-ion and monovalent-ion battery anodes

Matthew Li et al.

NATURE REVIEWS MATERIALS (2020)

Article Chemistry, Physical

Advanced Electrolytes for Fast-Charging High-Voltage Lithium-Ion Batteries in Wide-Temperature Range

Xianhui Zhang et al.

ADVANCED ENERGY MATERIALS (2020)

Article Chemistry, Physical

Ultralow-Concentration Electrolyte for Na-Ion Batteries

Yuqi Li et al.

ACS ENERGY LETTERS (2020)

Review Chemistry, Physical

Activating Li2S as the Lithium-Containing Cathode in Lithium-Sulfur Batteries

Hualin Ye et al.

ACS ENERGY LETTERS (2020)

Review Energy & Fuels

Current status and future directions of multivalent metal-ion batteries

Yanliang Liang et al.

NATURE ENERGY (2020)

Article Chemistry, Multidisciplinary

Electrolyte Oxidation Pathways in Lithium-Ion Batteries

Bernardine L. D. Rinkel et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

News Item Multidisciplinary Sciences

Cool metric for lithium-ion batteries could spur progress

Gregory Offer et al.

NATURE (2020)

Review Chemistry, Physical

Designing Advanced Lithium-Based Batteries for Low-Temperature Conditions

Abhay Gupta et al.

ADVANCED ENERGY MATERIALS (2020)

Article Multidisciplinary Sciences

Designing electrolytes with polymerlike glass-forming properties and fast ion transport at low temperatures

Qing Zhao et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2020)

Review Chemistry, Multidisciplinary

Dendrites in Zn-Based Batteries

Qi Yang et al.

ADVANCED MATERIALS (2020)

Article Chemistry, Physical

A self-smoothing Li-metal anode enabled via a hybrid interface film

Huirong Wang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Review Chemistry, Multidisciplinary

A review on energy chemistry of fast-charging anodes

Wenlong Cai et al.

CHEMICAL SOCIETY REVIEWS (2020)

Review Chemistry, Multidisciplinary

Electro-Chemo-Mechanical Issues at the Interfaces in Solid-State Lithium Metal Batteries

Peng Wang et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

Review Energy & Fuels

A review on various temperature-indication methods for Li-ion batteries

L. H. J. Raijmakers et al.

APPLIED ENERGY (2019)

Review Chemistry, Multidisciplinary

Recent Development in Separators for High-Temperature Lithium-Ion Batteries

Muhammad Waqas et al.

SMALL (2019)

Article Chemistry, Multidisciplinary

Aqueous Batteries Operated at-50 °C

Qingshun Nian et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Review Multidisciplinary Sciences

Energy storage: The future enabled by nanomaterials

Ekaterina Pomerantseva et al.

SCIENCE (2019)

Review Chemistry, Multidisciplinary

Intercalation chemistry of graphite: alkali metal ions and beyond

Yuqi Li et al.

CHEMICAL SOCIETY REVIEWS (2019)

Review Chemistry, Multidisciplinary

30 Years of Lithium-Ion Batteries

Matthew Li et al.

ADVANCED MATERIALS (2018)

Article Chemistry, Multidisciplinary

A Silica-Aerogel-Reinforced Composite Polymer Electrolyte with High Ionic Conductivity and High Modulus

Dingchang Lin et al.

ADVANCED MATERIALS (2018)

Article Multidisciplinary Sciences

Self-heating-induced healing of lithium dendrites

Lu Li et al.

SCIENCE (2018)

Article Electrochemistry

On the Decomposition of Carbonate-Based Lithium-Ion Battery Electrolytes Studied Using Operando Infrared Spectroscopy

Najmus Saqib et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2018)

Review Thermodynamics

Thermal issues about Li-ion batteries and recent progress in battery thermal management systems: A review

Huaqiang Liu et al.

ENERGY CONVERSION AND MANAGEMENT (2017)

Article Chemistry, Physical

Ex-situ and in-situ observations of the effects of gamma radiation on lithium ion battery performance

Chuting Tan et al.

