4.8 Review

Atomic Manufacturing of Advanced Nanomaterials

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Summary: The article demonstrates a new method for surface atom manipulation using a coordination compound for atomic-scale fabrication, overcoming the limitations of traditional scanning probe microscopy techniques.

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Valence oscillation and dynamic active sites in monolayer NiCo hydroxides for water oxidation

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Summary: Monolayer materials offer an extra degree of freedom to modulate electronic structures and catalytic performances, promoting dynamic active site generation for the oxygen evolution reaction at lower potentials. Lattice doping with cobalt tunes the electronic structure and reduces overpotential, while in situ experiments reveal valence state oscillation in NiCo hydroxides as a fundamental mechanism for active site generation.

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Topological Shiba bands in artificial spin chains on superconductors

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Summary: The study analyzes Bogoliubov quasiparticle interference in Mn chains constructed atom by atom on Nb(110), revealing the formation of multi-orbital Shiba bands, including one band with a topologically non-trivial p-wave gap. This work represents an important step towards experimentally determining topological phases in multi-orbital systems using only bulk electron band structure properties.

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Hetero-site nucleation for growing twisted bilayer graphene with a wide range of twist angles

Luzhao Sun et al.

Summary: The authors developed a chemical vapor deposition method for synthesizing twisted bilayer graphene with controllable angles. By employing a hetero-site nucleation strategy, they successfully prepared bilayer graphene with twist angles ranging from 0 degrees to 30 degrees, demonstrating high-quality and improved performance for potential applications in fundamental research and practical use.

NATURE COMMUNICATIONS (2021)

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Single-Atom Zinc and Anionic Framework as Janus Separator Coatings for Efficient Inhibition of Lithium Dendrites and Shuttle Effect

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Summary: This study presents a Janus separator prepared with anionic metal-organic framework and single-atom zinc catalyst, which effectively inhibits the dendrite growth and shuttle effect of Li-S batteries. The results show stable cyclic performance and outstanding protection capability, making it suitable for various types of Li-S or Li-Se batteries.

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High-Entropy Metal-Organic Frameworks for Highly Reversible Sodium Storage

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Summary: A new approach of introducing high entropy into Prussian blue analogues (PBAs) has been developed to improve their electrochemical properties, resulting in high-entropy PBAs (HE-PBA) with quasi-zero-strain reaction mechanism. The gassing behavior of PBAs and structural degradation of HE-PBA during battery operation were also investigated, achieving nearly 100% Coulombic efficiency after optimization of the electrochemical window.

ADVANCED MATERIALS (2021)

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Electronic Modulation of Non-van der Waals 2D Electrocatalysts for Efficient Energy Conversion

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Summary: This review critically examines the progress of non-vdW 2D electrocatalysts, with a special emphasis on electronic structure modulation and performance enhancement. Strategies such as heteroatom doping, vacancy engineering, pore creation, alloying, and heterostructure engineering are analyzed for tuning electronic structures to achieve higher electrocatalytic performance. A roadmap for the future development of non-vdW 2D electrocatalysts is provided from material, mechanism, and performance perspectives.

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Strongly Coupled Cobalt Diselenide Monolayers for Selective Electrocatalytic Oxygen Reduction to H2O2 under Acidic Conditions

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Summary: This study presents experimental evidence of narrowing the interlayer gap of metallic cobalt diselenide to create a high-performance catalyst for the selective production of H2O2 in an acidic environment. By enhancing the interlayer coupling, a favorable surface electronic structure is achieved that promotes the energetics for H2O2 production. The strongly coupled CoSe2 catalyst shows excellent performance and long-term stability in the production of H2O2.

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Strategies, Status, and Challenges in Wafer Scale Single Crystalline Two-Dimensional Materials Synthesis

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Summary: The successful exfoliation of graphene has led to an increased focus on research of two-dimensional materials, which exhibit unique properties and potential applications. To achieve large-scale practical applications, wafer scale single crystalline 2D materials are crucial but face challenges in synthesis. Different routes for synthesizing these materials have been explored, with some successes in WSSC graphene, hBN, and MoS2, while growth of other WSSC 2D materials remains a significant challenge. Opportunities for future research in the synthesis of various wafer scale single crystalline 2D materials have been summarized.

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A crystalline tri-thorium cluster with σ-aromatic metal-metal bonding

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Summary: Actinide-actinide bonding is typically predicted to be weak and difficult to observe under normal conditions, but the experimental discovery of thorium-thorium bonding in a crystalline cluster has revealed a new type of sigma-aromatic bond that challenges previous theoretical predictions. This discovery extends delocalized sigma-aromatic bonding to the heaviest elements in the periodic table and offers a new approach to studying actinide-actinide bonding.

