Functional Graphdiyne for Emerging Applications: Recent Advances and Future Challenges

Article Chemistry, Physical

Ultrathin graphdiyne oxide-intercalated MXene: A new heterostructure with interfacial synergistic effect for high performance lithium-ion storage

Tao Wang et al.

Summary: The sandwich-like heterostructure formed by graphdiyne oxide and MXene exhibits superior electrochemical performance and is suitable for lithium-ion storage.

ENERGY STORAGE MATERIALS (2023)

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Article Chemistry, Multidisciplinary

A Low-Strain Cathode by sp-Carbon Induced Conversion in Multi-Level Structure of Graphdiyne

Xiaoya Gao et al.

Summary: A multi-level architecture consisting of conformal graphdiyne (GDY) and CuS is designed for Li-free cathode, which efficiently integrates the advantages of GDY and forms new functional heterojunctions. This architecture successfully avoids structural collapse through the layer-by-layer 2D confinement effect, inhibits the shuttling of active components through selective transport, and significantly regulates the phase conversion reaction through the interfacial sp-C-S-Cu hybridization bond. The GDY-based interface strategy greatly improves the reaction dynamics and reversibility, enabling the cathode to deliver a high energy density of 934 Wh kg(-1) and an unattenuated lifespan of 3000 cycles at 1 C.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

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Review Chemistry, Multidisciplinary

Engineering Graphdiyne for Solar Photocatalysis

Jian Li et al.

Summary: This article first summarizes the prospect of graphdiyne (GDY) as a promising photocatalytic material for solar energy conversion, with direct band gap, excellent carrier mobility, and uniform pores. Then, it elaborates on the construction and progress of GDY-based photocatalysts for solar energy conversion, including H2 evolution reaction, CO2 reduction reaction, and N2 reduction reaction. Finally, the challenges and perspectives in developing GDY-based photocatalysts for solar fuel production are discussed.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

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Article Chemistry, Physical

Blue phosphorene/graphdiyne heterostructure as a potential anode for advanced lithium-ion batteries: First-principle investigation

Xiulin Zou et al.

Summary: Blue phosphorene/graphdiyne heterostructure is designed as a potential anode material for Li-ion batteries with excellent mechanical stability, good electrical conductivity, high capacity, and fast Li-ion mobility. The heterostructure exhibits good thermodynamics stability and enhanced elastic stiffness, effectively avoiding electrode cracking and pulverization. The synergistic effect between Blue phosphorene and graphdiyne significantly enhances the binding strength of Li and improves the metallic conductivity for fast electron transport.

APPLIED SURFACE SCIENCE (2023)

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Article Materials Science, Multidisciplinary

Tensile strain as an efficient way to tune transport properties of Graphdiyne/Borophene hetero-bilayers; a first principle investigation

Seifollah Jalili et al.

Summary: The influence of strain on the thermoelectric characteristics of Graphdiyne/Borophene hetero-bilayers was investigated using density functional theory and transport formulations. The maximum strain each hetero-bilayer can withstand was determined based on stress-strain behavior. It was found that strain significantly affects the transport properties and can be used to tune the thermoelectric behavior of the hetero-bilayers.

COMPUTATIONAL MATERIALS SCIENCE (2023)

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Review Energy & Fuels

Review on Electrochemical Reduction of Nitrogen by Graphdiyne- Based Catalysts: Recent Advances and Outlook

Junhui Hu et al.

Summary: The current industrial ammonia synthesis heavily relies on the energy-intensive Haber-Bosch process, which leads to significant greenhouse gas emissions. The electrochemical nitrogen reduction reaction (NRR) provides a green and sustainable alternative, but its efficiency has been limited by slow reactivity. Recent advancements in catalyst engineering and electrolyzer development have offered opportunities to improve the performance of the electrochemical NRR. This review focuses on the graphdiyne-based nitrogen reduction electrocatalysts and provides an overview of the electrochemical NRR fundamentals.

ENERGY & FUELS (2023)

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Article Chemistry, Physical

Electrodeposition synthesis of reduced graphdiyne oxide/NiCo2S4 hierarchical nanosheet arrays for small size and light weight aqueous asymmetry supercapacitors

Hongbo Zhang et al.

Summary: In this study, reduced graphdiyne oxide/NiCo2S4 hierarchical nanosheet array (r-GDYO/NiCo2S4) electrodes with high capacity, rate, and stability were successfully synthesized. The r-GDYO/NiCo2S4 electrode exhibited an area-specific capacity of 3.09 F cm-2 at 30 mA cm-2 and a capacitance retention rate of 93.10% after 5000 cycles. Density functional theory revealed that graphdiyne enhanced the pseudocapacitance of NiCo2S4 electrode through promoting binding with hydroxyl ions and increasing surface reactivity. A small volume and lightweight aqueous asymmetric supercapacitor was constructed using r-GDYO/NiCo2S4 as the positive electrode, activated carbon as the negative electrode, and a melamine foam membrane as the electrolyte container. This work provides insights for the design of high-performance NiCo2S4 electrode materials and expands the application of supercapacitors.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

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Article Engineering, Environmental

Graphdiyne oxide elicits a minor foreign-body response and generates quantum dots due to fast degradation

Lizhen Wang et al.

Summary: Graphdiyne (GDY) is a novel 2D carbon allotrope with excellent properties, attracting attention in various fields. Studies have explored its biomedical applications, but few have focused on its biocompatibility and potential environmental hazards. This study compared the cytotoxicity and biocompatibility of graphdiyne oxide (GDYO) and graphene oxide (GO), and found that GDYO had low biotoxicity in vitro and moderate biocompatibility in vivo. Highly oxidized products and graphdiyne quantum dots (GDQDs) were observed in peritoneal cells. GDYO showed better biocompatibility and its sheet size could easily be diminished through oxidative degradation, making it a promising candidate in biomedicine.

JOURNAL OF HAZARDOUS MATERIALS (2023)

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Article Materials Science, Multidisciplinary

Loaded Cu-Er metal iso-atoms on graphdiyne for artificial photosynthesis

Chao Zhang et al.

Summary: We report a bimetal atomic catalyst of CuEr-GDY featuring atomically dispersed Cu and Er atoms on crystalline graphdiyne for converting CO2 into sustainable fuel. The CuEr-GDY can efficiently separate electron-hole pairs for water oxidation and CO2 activation/reduction, as well as promote CO2/H2O adsorption and CO desorption. This heteroatomic catalyst exhibits high catalytic activity with a reaction selectivity of 97.6% and suppressed competitive hydrogen evolution reaction, achieving a CO yield of 181.04 lmol g-1 h-1 under ambient conditions.

MATERIALS TODAY (2023)

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Article Chemistry, Analytical

Electrochemical determination of benomyl using MWCNTs interspersed graphdiyne as enhanced electrocatalyst

Min Shi et al.

Summary: Graphdiyne (GDY) has been widely applied in electrochemical sensing due to its large conjugation system, porous structure, and high structure defects. In this study, conductive MWCNTs were added to enhance the sensing effect of GDY. By using polydopamine (PDA) as a connecting bridge, a stable composite material GDY@PDA/MWCNTs-NH2 was formed and used as an electrochemical sensor for benomyl (Ben) detection. The sensor exhibited a wide linear range, low detection limit, high stability, repeatability, reproducibility, and selectivity, making it suitable for detecting Ben in apple and cucumber samples.

MICROCHIMICA ACTA (2023)

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Article Multidisciplinary Sciences

Multi-heterointerfaces for selective and efficient urea production

Danyan Zhang et al.

Summary: A multiple heterogeneous interface with unique incomplete charge transfer was constructed by growing graphdiyne on cobalt-nickel mixed oxides surface, enabling high-performance urea production at room temperature and pressure. The catalyst system exhibits outstanding performance in selectively synthesizing urea directly from nitrite and carbon dioxide, with a record-high Faradaic efficiency, nitrogen and carbon selectivity, as well as remarkable long-term stability.

NATIONAL SCIENCE REVIEW (2023)

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Review Chemistry, Multidisciplinary

Recent Progress in Interface Engineering of Nanostructures for Photoelectrochemical Energy Harvesting Applications

You Zi et al.