JOURNAL OF POWER SOURCES (2017)

Review Multidisciplinary Sciences

Functional membrane separators for next-generation high-energy rechargeable batteries

Yuede Pan et al.

NATIONAL SCIENCE REVIEW (2017)

Review Energy & Fuels

A materials perspective on Li-ion batteries at extreme temperatures

Marco-Tulio F. Rodrigues et al.

NATURE ENERGY (2017)

Article Chemistry, Multidisciplinary

Feasibility of Cathode Surface Coating Technology for High-Energy Lithium-ion and Beyond-Lithium-ion Batteries

Sujith Kalluri et al.

ADVANCED MATERIALS (2017)

Article Chemistry, Physical

4.0 V Aqueous Li-Ion Batteries

Chongyin Yang et al.

JOULE (2017)

Review Chemistry, Multidisciplinary

High temperature electrical energy storage: advances, challenges, and frontiers

Xinrong Lin et al.

CHEMICAL SOCIETY REVIEWS (2016)

Article Chemistry, Physical

Radiation effects on the electrode and electrolyte of a lithium-ion battery

Chuting Tan et al.

JOURNAL OF POWER SOURCES (2016)

Article Chemistry, Physical

Exothermic behaviors of mechanically abused lithium-ion batteries with dibenzylamine

Yang Shi et al.

JOURNAL OF POWER SOURCES (2016)

Article Chemistry, Physical

Niobium-doped titanium oxide anode and ionic liquid electrolyte for a safe sodium-ion battery

Hiroyuki Usui et al.

JOURNAL OF POWER SOURCES (2016)

Article Chemistry, Physical

Experimental and theoretical analysis of a method to predict thermal runaway in Li-ion cells

Krishna Shah et al.

JOURNAL OF POWER SOURCES (2016)

Article Multidisciplinary Sciences

Lithium-ion battery structure that self-heats at low temperatures

Chao-Yang Wang et al.

NATURE (2016)

Article Nanoscience & Nanotechnology

In Situ Catalytic Synthesis of High-Graphitized Carbon-Coated LiFePO4 Nanoplates for Superior Li-Ion Battery Cathodes

Zhipeng Ma et al.

ACS APPLIED MATERIALS & INTERFACES (2015)

Review Chemistry, Multidisciplinary

Lithium salts for advanced lithium batteries: Li-metal, Li-O-2, and Li-S

Reza Younesi et al.

ENERGY & ENVIRONMENTAL SCIENCE (2015)

Editorial Material Multidisciplinary Sciences

The energy-storage revolution

George Crabtree

NATURE (2015)

Article Chemistry, Physical

Mixed salts of LiTFSI and LiBOB for stable LiFePO4-based batteries at elevated temperatures

Xilin Chen et al.

JOURNAL OF MATERIALS CHEMISTRY A (2014)

Review Chemistry, Multidisciplinary

High temperature sodium batteries: status, challenges and future trends

Karina B. Hueso et al.

ENERGY & ENVIRONMENTAL SCIENCE (2013)

Article Chemistry, Multidisciplinary

Fluorinated electrolytes for 5 V lithium-ion battery chemistry

Zhengcheng Zhang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2013)

Article Chemistry, Physical

A high temperature operating nanofibrous polyimide separator in Li-ion battery

Wen Jiang et al.

SOLID STATE IONICS (2013)

Article Electrochemistry

Suppression of lithium deposition at sub-zero temperatures on graphite by surface modification

Nanda Gunawardhana et al.

ELECTROCHEMISTRY COMMUNICATIONS (2011)

Review Chemistry, Physical

Structure and performance of LiFePO4 cathode materials: A review

Wei-Jun Zhang

JOURNAL OF POWER SOURCES (2011)

Review Multidisciplinary Sciences

Electrical Energy Storage for the Grid: A Battery of Choices

Bruce Dunn et al.

SCIENCE (2011)