NATURE (2021)

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Constructing covalent organic nanoarchitectures molecule by molecule via scanning probe manipulation

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Summary: Constructing low-dimensional covalent assemblies with tailored size and connectivity is challenging but important in molecular electronics for tuning the properties of quantum materials. A versatile approach has been developed for building such structures block by block on a surface through highly selective tip-induced intermolecular reactions.

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Epitaxial growth of wafer-scale molybdenum disulfide semiconductor single crystals on sapphire

Taotao Li et al.

Summary: This study successfully achieved epitaxial growth of 2-inch monolayer molybdenum disulfide single crystals on a sapphire substrate, breaking through the technical challenges in the field of MoS2. Tests showed that the MoS2 has a single crystal structure with excellent substrate uniformity, and its device performance has reached a high level.

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A Liquid Metal Reaction System for Advanced Material Manufacturing

Mengqi Zeng et al.

Summary: Liquid metal, with unique properties like self-limited growth and good rheological properties, shows great potential in the controllable fabrication of 2D materials and functional composite materials. The research on advanced materials manufacturing on liquid metals is still in its infancy, but offers promising prospects for various applications in energy field and beyond.

ACCOUNTS OF MATERIALS RESEARCH (2021)

Article Multidisciplinary Sciences

Real-time imaging of Na+ reversible intercalation in Janus graphene stacks for battery applications

Jinhua Sun et al.

Summary: The study introduces a novel Janus graphene for sodium ion storage, demonstrating a different mechanism of sodium storage compared to graphite and stacked graphene. Through density functional theory calculations and experimental validation, the synergic ionic bonds formation process between Na+ and graphene is revealed.

SCIENCE ADVANCES (2021)

Review Chemistry, Multidisciplinary

High-entropy energy materials: challenges and new opportunities

Yanjiao Ma et al.

Summary: The essential demand for functional materials enabling the realization of new energy technologies has driven significant efforts in scientific and industrial research. High-entropy materials, with their unique structural characteristics and tunable functional properties, have gained increasing interest in the fields of environmental science and renewable energy technology. Effective strategies for designing high-entropy materials from computational techniques and experimental aspects provide researchers with guidance on potential advantages and remaining challenges.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Article Physics, Multidisciplinary

Nucleic acid-metal complex and its application in atomic-scale manufacturing

Li Sheng-Kai et al.

Summary: This review discusses precise atomic-scale manufacturing technology of nucleic acid materials, including the basic structures and functions of nucleic acid materials, the basic principles of the interaction between DNA and metal atoms, and the development process and breakthrough progress of nucleic acid materials-mediated precise atomic-scale manufacturing.

ACTA PHYSICA SINICA (2021)

Article Chemistry, Multidisciplinary

High-Entropy Layered Oxide Cathodes for Sodium-Ion Batteries

Chenglong Zhao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Review Chemistry, Multidisciplinary

Near-Atomic Fabrication with Nucleic Acids

Kai Xia et al.

ACS NANO (2020)

Article Chemistry, Physical

Bandgap tuning of two-dimensional materials by sphere diameter engineering

Mengqi Zeng et al.

NATURE MATERIALS (2020)

Article Chemistry, Physical

Programming nanoparticle valence bonds with single-stranded DNA encoders

Guangbao Yao et al.

NATURE MATERIALS (2020)

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Distance Synergy of MoS2-Confined Rhodium Atoms for Highly Efficient Hydrogen Evolution

Xiangyu Meng et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Building an Air Stable and Lithium Deposition Regulable Garnet Interface from Moderate-Temperature Conversion Chemistry

Hui Duan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Review Chemistry, Multidisciplinary

Evolution of Dip-Pen Nanolithography (DPN): From Molecular Patterning to Materials Discovery

Guoqiang Liu et al.

CHEMICAL REVIEWS (2020)

Article Multidisciplinary Sciences

Ultrathin high-κ antimony oxide single crystals

Kena Yang et al.

NATURE COMMUNICATIONS (2020)

Article Chemistry, Physical

Building Lithiophilic Ion-Conduction Highways on Garnet-Type Solid-State Li+ Conductors

Zhangyuan Cheng et al.

ADVANCED ENERGY MATERIALS (2020)

Article Multidisciplinary Sciences

Quantum entanglement between an atom and a molecule

Yiheng Lin et al.

NATURE (2020)

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Phase engineering of nanomaterials

Ye Chen et al.

NATURE REVIEWS CHEMISTRY (2020)

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Evaporated SexTe1-xThin Films with Tunable Bandgaps for Short-Wave Infrared Photodetectors

Chaoliang Tan et al.

ADVANCED MATERIALS (2020)

Article Multidisciplinary Sciences

Spatial defects nanoengineering for bipolar conductivity in MoS2

Xiaorui Zheng et al.