Summary: With the rapid consumption of nonrenewable energy, solar energy is considered to be a promising solution to meet future energy requirements and mitigate environmental issues. The photoelectrochemical (PEC) device, which utilizes semiconductor nanostructure-based photocatalysts, is believed to be an energy-efficient and environmentally friendly way to utilize solar energy. This review provides a comprehensive summary of the recent progress in interface engineering of semiconductor nanostructures for PEC applications, as well as the challenges and future directions in the field of next-generation PEC devices.

SMALL (2023)

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Article Materials Science, Multidisciplinary

Graphdiyne (C n H2n-2) based S-scheme heterojunction to promote carrier transfer for efficiently photocatalytic hydrogen evolution

Zhiliang Jin et al.

Summary: In this study, a GDY/CuMoO4 (CMO)/CuO tandem S-scheme heterojunction was constructed using the cross-coupling method. The GDY was easily collected with the help of CuI as a coupling catalyst and precursor for more active composite catalysts. The highly conjugated system and excellent electrical conductivity of 2D GDY provided a unique system with strong charge distribution and transport, resulting in stronger reducing activity and carrier transfer capability in the constructed S-scheme heterojunctions. The intrinsic charge transfer mechanism of the catalyst was investigated, and a proposed mechanism for the photocatalytic hydrogen production reaction was proposed.

2D MATERIALS (2023)

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Article Multidisciplinary Sciences

Ir0/graphdiyne atomic interface for selective epoxidation

Zhiqiang Zheng et al.

Summary: A new type of zerovalent atom catalysts comprised of zerovalent Ir atoms highly dispersed and anchored on graphdiyne (Ir-0/GDY) is developed. The catalyst can selectively and efficiently produce styrene oxides (SO) by electro-oxidizing styrene (ST) in aqueous solutions at ambient conditions. The incomplete charge transfer between Ir-0 and GDY plays a crucial role in enhancing the electron exchange and achieving the selective epoxidation of ST to SO.

NATIONAL SCIENCE REVIEW (2023)

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Article Chemistry, Multidisciplinary

Rapid and Reversible Sensing Performance of Hydrogen-Substituted Graphdiyne

Yoon Tae Nam et al.

Summary: The design of new nanomaterials for rapid and reversible detection of molecules in existence is crucial for real-world sensing applications. A hydrogen-substituted graphdiyne (HsGDY), which possesses reactive sp carbons in acetylenic linkages throughout nanopores, shows exceptional sensitivity (Delta R/Rb = 542%) and fast response/recovery time (tau 90 = 8 s and tau 10 = 38 s) in detecting target molecules without postmodification. It offers two orders of magnitude higher sensing ability than existing nanomaterial libraries, attributed to the cooperative interaction with adjacent double sp carbon in its layered nanoporous structure.

ACS SENSORS (2023)

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Article Chemistry, Multidisciplinary

Yolk-Shell Sb@Void@Graphdiyne Nanoboxes for High-Rate and Long Cycle Life Sodium-Ion Batteries

Yan Liu et al.

Summary: Antimony (Sb) is encapsulated into a carbon matrix to mitigate volume expansion during cycling in sodium-ion batteries. A yolk-shell Sb@Void@graphdiyne (GDY) nanobox with three-dimensional Na+ transport channels is synthesized, enabling fast Na+ diffusion. The Sb@Void@GDY nanobox exhibits excellent rate capability and cycling stability.

ACS NANO (2023)

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Article Chemistry, Multidisciplinary

Gradient Graphdiyne Induced Copper and Oxygen Vacancies in Cu0.95V2O5 Anodes for Fast-Charging Lithium-Ion Batteries

Fan Wang et al.

Summary: A Cu/O-dual-vacancies abundant Cu0.95V2O5@GDY heterostructure material is prepared, in which the Cu0.95V2O5 self-catalyzes the growth of gradient GDY and induces the formation of Cu and O vacancies. The synergistic effect of vacancies and gradient GDY enhances the Li-ion transport kinetics and electrochemical reaction reversibility of Cu0.95V2O5, leading to excellent fast-charging performance with high capacities and negligible capacity decay for thousands of cycles at extremely high current densities. Over 30% of capacity can be delivered in 35 seconds.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

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Review Chemistry, Multidisciplinary

Graphdiyne-Based Single-Atom Catalysts with Different Coordination Environments

Xinliang Fu et al.

Summary: As a special carbon material, graphdiyne (GDY) provides an ideal platform for constructing single-atom catalysts (ACs) due to its incomplete charge transfer effect, tunable electronic structure, and ability to anchor metal atoms directly. This mini-review highlights recent progress in the rational design and application of GDY-based ACs, and examines the relationship between coordination engineering of these catalysts and their catalytic performance. Prospects for the future development of GDY-based ACs in energy conversion are also discussed.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

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Article Chemistry, Multidisciplinary

Graphdiyne nanoplatforms for photothermal-ferroptosis combination therapy against glioblastoma

Ling-Xiao Zhao et al.

Summary: Glioblastoma, a highly malignant tumor, can be treated by inducing ferroptosis using graphdiyne-based nanoplatforms. These nanoplatforms can penetrate the blood-brain barrier and release the therapeutic drug in the tumor tissue, leading to inhibition of tumor growth and prolonged survival.

JOURNAL OF CONTROLLED RELEASE (2023)

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Article Nanoscience & Nanotechnology

Metal-Organic Frameworks/Graphdiyne/Copper Foam Composite Membranes for Catalytic Applications

Yanjie Wu et al.

Summary: Graphdiyne (GDY) with a three-dimensional network structure was synthesized on a copper foam (CF) via an in situ Glaser-Hay coupling reaction. A metal-organic framework/GDY composite membrane was designed and synthesized for the first time. The catalytic activities of HKUST-1/GDY/CF membrane in wet peroxide oxidation of phenol, oxidation of benzyl alcohol, and ring opening of epoxide were studied.

ACS APPLIED MATERIALS & INTERFACES (2023)

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Review Chemistry, Multidisciplinary

Two-Dimensional Carbon Graphdiyne: Advances in Fundamental and Application Research

Xuchen Zheng et al.

Summary: Graphdiyne (GDY), a two-dimensional all-carbon network with sp/sp(2)-hybridized structure, has shown great potential for innovation and development in various fields. GDY has attracted extensive attention from scientists due to its controlled growth, chemical and physical properties, and mechanisms that differ from traditional carbon materials. It has become one of the frontiers of chemistry and materials science and has generated numerous research achievements in the fundamental and applied study of carbon materials. The applications of GDY in catalysis, energy storage, photoelectronic, biomedicine, environmental science, life science, detectors, and material separation are comprehensively introduced in this review.

ACS NANO (2023)

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Article Biophysics

Self-powered dual-mode sensing strategy based on graphdiyne and DNA nanoring for sensitive detection of tumor biomarker

Jinyue Shi et al.

Summary: MicroRNA-21 (miRNA-21) is an oncogenic miRNA that is upregulated in almost all malignant tumors and has a broad spectrum of tumor recognition characteristics. A new dual-mode self-powered sensing platform using Au nanoparticles/graphdiyne as the electrode substrate and DNA nanoring for highly sensitive and specific detection of miRNA-21 is developed in this study. This strategy provides a new reference for the sensitive detection of microRNA and has immense potential for application in the screening and detection of clinical nucleic acid diseases.

BIOSENSORS & BIOELECTRONICS (2023)

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Article Engineering, Environmental

Rationally engineered active site over graphdiyne (CnH2n-2) based S-scheme heterojunction for efficient and durable hydrogen production

Cheng Yang et al.

Summary: A strategy of constructing S-scheme heterostructure based on graphdiyne by inducing Co-P bond through high-temperature phosphorylation. The Co-P bond builds the electron bridge at the interface between CuCo2O4 and graphdiyne, inhibiting carrier recombination and weak light absorption. The anchored lamellar structure of graphdiyne on nanospheres increases surface area and serves as an active site for hydrogen evolution.

CHEMICAL ENGINEERING JOURNAL (2023)

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Article Chemistry, Multidisciplinary

Highly Efficient Van Der Waals Heterojunction on Graphdiyne toward the High-Performance Photodetector

Dinh Phuc Do et al.

Summary: Graphdiyne (GDY), a new 2D material, has proven excellent performance in photodetector applications due to its direct bandgap and high mobility. A highly effective GDY/MoS2 type-II heterojunction is reported, which facilitates the effective electron-hole pairs separation and transfer, resulting in significant suppression of Auger recombination. The GDY/MoS2 device exhibits broadband detection and high speed, making it a promising strategy for future optoelectronic applications.

ADVANCED SCIENCE (2023)

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Article Energy & Fuels

One-step firmly anchor graphdiyne on NiCo-LDHs as supercapacitor electrode for considerable durability

Guiquan Liu et al.

Summary: In order to compensate for the poor stability and low conductivity of nickel cobalt hydrotalcite (NiCo-LDHs) in energy storage applications, graphdiyne (GDY) nanosheets were added to the synthesis process. Due to the strong combination of NiCo-LDHs and GDY, the obtained NiCo-LDHs@GDY exhibits a specific capacitance of 1284 F g-1 (1.5 times higher than NiCo-LDHs) at a current density of 1 A g-1, with a rate performance of 72.08% at a current density of 20 A g-1. Furthermore, the NiCo-LDHs@GDY//AC Asymmetric Supercapacitor (ASC) assembled with activated carbon demonstrates an energy density of 23.06 Wh kg-1 at a high power density of 3108.96 W kg 1. Rejoicingly, the charge storage capacity remains at 89.53% after 5200 charge-discharge cycles under a current density of 10 A g-1. These outcomes indicate the remarkable application potential of NiCo-LDHs@GDY electrode material for high-performance supercapacitors in energy storage applications.

JOURNAL OF ENERGY STORAGE (2023)

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Article Materials Science, Multidisciplinary

Controlled growth of a graphdiyne-Prussian blue analog heterostructure for efficient ammonia production

Yaqi Gao et al.

Summary: Selective and efficient ammonia production using an electrocatalytic nitrate reduction reaction (ECNtRR) provides a green and promising alternative to the traditional energy-intensive Haber-Bosch process. In this study, a graphdiyne-hollowed FeCoNi Prussian blue analog electrode with highly selective and active interfaces was synthesized and used for the ECNtRR under ambient conditions. The experimental results showed high selectivity, activity, and stability of the electrocatalyst, with a Faraday efficiency of 95.1% and a NH3 yield rate of 1015.5 μmol h-1 cm-2.

NPG ASIA MATERIALS (2023)

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Article Nanoscience & Nanotechnology

Sandwich-like MXene/α-Fe2O3-C-MoS2-PEDOT:PSS/MXene Film Electrodes with Ultrahigh Area Capacitance for Flexible Supercapacitors

Chenglong Li et al.

Summary: This study significantly increases the area capacitance of MXene films by introducing FMP and designs a reasonable sandwich structure electrode, showing breakthrough performance in high energy density.

ACS APPLIED MATERIALS & INTERFACES (2022)

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Article Chemistry, Multidisciplinary

Graphdiyne/Graphene/Graphdiyne Sandwiched Carbonaceous Anode for Potassium-Ion Batteries

Jiaqiang Li et al.

Summary: In this study, a GDY/Gr/GDY sandwiched architecture was designed to improve the K-ion storage performance. Experimental results showed that the GDY/Gr/GDY electrode exhibited better capacity output and cyclic stability. In situ testing revealed the reversibility of the GDY/Gr/GDY electrode. A full-cell device demonstrated the potential of the GDY/Gr/GDY anode for K-ion batteries.

ACS NANO (2022)

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Article Chemistry, Multidisciplinary

Plasmonic Nanozyme of Graphdiyne Nanowalls Wrapped Hollow Copper Sulfide Nanocubes for Rapid Bacteria-Killing

Qiang Bai et al.

Summary: This study develops a heterojunction composite based on graphdiyne nanowalls wrapped hollow copper sulfide nanocubes, which can enhance enzyme-like activity using localized surface plasmon resonance in the near-infrared region. The nanozyme exhibits rapid, efficient, and broad-spectrum antibacterial activity. This research not only reveals the mechanism of the nanozyme/photocatalysis coupling process, but also provides a new approach for engineering rapid synergistic photothermal and photo-enhanced nanozyme therapy.

ADVANCED FUNCTIONAL MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Oxidase Mimic Graphdiyne for Efficient Superoxide Generation in Wide pH Ranges

Yu Gu et al.

Summary: Efforts have been made to explore techniques and catalysts for efficient O-2(center dot-) generation, and a unique oxidase mimic catalyst design using hemin molecules on graphdiyne has been presented. This catalyst demonstrates high efficiency in producing O-2(center dot-) in wide pH ranges, with the ability to work in acidic, alkaline, and neutral environments. Its oxidase mimic ability has been shown to be promising for various applications, including sensing glutathione molecules in cell assays.

ADVANCED FUNCTIONAL MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Self-Expanding Ion-Transport Channels on Anodes for Fast-Charging Lithium-Ion Batteries

Juan An et al.

Summary: This paper proposes a self-expanding lithium-ion transport channel method to construct a fast-charging anode for high-performance Li-ion batteries. By enabling self-reversible conversion of chemical bonds during cycling, the method reduces the energy barrier of Li-ion transport and allows fast Li-ion diffusion, effectively addressing issues like severe voltage polarization and Li metal plating.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Article Chemistry, Physical

Plasmon-Enhanced Peroxidase-like Activity of Nitrogen-Doped Graphdiyne Oxide Quantum Dots/Gold-Silver Nanocage Heterostructures for Antimicrobial Applications

Zhiling Zhu et al.

Summary: This study reports the synthesis of hollow cube-shaped nitrogen-doped graphdiyne quantum dots loaded onto gold-silver nanocages, which exhibit strong localized surface plasmon resonance in the near-infrared region. The resulting nanozyme shows significantly enhanced peroxidase-like activity upon 808 nm irradiation and achieves high antibacterial efficiency against drug-resistant bacteria.

CHEMISTRY OF MATERIALS (2022)

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Article Chemistry, Physical

High-loading metal atoms on graphdiyne for efficient nitrogen fixation to ammonia

Yan Fang et al.

Summary: This research successfully designed and synthesized a new graphdiyne-based manganese atomic electrocatalyst with high ammonia yield rate and faradaic efficiency, as well as excellent cycling durability, demonstrating superior performance compared to most reported conventional and heterostructured atomic catalysts.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

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Article Materials Science, Multidisciplinary

Second harmonic generation from tetraphenylethylene functionalized graphdiyne

Chao Liu et al.

Summary: This study reports the observation of optical second harmonic from a fully conjugated fluorescent 2D material, tetraphenylethylene-graphdiyne (TPE-GDY), based on sp and sp(2) hybridized carbon atoms. The stability of TPE-GDY is improved by mixing it with polyvinylpyrrolidone (PVP) to prepare TPE-GDY/PVP nanocomposite films. Cotton effect and favorable SHG response have been observed from these composite films, enriching the material system in the field of NLO effects.

2D MATERIALS (2022)

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Article Materials Science, Multidisciplinary

Graphdiyne based GDY/CuI/NiO parallel double S-scheme heterojunction for efficient photocatalytic hydrogen evolution

Zhiliang Jin et al.

Summary: This study constructed a GDY/CuI/NiO heterostructure photocatalytic system and demonstrated its excellent photocatalytic performance and stability. Amorphous GDY provided more active sites for hydrogen evolution, while the construction of heterojunction promoted electron transfer and played a crucial role in enhancing hydrogen production activity.

2D MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Graphdiyne-Induced Iron Vacancy for Efficient Nitrogen Conversion

Yan Fang et al.

Summary: An iron vacancy-rich ferroferric oxide/graphdiyne heterostructure was designed and fabricated for high-efficiency electrocatalytic nitrogen fixation to ammonia. Experimental and theoretical results show promising electrocatalytic performances with high ammonia yield and Faradaic efficiency, as well as long-term stability in neutral electrolytes. The proposed cationic vacancy activation strategy has strong general guiding significance for the design of new efficient electrocatalysts.

ADVANCED SCIENCE (2022)

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Article Chemistry, Multidisciplinary

π-Conjugation Induced Anchoring of Ferrocene on Graphdiyne Enable Shuttle-Free Redox Mediation in Lithium-Oxygen Batteries

Xudong Li et al.

Summary: A novel carbon family of graphdiyne matrix is proposed to decouple the charge-carrying redox property of ferrocene and the shuttle effects, serving as a stationary RM in lithium-oxygen batteries. The ferrocene-anchored graphdiyne framework promotes localized three-dimensional growth of Li2O2, preserving the redox-mediating capability of ferrocene and enhancing electrochemical performance efficiently and stably.