NATURE COMMUNICATIONS (2020)

Article Multidisciplinary Sciences

Boosting hydrogen evolution on MoS2 via co-confining selenium in surface and cobalt in inner layer

Zhilong Zheng et al.

NATURE COMMUNICATIONS (2020)

Article Multidisciplinary Sciences

Universal growth of ultra-thin III-V semiconductor single crystals

Yunxu Chen et al.

NATURE COMMUNICATIONS (2020)

Article Chemistry, Multidisciplinary

Phase-Selective Epitaxial Growth of Heterophase Nanostructures on Unconventional 2H-Pd Nanoparticles

Yiyao Ge et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Review Materials Science, Multidisciplinary

Surface Chemistry of Gallium-Based Liquid Metals

Yiran Ding et al.

MATTER (2020)

Review Chemistry, Multidisciplinary

Intermetalloid and Heterometallic Clusters Combining p-Block (Semi)Metals with d- or f-Block Metals

Robert J. Wilson et al.

CHEMICAL REVIEWS (2019)

Article Chemistry, Physical

Disorder in van der Waals heterostructures of 2D materials

Daniel Rhodes et al.

NATURE MATERIALS (2019)

Review Chemistry, Multidisciplinary

Development of Dip-Pen Nanolithography (DPN) and Its Derivatives

Guoqiang Liu et al.

SMALL (2019)

Article Chemistry, Multidisciplinary

Metal-Organic Framework Stabilizes a Low-Coordinate Iridium Complex for Catalytic Methane Borylation

Xuanyu Feng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Review Nanoscience & Nanotechnology

Atom-by-atom fabrication with electron beams

Ondrej Dyck et al.

NATURE REVIEWS MATERIALS (2019)

Review Nanoscience & Nanotechnology

High-entropy alloys

Easo P. George et al.

NATURE REVIEWS MATERIALS (2019)

Article Chemistry, Multidisciplinary

Anionic Dopant Delocalization through p-Band Modulation to Endow Metal Oxides with Enhanced Visible-Light Photoactivity

Xianyin Song et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Disassembly of 2D Vertical Heterostructures

Yao Xiao et al.

ADVANCED MATERIALS (2019)

Article Chemistry, Multidisciplinary

Synergetic interaction between neighboring platinum and ruthenium monomers boosts CO oxidation

Peng Zhou et al.

CHEMICAL SCIENCE (2019)

Article Chemistry, Multidisciplinary

Multi-anionic and -cationic compounds: new high entropy materials for advanced Li-ion batteries

Qingsong Wang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2019)

Article Chemistry, Multidisciplinary

Molecular Scaffold Growth of Two-Dimensional, Strong Interlayer-Bonding-Layered Materials

Mengqi Zeng et al.

CCS CHEMISTRY (2019)

Article Chemistry, Multidisciplinary

Nanocage-Confined Synthesis of Fluorescent Polycyclic Aromatic Hydrocarbons in Zeolite

Seung Hyeon Ko et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Chemistry, Multidisciplinary

Self-Assembled Pd(II) Barrels as Containers for Transient Merocyanine Form and Reverse Thermochromism of Spiropyran

Prodip Howlader et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Multidisciplinary Sciences

A photochemical diode artificial photosynthesis system for unassisted high efficiency overall pure water splitting

Faqrul A. Chowdhury et al.

NATURE COMMUNICATIONS (2018)

Article Chemistry, Physical

Sub-3 nm Ultrafine Monolayer Layered Double Hydroxide Nanosheets for Electrochemical Water Oxidation

Yufei Zhao et al.

ADVANCED ENERGY MATERIALS (2018)

Review Nanoscience & Nanotechnology

Epitaxial growth of hybrid nanostructures

Chaoliang Tan et al.

NATURE REVIEWS MATERIALS (2018)

Article Multidisciplinary Sciences

Atom-hybridization for synthesis of polymetallic clusters

Takamasa Tsukamoto et al.

NATURE COMMUNICATIONS (2018)

Article Chemistry, Multidisciplinary

Growth of 2D GaN Single Crystals on Liquid Metals

Yunxu Chen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Chemistry, Multidisciplinary

Crystal-Field Tuning of Photoluminescence in Two-Dimensional Materials with Embedded Lanthanide Ions

Ding Xu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Review Chemistry, Physical

Characteristics and performance of two-dimensional materials for electrocatalysis

Xinyi Chia et al.

NATURE CATALYSIS (2018)

Article Physics, Multidisciplinary

High-resolution studies of the Majorana atomic chain platform

Benjamin E. Feldman et al.