ADVANCED SCIENCE (2022)

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Article Multidisciplinary Sciences

Uniform single atomic Cu1-C4 sites anchored in graphdiyne for hydroxylation of benzene to phenol

Jia Yu et al.

Summary: Cu single atoms anchored on graphdiyne exhibit superior activity and selectivity in direct benzene oxidation to phenol. The uniform Cu-1-C-4 single sites on the graphdiyne support enhance the catalytic performance. This study provides insights into the structure-property relationship of single-atom catalysts and offers guidance for designing efficient catalysts.

NATIONAL SCIENCE REVIEW (2022)

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Article Optics

Four-wave mixing in graphdiyne-microfiber based on synchronized dual-wavelength pulses

Xinxin Jin et al.

Summary: In this study, four-wave mixing (FWM) in graphdiyne (GDY) microfiber is demonstrated using synchronized dual-wavelength pump pulses obtained from a mode-locked fiber laser. The large nonlinear refractive index of GDY and the synchronized pump pulses contribute to a high conversion efficiency, which has potential applications in measuring the nonlinear coefficient gamma of nanomaterials-based devices.

PHOTONICS RESEARCH (2022)

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Article Chemistry, Physical

Graphdiyene enables ultrafine Cu nanoparticles to selectively reduce CO2 to C2+ products

Yong-Bin Chang et al.

Summary: Reducing the size of nanocatalysts can enhance atomic utilization and activities, but small-sized Cu nanoparticles often have overly strong binding of intermediates, limiting CO2 conversion efficiency. The introduction of Pyr-GDY can improve selectivity and stability of ultrafine Cu NPs, leading to significantly higher Faradic efficiency for C2+ products. This study highlights the crucial role of graphdiyne in influencing the selectivity of Cu-catalyzed CO2 electroreduction, showing promise for ultrafine Cu NPs in converting CO2 into valuable C2+ products.

NANO RESEARCH (2022)

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Article Biophysics

Graphdiyne nanosheet as a novel sensing platform for self-enhanced electrochemiluminescence of MOF enriched ruthenium (II) in the presence of dual co-reactants for detection of tumor marker

Delnia Bahari et al.

Summary: Graphdiyne (GDY) is a new two-dimensional carbon material introduced as a novel electrochemiluminescent sensing platform, in combination with metal organic frameworks and other materials for enrichment of luminophores, forming an efficient ECL platform with excellent signal response.

BIOSENSORS & BIOELECTRONICS (2022)

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Article Nanoscience & Nanotechnology

Controlled Growth of 3D Interpenetrated Networks by NiCo2O4 and Graphdiyne for High-Performance Supercapacitor

Xiangang Zhai et al.

Summary: In this paper, a two-dimensional all-carbon graphdiyne material is used to protect multidimensional nickel cobalt oxide nanostructures, leading to significant improvement in conductivity and structural stability. The assembled hybrid supercapacitor demonstrates high specific capacitance, energy density, and power density, as well as excellent rate capability and long-term cycling performance.

ACS APPLIED MATERIALS & INTERFACES (2022)

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Article Chemistry, Multidisciplinary

Hierarchical Nanocapsules of Cu-Doped MoS2@H-Substituted Graphdiyne for Magnesium Storage

Sifei Zhuo et al.

Summary: Hierarchical nanocapsules containing Cu-doped MoS2 nanopetals enclosed in carbonaceous nanotubes have been developed for rechargeable magnesium batteries. These nanocapsules exhibit excellent energy storage performance and efficient electron/ion transfer channels.

ACS NANO (2022)

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Article Chemistry, Multidisciplinary

Low-Valence Metal Single Atoms on Graphdiyne Promotes Electrochemical Nitrogen Reduction via M-to-N2 π-Backdonation

Haiyuan Zou et al.

Summary: The M-to-N-2 π-backdonation weakens the triple bond of N-2 and promotes the sluggish electrochemical nitrogen reduction reaction (ENRR). By using graphdiyne as a supporting material, low-valence metal single atoms (SA) can be stabilized. Re SA/GDY exhibits the highest activity and requires the lowest energy for the reductive hydrogenation of *N-2 during the ENRR process. Additionally, NH3 desorption from Re SA/GDY can be facilitated through a novel ligand exchange mechanism aided by N-2 or H2O.

ADVANCED FUNCTIONAL MATERIALS (2022)

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Review Chemistry, Multidisciplinary

Carbon-based single atom catalyst: Synthesis, characterization, DFT calculations

Yanan Shang et al.

Summary: This review discusses the preparation strategies of carbon-based single-atom catalysts (SACs), summarizes the recent advancements in characterization techniques and computational achievements for understanding the electronic and geometric characteristics of carbon-based SACs, and discusses the challenges and future directions in single-atom site identification and advanced tool development.

CHINESE CHEMICAL LETTERS (2022)

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Article Biophysics

Ultrathin graphdiyne nanosheets confining Cu quantum dots as robust electrocatalyst for biosensing featuring remarkably enhanced activity and stability

Kai Niu et al.

Summary: In this study, a Cu@GDY nanocomposite was synthesized and used to fabricate an AChE biosensor for rapid detection of organophosphorus pesticides. The Cu@GDY nanocomposite exhibited excellent catalytic activity and the ability to regulate enzyme inhibition kinetics, resulting in amplified electrochemical signal and reduced oxidation potential for the pesticides. The biosensor achieved sensitive detection with high reproducibility and stability.

BIOSENSORS & BIOELECTRONICS (2022)

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Article Engineering, Environmental

High efficiently piezocatalysis degradation of tetracycline by few-layered MoS2/GDY: Mechanism and toxicity evaluation

Bingjie Huo et al.

Summary: A new strategy for the degradation of tetracycline in water using doped MoS2 and graphdiyne was proposed, which showed excellent catalytic activity and stability. By analyzing the intermediate products, the possible degradation path and mechanism were proposed. This work provides a new approach for enhancing the piezocatalytic performance of MoS2 and effectively degrading tetracycline in water.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

In-situ synthesis of graphdiyne on Mn3O4 nanoparticles for efficient Zn ions diffusion and storage

Quanhu Sun et al.

Summary: This study reports an in-situ chemical synthesis method to prepare Mn3O4-GDY composite material as an electrode material for zinc-ion batteries. The as-prepared composite material shows unique structural and chemical properties, which can improve the cyclic stability and capacity decay issues in batteries. Electrochemical characterization results demonstrate that Mn3O4-GDY material exhibits high reversible capacity and good cycling performance.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Chemistry, Multidisciplinary

Bismuth/Graphdiyne Heterostructure for Electrocatalytic Conversion of CO2 to Formate

Du Yuncheng et al.

Summary: In this study, a Bismuth nanoflower/graphdiyne heterostructure electrocatalyst was developed for efficient CO2 conversion to formate. The obtained electrocatalyst exhibited high partial current density, selectivity, Faradic efficiency, and energy efficiency, and maintained high formate yield rates over a wide potential range. Detailed characterizations revealed that the unique interface structures between GDY and Bi enhanced charge transfer ability, increased active sites, and improved long-term stability.

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES (2022)

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Article Chemistry, Physical

Boron doped graphdiyne: A metal-free peroxidase mimetic nanozyme for antibacterial application

Xuelong Bi et al.

Summary: The abuse of conventional antibiotics leads to bacterial resistance, while nanozymes and boron doped GDY nanosheets show great potential as next generation nanobactericides, effectively killing various bacteria with excellent biocompatibility.

NANO RESEARCH (2022)

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Article Chemistry, Physical

Graphdiyne oxide doping for aggregation control of hole-transport nanolayer in inverted perovskite solar cells

Xu Cai et al.

Summary: The study demonstrates that doping graphdiyne oxide into P3CT-K nanocomposites can effectively enhance the performance of inverted perovskite solar cells, by controlling the aggregation and improving both device performance and crystal quality.

NANO RESEARCH (2022)

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Review Chemistry, Physical

Graphdiyne-supported metal electrocatalysts: From nanoparticles and cluster to single atoms

Tiantian Lu et al.

Summary: This review systematically summarizes the synthesis of size-controlled metal catalysts anchored on graphdiyne (GDY) and their applications in energy-related electrocatalysis. GDY, as a two-dimensional carbon allotrope, possesses uniformly distributed pores, high electrical conductivity, and good stability, making it an ideal matrix for supporting metal catalysts. The review discusses the effect of support-metal interaction on electrocatalytic performance and highlights the potential applications of GDY-supported metal catalysts in various electrocatalytic reactions.

NANO RESEARCH (2022)

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Article Chemistry, Multidisciplinary

Piezoelectric enhanced peroxidase-like activity of metal-free sulfur doped graphdiyne nanosheets for efficient water pollutant degradation and bacterial disinfection

Jiancheng Zhang et al.

Summary: This study synthesized sulfur-doped graphdiyne nanosheets and demonstrated their impressive peroxidase-like activities and piezoelectric properties. Kinetic investigations and DFT calculations revealed the mechanism of piezoelectric effect on promoting peroxidase-like activity. The results showed the great potential of sulfur-doped graphdiyne in applications, especially in wastewater treatment.

NANO TODAY (2022)

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Article Chemistry, Physical

Electrochemically induced amorphous-to-rock-salt phase transformation in niobium oxide electrode for Li-ion batteries

Pete Barnes et al.

Summary: A nanostructured rock-salt Nb2O5 electrode formed through amorphous-to-crystalline transformation during cycling with Li+ exhibits superb cycling stability and high capacity at high rates.

NATURE MATERIALS (2022)

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Article Materials Science, Multidisciplinary

Tunable Nonlinearity in 2D Graphdiyne Oxide for High-Performance All-Optical Modulation

Leiming Wu et al.

Summary: In this study, 2D graphdiyne oxide nanosheets were synthesized and their nonlinear modulation performance was investigated. The results showed that 2D graphdiyne oxide exhibited tunable nonlinearity and high stability, making it an ideal material for designing low-power loss devices in all-optical modulation systems. With the use of 2D graphdiyne oxide nanosheets, a modulation depth of over 98% was achieved at low pump light power, surpassing most currently reported all-optical modulators. Therefore, graphdiyne oxide is a promising modulation material for all-optical devices.

ADVANCED OPTICAL MATERIALS (2022)

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Article Materials Science, Multidisciplinary

Large-scale CuS nanotube arrays@graphdiyne for high-performance sodium ion battery

Xiangang Zhai et al.

Summary: Copper sulfide (CuS) has been identified as a promising electrode material for Na-ion batteries due to its high theoretical specific capacity, environmentally friendly nature, and abundance. However, the conversion type mechanism used for storing Na+ in CuS electrodes leads to issues such as volume variations and irreversible phase changes, resulting in capacity degradation and sluggish reaction kinetics. In this study, a large-scale free-standing CuS nanotube array protected by a graphdiyne (GDY) nanofilm was successfully prepared. The GDY nanofilm provided in-situ protection, enhancing the structural stability and network conductivity of the CuS electrode. The CuS electrode protected by GDY exhibited excellent electrochemical sodium storage capability, showing long-term reversibility and good rate performance.

2D MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Application of graphdiyne oxide in photoelectrochemical-type photodetectors and ultrafast fiber lasers

Ye Zhang et al.

Summary: This study demonstrates the potential applications of GDYO in PDs and mode-lockers, utilizing its excellent nonlinear optical absorption properties, providing new pathways for the development of high-performance optoelectronic devices in the future.

NANO TODAY (2022)

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Review Chemistry, Multidisciplinary

Functional MXene-Based Materials for Next-Generation Rechargeable Batteries

Chao Zheng et al.

Summary: This review examines the applications of MXenes and their derivatives in the field of energy, and discusses the methods of functionalization and structural engineering. These approaches can improve the performance and cycle life of battery materials, and provide directions for the development of next-generation high-power and low-cost batteries.

ADVANCED MATERIALS (2022)

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Article Materials Science, Multidisciplinary

Graphdiyne@MoS2/WS2 heterostructures for infrared and visible photodetectors: A first-principles study

Chuyu Li et al.

Summary: This study systematically investigated the performance of graphdiyne@MoS2/WS2 heterojunction and found that it exhibits enhanced performance in the short-wavelength infrared regime due to its smaller bandgap and the tunability of the perpendicular electric field.

COMPUTATIONAL MATERIALS SCIENCE (2022)

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Article Chemistry, Multidisciplinary

Graphdiyne oxide nanosheets reprogram immunosuppressive macrophage for cancer immunotherapy

Mengyu Guo et al.

Summary: Graphdiyne oxide (GDYO) nanosheets exhibit excellent properties and have the potential to be used in biomedical applications. In this study, it was found that M2-like macrophages could kill cancer cells with GDYO treatment by activating pro-inflammatory pathways. Intraperitoneal injection of GDYO also reduced tumor growth in a melanoma-bearing mouse model. Additionally, GDYO activated cytotoxic T cells directly or indirectly through macrophages, enhancing the response to checkpoint inhibitors in a breast cancer model. GDYO has the potential to enhance the efficacy of cancer immunotherapy by activating both the innate and adaptive arms of the immune system.

NANO TODAY (2022)

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Article Chemistry, Analytical

Graphdiyne-Templated Platinum Nanoparticles as a Novel Platform for the Electrochemical Determination of Bisphenol AF

Yu Zhang et al.

Summary: This work presents the construction of an ultrasensitive electrochemical bisphenol AF (BPAF) sensor using stable graphdiyne-templated platinum nanoparticles (PtNPs@GDY) as a sensing platform. The sensors exhibited excellent catalytic activities towards BPAF with linear ranges of 0.4 to 15.4 μM and 35.4 to 775.4 μM, and a detection limit of 0.09 μM. Furthermore, they demonstrated good reproducibility, stability, and anti-interference properties.

CHEMOSENSORS (2022)

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Article Chemistry, Multidisciplinary

Photoelectrochemical sensor based on carboxylated graphdiyne co-sensitized TiO2 for sensitive detection of dopamine

Y. Z. Xie et al.

Summary: Graphdiyne (GDY), as a new type of carbon material, shows great potential in the fields of photocatalysts and photoelectrochemical detection due to its suitable energy bandwidth and high electronic conductivity. However, the highly conjugated and stable macrocyclic structure of GDY makes it challenging to isomerize and modify on other materials. In this study, click chemistry was used to successfully carboxylate GDY, enabling stable combination with optoelectronic materials and small biological molecules through chemical bonds. A composite optoelectronic material of carboxylated GDY and TiO2 was synthesized and applied in photoelectrochemical detection, resulting in a stable and sensitive dopamine sensor. By utilizing a multiple signal amplification strategy, a wide linear detection range and a low detection limit were achieved.

MATERIALS TODAY CHEMISTRY (2022)

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Article Chemistry, Physical

Flexible modulations on selectivity of syngas formation via CO2 reduction on atomic catalysts

Mingzi Sun et al.

Summary: This study systematically investigates syngas formation on graphene-based single atomic catalysts, finding that these catalysts can flexibly control the ratio of CO and H2 in syngas. Machine learning results indicate that accurate prediction of selectivity requires a comprehensive understanding of thermodynamic preference and electronic structures.

NANO ENERGY (2022)

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Article Chemistry, Physical

Effect of particle size on thermodynamics and lithium ion transport in electrodes made of Ti2Nb2O9 microparticles or nanoparticles

Yucheng Zhou et al.

Summary: This study compares the performance of lithium-ion battery electrodes made of Ti2Nb2O9 microparticles or nanoparticles synthesized by different methods. The results show that nanoparticles exhibit larger capacity, smaller polarization, better capacity retention, and faster lithium ion transport. Additionally, nanoparticles have smaller overpotential, lower resistive losses, and higher electrical conductivity.

ENERGY STORAGE MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Graphdiyne-Based Nanofilms for Compliant On-Skin Sensing

Yichen Cai et al.

Summary: This study presents the design of a flexible conductive hydrogen-substituted graphdiyne nanofilm for the fabrication of on-skin sensors with high sensitivity and fast response. These sensors can monitor human body movements and health conditions in real-time, providing a new approach for the design of next-generation wearable organic bioelectronics.

ACS NANO (2022)

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Article Chemistry, Analytical

Ultrathin Graphdiyne/Graphene Heterostructure as a Robust Electrochemical Sensing Platform

Xiuchao Sun et al.