NATURE PHYSICS (2017)

Article Chemistry, Multidisciplinary

Hexagonal Boron Nitride-Graphene Core-Shell Arrays Formed by Self-Symmetrical Etching Growth

Chenxiao Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

Exploring a Proximity-Coupled Co Chain on Pb(110) as a Possible Majorana Platform

Michael Ruby et al.

NANO LETTERS (2017)

Article Multidisciplinary Sciences

Wafer-scale two-dimensional semiconductors from printed oxide skin of liquid metals

Benjamin J. Carey et al.

NATURE COMMUNICATIONS (2017)

Article Chemistry, Multidisciplinary

In Situ Observation of Oxygen Vacancy Dynamics and Ordering in the Epitaxial LaCoO3 System

Jae Hyuck Jang et al.

ACS NANO (2017)

Review Chemistry, Multidisciplinary

Surface chemistry and catalysis confined under two-dimensional materials

Qiang Fu et al.

CHEMICAL SOCIETY REVIEWS (2017)

Article Nanoscience & Nanotechnology

Reversible trapping and reaction acceleration within dynamically self-assembling nanoflasks

Hui Zhao et al.

NATURE NANOTECHNOLOGY (2016)

Article Chemistry, Multidisciplinary

Isotropic Growth of Graphene toward Smoothing Stitching

Mengqi Zeng et al.

ACS Nano (2016)

Article Chemistry, Multidisciplinary

Self-Assembly of Graphene Single Crystals with Uniform Size and Orientation: The First 2D Super-Ordered Structure

Mengqi Zeng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Article Chemistry, Multidisciplinary

Highly efficient catalysis of the Kemp elimination in the cavity of a cubic coordination cage

William Cullen et al.

NATURE CHEMISTRY (2016)

Article Multidisciplinary Sciences

Twinned growth behaviour of two-dimensional materials

Tao Zhang et al.

NATURE COMMUNICATIONS (2016)

Article Multidisciplinary Sciences

Visible light-driven efficient overall water splitting using p-type metal-nitride nanowire arrays

M. G. Kibria et al.

NATURE COMMUNICATIONS (2015)

Article Chemistry, Multidisciplinary

Sodium Storage Behavior in Natural Graphite using Ether-based Electrolyte Systems

Haegyeom Kim et al.

ADVANCED FUNCTIONAL MATERIALS (2015)

Article Nanoscience & Nanotechnology

Atomic mechanism of the semiconducting-to-metallic phase transition in single-layered MoS2

Yung-Chang Lin et al.

NATURE NANOTECHNOLOGY (2014)

Review Nanoscience & Nanotechnology

Advanced scanning probe lithography

Ricardo Garcia et al.

NATURE NANOTECHNOLOGY (2014)

Article Multidisciplinary Sciences

Exfoliation of layered double hydroxides for enhanced oxygen evolution catalysis

Fang Song et al.

NATURE COMMUNICATIONS (2014)

Article Multidisciplinary Sciences

Tuning the surface Fermi level on p-type gallium nitride nanowires for efficient overall water splitting

M. G. Kibria et al.

NATURE COMMUNICATIONS (2014)

Article Multidisciplinary Sciences

High-mobility graphene on liquid p-block elements by ultra-low-loss CVD growth

Jiao Wang et al.

SCIENTIFIC REPORTS (2013)

Article Chemistry, Multidisciplinary

Single-atom catalysis of CO oxidation using Pt1/FeOx

Botao Qiao et al.

NATURE CHEMISTRY (2011)

Review Chemistry, Multidisciplinary

Crystalline molecular flasks

Yasuhide Inokuma et al.

NATURE CHEMISTRY (2011)

Article Chemistry, Multidisciplinary

Synthesis of a Cross-Linked Branched Polymer Network in the Interior of a Protein Cage

Md Joynal Abedin et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

Article Chemistry, Multidisciplinary

Minimal nucleotide duplex formation in water through enclathration in self-assembled hosts

Tomohisa Sawada et al.

NATURE CHEMISTRY (2009)

Article Chemistry, Multidisciplinary

Size-specific catalytic activity of platinum clusters enhances oxygen reduction reactions

Kimihisa Yamamoto et al.

NATURE CHEMISTRY (2009)

Review Multidisciplinary Sciences

Engineering atomic and molecular nanostructures at surfaces

JV Barth et al.

NATURE (2005)

Article Physics, Applied

Nanomachining carbon nanotubes with ion beams

MS Raghuveer et al.

APPLIED PHYSICS LETTERS (2004)

Article Microscopy

Radiation damage in the TEM and SEM

RF Egerton et al.

MICRON (2004)

Article Multidisciplinary Sciences

Materials science - Nanoscale control of chain polymerization

Y Okawa et al.

NATURE (2001)