Summary: In this study, a two-dimensional ultrathin GDY/graphene nanostructure was utilized as an electrode material for electrochemical sensing. The graphene acted as a template for the growth of few-layered GDY and conductive layers. The GDY/G modified with hemin enzyme mimic showed excellent detection performance and demonstrated the feasibility of this electrochemical sensor as a wearable biosensor.

ANALYTICAL CHEMISTRY (2022)

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Article Chemistry, Analytical

AuNPs and graphdiyne nanocomposite as robust electrocatalyst for methyl parathion detection in real samples

Zhi Xia et al.

Summary: This research describes a simple and rapid synthesis method for gold nanoparticles and graphdiyne nanocomposites with a porous structure. The synthesized material was used to construct a non-enzymatic electrochemical pesticide sensor, which exhibited excellent electrocatalytic ability and low detection limits.

ANALYTICAL SCIENCES (2022)

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Review Environmental Sciences

Graphdiyne applications in sensors: A bibliometric analysis and literature review

Xiaolong Li et al.

Summary: This article summarizes the research on graphdiyne in the sensing field through literature review and bibliometric analysis. Graphdiyne shows potential in gas sensing and electrochemical sensing, and has applications in DNA sequencing and fluorescent sensors. However, current research results do not indicate that graphdiyne has irreplaceable advantages in sensing, and further exploration is needed.

CHEMOSPHERE (2022)

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Article Chemistry, Analytical

Enzyme free electrochemical determination of bisphenol A using screen-printed electrode modified by graphdiyne and carbon nanotubes

Shuai He et al.

Summary: Graphdiyne (GDY) was synthesized and blended with carboxylated multi-walled carbon nanotubes (cMWCNTs) for the first time to modify a screen-printed electrode (SPE). The modified electrode showed excellent performance for the determination of bisphenol A (BPA), with a significant reduction in oxidation peak potential and enhancement of peak current. The optimized conditions for BPA detection were determined, and the sensor was successfully applied for BPA measurement in lake water and tissue samples.

MICROCHEMICAL JOURNAL (2022)

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Article Chemistry, Multidisciplinary

Graphdiyne oxide nanosheets exert anti-lymphoma effect by killing cancer stem cells and remodeling tumor microenvironment

Jinxin Li et al.

Summary: Inflammatory and immunosuppressive tumor microenvironment (TME) plays a role in lymphoma initiation and progression, but Graphdiyne oxide (GDYO) nanosheets can restrain tumor inflammation, remodel TME, and suppress tumor growth. GDYO exerts duplex anti-lymphoma effects by simultaneously killing cancer stem cells and remodeling the lymphoma TME.

NANO TODAY (2022)

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Article Chemistry, Multidisciplinary

Rational Construction of Z-Scheme Charge Transfer Based on 2D Graphdiyne (g-CnH2n-2) Coupling with Amorphous Co3O4 Quantum Dots for Efficient Photocatalytic Hydrogen Generation

Dingzhou Xiang et al.

Summary: In this study, a novel Co3O4 quantum dots/2D graphdiyne Z-scheme heterojunction was fabricated and its application in photocatalytic hydrogen generation was investigated. The Z-scheme heterojunction exhibited high hydrogen generation rate and quantum efficiency, attributed to its unique structure and the size effect of the quantum dots.

ADVANCED MATERIALS INTERFACES (2022)

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Article Chemistry, Multidisciplinary

Cobalt(III) corrole-tethered semiconducting graphdiyne film for efficient electrocatalysis of oxygen reduction reaction

J. Zeng et al.

Summary: In this study, a new method was reported to prepare a highly efficient catalytic material by covalently linking cobalt(III) corrole and cobalt(II) porphyrin onto a semiconducting fluoro-graphdiyne film. The material exhibited excellent performance in oxygen reduction reaction and zinc-air battery, outperforming commercial Pt/C.

MATERIALS TODAY CHEMISTRY (2022)

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Article Engineering, Environmental

MXene/Graphdiyne nanotube composite films for Free-Standing and flexible Solid-State supercapacitor

Yongbin Wang et al.

Summary: In this study, a MXene/graphdiyne nanotube (MG) composite film was constructed to address the restacking issue of MXene. This composite film showed improved capacitance and rate capability, leading to the development of a high-performance flexible supercapacitor.

CHEMICAL ENGINEERING JOURNAL (2022)

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Review Engineering, Environmental

Recent advances in two-dimensional graphdiyne for nanophotonic applications

Yi Hu et al.

Summary: Graphdiyne (GDY) is an emerging carbon allotrope with various potential applications. It possesses excellent properties such as environmental friendliness, high chemical stability, large specific surface area, narrow band gap, and high carrier mobility. The interaction between 2D GDY nanosheets and photons has shown great potential in nanophotonic devices. This review provides an in-depth understanding of the relationship between 2D GDY and photons and aims to inspire the development of functional GDY-based nanophotonic devices.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

A high-performance nano-Sn/G@C composite anode prepared by waste carbon residue from spent Lithium-ion batteries

Xiangdong Zhu et al.

Summary: The high-value utilization of waste carbon residue (WCR) from spent lithium-ion batteries (LIBs) is of great significance in terms of environmental protection and economic growth. In this study, a nano-SnO2/Graphite (nano-SnO2/G) precursor is synthesized and used to remove impurities from the WCR. A high-performance nano-Sn/G@C composite anode with a sandwich structure is prepared, demonstrating excellent cycling performance and reversible specific capacity.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Chemistry, Multidisciplinary

In situ construction of 1D/2D ZnO/graphdiyne oxide heterostructures for enhanced photocatalytic reduction in a gas phase

Jiangting Zhao et al.

Summary: In this study, a 1D/2D ZnO nanofiber/graphdiyne oxide heterojunction was designed as a photocatalyst for CO2 reduction. The difference between graphdiyne and graphdiyne oxide as co-catalysts was investigated. It was found that graphdiyne oxide had better abilities in adsorbing CO2 and enhancing light absorption compared to graphdiyne, resulting in higher CO yield in the photocatalytic reduction of CO2.

MATERIALS CHEMISTRY FRONTIERS (2022)

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Article Chemistry, Multidisciplinary

High energy density primary cathode with a mixed electron/ion interface

Jingchi Gao et al.

Summary: An effective two-dimensional encapsulation strategy was used to prepare a high-performance fluorinated carbon cathode. The obtained cathode showed outstanding charge transport kinetics, lithium-ion diffusion dynamics, and improved voltage platform, battery rate performance, and energy density.

MATERIALS HORIZONS (2022)

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Article Chemistry, Multidisciplinary

Phosphorus-modified two-dimensional graphdiyne (CnH2n-2)/ZnCdS forms S-scheme heterojunctions for photocatalytic hydrogen production

Yanan Liu et al.

Summary: This study improves the hydrogen evolution activity by constructing a phosphorus-doped graphdiyne/zinc-cadmium sulfide heterojunction photocatalyst. The graphite alkyne material serves as a substrate to anchor the bimetallic sulfide-zinc-cadmium sulfide, resulting in a close contact 2D/0D heterojunction interface.

NANOSCALE (2022)

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Review Nanoscience & Nanotechnology

Nanoengineering of Tin Monosulfide (SnS)-Based Structures for Emerging Applications

You Zi et al.

Summary: Tin monosulfide (SnS), a black phosphorus analogues, has attracted significant attention due to its unique properties, such as low cost, environmental compatibility, nontoxicity, and earth-abundance, making it an ideal candidate for modern devices. The controllable synthesis of SnS-based nanostructures with various crystal phases, sizes, and compositions holds great potential for high-performance devices. Recent research and progress on SnS-based nanostructures, including different dimensions and loaded models, are comprehensively discussed, focusing on their synthetic approaches, fundamental properties, and applications in batteries, solar cells, catalysis, optoelectronics, sensors, ferroelectrics, thermoelectrics, nonlinear properties, and biomedical applications. Challenges and perspectives for further improvement of SnS-based nanostructures in these fields are also highlighted.

SMALL SCIENCE (2022)

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Review Chemistry, Multidisciplinary

2D graphdiyne: an emerging carbon material

Yan Fang et al.

Summary: Graphdiyne (GDY), as a new member of carbon allotropes, possesses unique chemical and electronic structures and has found applications in energy, catalysis, environmental science, and electronic devices. It has been recognized for its scientific value and development potential.

CHEMICAL SOCIETY REVIEWS (2022)

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Article Engineering, Environmental

Triazine-graphdiyne with well-defined two kinds of active sites for simultaneous detection of Pb2+ and Cd2+

Xihong Guo et al.

Summary: Graphdiyne-based materials show great potential for adsorption and detection of heavy metal ions due to strong interactions between acetylenic links in graphdiyne and some metal ions. The introduction of N atoms in graphdiyne greatly improves the electrochemical performance, and the signal intensity is closely related to the number of detection sites. The TGDY-based electrochemical sensor demonstrates satisfactory selectivity, reproducibility, stability, and applicability for detecting Cd2+ and Pb2+ in water.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2022)

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Article Chemistry, Multidisciplinary

Solvent induced enhancement of nonlinear optical response of graphdiyne

Yuze Dong et al.

Summary: The study experimentally probed the third-order nonlinear optical response of graphdiyne (GD) dispersed in different alcohols using a femtosecond Z-scan technique. Results showed that the strongest NLO response was observed when GD was dispersed in 1-propanol, indicating that solvent properties such as polarity and viscosity could influence GD materials' NLO response.

CHINESE CHEMICAL LETTERS (2021)

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Article Nanoscience & Nanotechnology

Density Functional Theory Study of a Graphdiyne-Supported Single Au Atom Catalyst for Highly Efficient Acetylene Hydrochlorination

Sajjad Ali et al.

Summary: This study investigated the efficiency of supported single Au on graphdiyne as a catalyst for acetylene hydrochlorination, revealing its superior performance compared to catalysts supported on pristine graphene and single-walled carbon nanotubes. By examining different reaction mechanisms, the study elucidated the reaction pathways and demonstrated the potential of single-atom catalysis on novel support materials.

ACS APPLIED NANO MATERIALS (2021)

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Article Multidisciplinary Sciences

Graphdiyne-based metal atomic catalysts for synthesizing ammonia

Huidi Yu et al.

Summary: Researchers have successfully synthesized a novel catalyst Pd-GDY, showing excellent electrocatalytic performance in nitrogen reduction with high yield and selectivity. The catalyst exhibits extremely high NH3 yield and reaction selectivity in neutral media, with minimal performance degradation.

NATIONAL SCIENCE REVIEW (2021)

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Article Nanoscience & Nanotechnology

Interconnected MoS2 on 2D Graphdiyne for Reversible Sodium Storage

Jing Xu et al.

Summary: The study found that the hybridization of GDY and MoS2 can result in a composite material with high charge transport rate and discharge capacity. The MoS2@GDY anode demonstrates excellent capacity retention and cyclic performance at high testing density.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Multidisciplinary

Large-Scale and Flexible Optical Synapses for Neuromorphic Computing and Integrated Visible Information Sensing Memory Processing

Ya-Xin Hou et al.

Summary: Optoelectronic synapses combining synaptic and optical-sensing functions have advantages in neuromorphic computing for visual information processing and learning. A novel optical synapse based on a pyrenyl graphdiyne/graphene/PbS quantum dot heterostructure shows linear and symmetric conductance updates with multiple states, allowing accurate pattern recognition. This optical synapse demonstrates strong fault tolerance and is suitable for wearable electronics applications.

ACS NANO (2021)

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Review Chemistry, Multidisciplinary

Emerging Mono-Elemental Bismuth Nanostructures: Controlled Synthesis and Their Versatile Applications

Weichun Huang et al.

Summary: Mono-elemental Bi nanomaterials, with controlled synthesis, different shapes and sizes, and versatile applications, exhibit excellent performances in electronics/optoelectronics, energy storage and conversion, catalysis, nonlinear photonics, sensors, and biomedical applications.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Graphdiyne@Janus Magnetite for Photocatalytic Nitrogen Fixation

Yan Fang et al.

Summary: This study designed and fabricated a highly active graphdiyne heterojunction catalyst, showing transformative photocatalytic activity for ammonia synthesis by incorporating Fe site-specific magnetite into graphdiyne. The catalyst demonstrated remarkable catalytic performance with unprecedented levels of ammonia yield.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Physical

NIR enhanced peroxidase-like activity of Au@CeO2 hybrid nanozyme by plasmon-induced hot electrons and photothermal effect for bacteria killing

Chuang Liu et al.

Summary: By constructing a dumbbell-shaped Au@CeO2 hybrid nanozyme with strong surface plasmon resonance response in the Near Infrared (NIR) range, the peroxidase-like activity of Au@CeO2 was significantly enhanced under 808 nm irradiation. The efficient utilization of plasmon excitation through spatially separated structure led to improved antibacterial efficacy.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

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Article Chemistry, Physical

Nitrogen-doped graphdiyne for efficient electrocatalytic N2 reduction: A first-principles study

Gang Wang et al.

Summary: The study investigates the activity of N-doped graphdiyne for electrochemical N-2 reduction reaction using density functional theory. It shows that sp-N-2 GDY is the most active model, while pyridinic-N GDY follows a Mars-van Krevelen pathway. Graph-C vacancy efficiently reduces N-2, enhancing the selectivity for NRR over HER.

APPLIED SURFACE SCIENCE (2021)

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Article Engineering, Environmental

Construction of ultra-stable and Z-scheme Fe-Graphdiyne/MIL-100(Fe) photo-Fenton catalyst with C = C-Fe|O interface for the highly enhanced catalytic degradation of Dinotefuran

Zhengsheng Zhang et al.

Summary: In this study, the Z-scheme photocatalyst Fe-GDY3@MIL(Fe) was successfully developed by compositing with GDY, which effectively enhanced the catalytic performance and stability of Fe-based metal-organic frameworks for pesticide degradation, showing higher efficiency in degradation.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Chemistry, Multidisciplinary

Tuning the Intermolecular Electron Transfer of Low-Dimensional and Metal-Free BCN/C60 Electrocatalysts via Interfacial Defects for Efficient Hydrogen and Oxygen Electrochemistry

Md Ariful Ahsan et al.

Summary: The development of OD-2D heterostructures composed of BCN NSs and C-60/F has led to the synthesis of supramolecular materials with multifunctional electrocatalytic properties for various reactions. By optimizing the intermolecular electron transfer, a nanohybrid material with 10% F in BCN NSs showed enhanced catalytic activity surpassing commercial RuO2 catalysts. The 10% F/BCN catalyst exhibited the highest tetrafunctional catalytic performance, achieving a cell potential of 1.61 V for water splitting at a current density of 10 mA cm(-)(2).

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Multidisciplinary

Near-Infrared Regulated Nanozymatic/Photothermal/Photodynamic Triple-Therapy for Combating Multidrug-Resistant Bacterial Infections via Oxygen-Vacancy Molybdenum Trioxide Nanodots

Yan Zhang et al.

Summary: The oxygen-vacancy molybdenum trioxide nanodots (MoO3-x NDs) possess triple-therapy synergistic efficiency based on the single near-infrared irradiation (808 nm) regulated combination of photodynamic, photothermal, and peroxidase-like enzymatic activities, showing excellent antibacterial efficiency against drug-resistant bacteria.

SMALL (2021)

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Article Chemistry, Inorganic & Nuclear

CdS@CdSe Core/Shell Quantum Dots for Highly Improved Self-Powered Photodetection Performance

You Zi et al.

Summary: Uniform and well-defined cadmium sulfide@cadmium selenide core/shell quantum dots (CdS@CdSe QDs) were successfully synthesized for the first time using a solvothermal method and chemical bath growth. The as-synthesized CdS@CdSe QDs exhibit superior self-powered photoresponse behavior, excellent stability, and significantly improved current densities and photoresponsivity compared to individual CdS QDs or CdSe QDs. These properties are mainly attributed to the built-in electric field, suggesting great potential in the fields of renewable energy and carbon neutrality target achievement.

INORGANIC CHEMISTRY (2021)

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Article Chemistry, Applied

CoS2 nanowires supported graphdiyne for highly efficient hydrogen evolution reaction

Wangjing Xie et al.

Summary: In this study, planar unsaturated sulfurs in CoS2 nanowires have been activated through constructing Graphdiyne-CoS2 heterojunction nanocomposites, leading to enhanced electron transfer energy barriers and improved catalytic performance for hydrogen evolution reaction. The heterojunction exhibits superior HER catalytic performance and stability, paving the way for further efficient transition metal disulfides catalyst manufacture.

JOURNAL OF ENERGY CHEMISTRY (2021)

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Article Chemistry, Physical

Cationic chitosan@Ruthenium dioxide hybrid nanozymes for photothermal therapy enhancing ROS-mediated eradicating multidrug resistant bacterial infection

Xufeng Zhu et al.

Summary: By constructing a nanozyme with antibacterial activity, the research successfully disrupted bacterial biofilms and demonstrated its therapeutic efficacy in rescuing skin wound infections and chronic lung infections in mice.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

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Article Engineering, Environmental

Single-metal-atom catalysts: An emerging platform for electrocatalytic oxygen reduction

Yong Wang et al.

Summary: Single-atom catalysts (SACs) have attracted increasing interest as promising electrocatalysts, with their features of maximum utilization of active species, low-coordination environment, quantum size effect, and tunable metal-support interaction. Tremendous SACs have been fabricated using various approaches and play important roles in advanced energy conversion processes.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Chemistry, Multidisciplinary

Nanozymes: A clear definition with fuzzy edges

Hui Wei et al.

NANO TODAY (2021)

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Article Chemistry, Applied

Theoretical screening of the transition metal heteronuclear dimer anchored graphdiyne for electrocatalytic nitrogen reduction

Dongwei Ma et al.

Summary: The study found that FeCo@ and NiCo@GDY are efficient NRR catalysts with excellent catalytic activity, high ability to suppress HER, and good stability. These bimetallic catalysts improve the catalytic activity and selectivity of NRR through alloying.

JOURNAL OF ENERGY CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

NIR Laser-Triggered Microneedle-Based Liquid Band-Aid for Wound Care

Yun Sun et al.

Summary: This study introduces a new light-controlled liquid band-aid based on microneedles (MNs) loaded with metal-organic framework-derived peroxidase-like nanozyme for antibacterial applications. This innovative approach not only enhances drug permeation through heat conversion from light energy but also decomposes hydrogen peroxide for antibacterial purposes. The heat generated by the nanozyme facilitates the formation of a liquid band-aid, effectively reducing skin inflammation and promoting wound healing in a Staphylococcus aureus-infected mice model.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Multifunctional Graphdiyne-Cerium Oxide Nanozymes Facilitate MicroRNA Delivery and Attenuate Tumor Hypoxia for Highly Efficient Radiotherapy of Esophageal Cancer

Xuantong Zhou et al.

Summary: Radioresistance poses a significant challenge in clinical treatments, attributed to factors such as hypoxia in the tumor microenvironment, antioxidant systems in cancer cells, and upregulation of DNA repair proteins. A novel strategy involving GDY-CeO2 nanocomposites and miR181a shows promise in overcoming radioresistance and enhancing therapeutic efficacy in ESCC patients by mitigating hypoxia, promoting DNA damage, and facilitating personalized treatment.

ADVANCED MATERIALS (2021)

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Article Chemistry, Physical

Porous graphdiyne loading CoOx quantum dots for fixation nitrogen reaction

Yuxin Liu et al.

Summary: Scientists have developed a novel catalyst for efficient ammonia production, achieving ultra-high catalytic performance and excellent photocatalytic performance. After multiple experiments, the catalyst showed high efficiency and long-term stability in ammonia production.

NANO ENERGY (2021)

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Article Materials Science, Multidisciplinary

Graphdiyne oxide modified nano CuO as inorganic hole transport layer for efficient and stable organic solar cells

Jianxiao Wang et al.

Summary: The stability and performance of organic solar cells (OSCs) have become a focus of research due to the rapid development of OSCs. In this study, CuO nanomaterials were used as hole transport materials for high-efficiency OSCs, with the addition of graphdiyne oxide (GDYO) for improved conductivity and reduced contact resistance. The modified OSCs exhibited a high power conversion efficiency of 16.61%, with enhancements in current density and fill factor. The results indicate that GDYO-modified CuO as a hole transport layer shows great potential for fabricating highly efficient and stable OSCs.

2D MATERIALS (2021)

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Article Engineering, Biomedical

Water-soluble PANI:PSS designed for spontaneous non-disruptive membrane penetration and direct intracellular photothermal damage on bacteria

Huanfeng Tang et al.

Summary: This study discovered a water-soluble polymer composed of polyaniline-poly (p-styrenesulfonic acid) copolymer that can penetrate bacterial cell membranes in a non-disruptive manner, exhibiting excellent antibacterial activity. Under 808 nm near-infrared irradiation, this polymer can efficiently kill various bacteria, including Staphylococcus aureus, Methicillin-resistant Staphylococcus aureus, and Escherichia coli.

BIOACTIVE MATERIALS (2021)

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Article Engineering, Biomedical

Copper single-atom catalysts with photothermal performance and enhanced nanozyme activity for bacteria-infected wound therapy

Xianwen Wang et al.

Summary: This study highlights the enhanced catalytic activity of nanozymes through the construction of Cu SASs/NPC for photothermal-catalytic antibacterial treatment strategy. The introduction of Cu significantly improves the catalytic performance of nanozymes, effectively killing bacteria and improving sterilization effect. The synergistic PTT-catalytic antibacterial strategy shows almost 100% antibacterial efficiency against E. coli and MRSA, demonstrating wide bio-applications of Cu-containing catalysts in antibacterial and anti-infective treatments.

BIOACTIVE MATERIALS (2021)

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Article Chemistry, Physical

2D/2D Heterostructure of Metal-Free Ultrathin Graphdiyne/Carbon Nitride Nanosheets for Enhanced Photocatalytic Reduction of Carbon Dioxide with Water

Jiangting Zhao et al.

Summary: In this study, a stable 2D/2D graphdiyne/carbon nitride (GD/CN) heterojunction was prepared by electrostatic self-assembly, enabling efficient separation of photogenerated holes and electrons. Photogenerated electrons generated on CN were transferred to GD under illumination, leading to increased CO and CH4 yields. This work provides new insights for the design and preparation of efficient and environmentally friendly photocatalysts for the robust photoreduction of CO2.

ACS APPLIED ENERGY MATERIALS (2021)

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Article Nanoscience & Nanotechnology

Nitrogen-Doped Graphdiyne Quantum Dots for Electrochemical Chloramphenicol Quantification in Water

Qingyu Gu et al.

Summary: A chloramphenicol electrochemical sensor prepared from nitrogen-doped graphdiyne quantum dots exhibits high sensitivity, selectivity, and resistance to interference, allowing for accurate quantification of chloramphenicol in water samples and various applications.

ACS APPLIED NANO MATERIALS (2021)

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Article Multidisciplinary Sciences

Decorating graphdiyne on ultrathin bismuth subcarbonate nanosheets to promote CO2 electroreduction to formate

Shang-Feng Tang et al.

Summary: The study introduces a catalyst consisting of graphdiyne-decorated bismuth subcarbonate (denoted as BOC@GDY) for efficient electroreduction of CO2 to formate. The BOC@GDY demonstrates a stable current density of 200 mA cm(-2) at -1.1 V, with a high faradaic efficiency for formate. Experimental results suggest that the synergistic effect in BOC@GDY enhances CO2 adsorption affinity, reaction kinetics, and selectivity for formate.

SCIENCE BULLETIN (2021)

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Article Nanoscience & Nanotechnology

Constructing van der Waals Heterogeneous Photocatalysts Based on Atomically Thin Carbon Nitride Sheets and Graphdiyne for Highly Efficient Photocatalytic Conversion of CO2 into CO

Yong Wang et al.

Summary: The introduction of metal-free graphdiyne (GDY) in carbon nitride sheets (CNs) to form atomically thin 2D/2D van der Waals heterostructures significantly improves the efficiency of photocatalytic CO2 reduction.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Analytical

Nitrogen-Doped Graphdiyne as a Robust Electrochemical Biosensing Platform for Ultrasensitive Detection of Environmental Pollutants

Kai Niu et al.

Summary: Enzymatic biosensors based on nitrogen-doped graphdiyne exhibit high sensitivity, excellent reproducibility, and stability, showing great potential for rapid detection of environmental pollutants. The nitrogen doping enhances electrical conductivity and substance adsorption, contributing to significantly improved biosensing performance.

ANALYTICAL CHEMISTRY (2021)

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Article Chemistry, Physical

Self-assembled g-C3N4 nanotubes/graphdiyne composite with enhanced photocatalytic CO2 reduction

Cong Sun et al.

Summary: In this study, g-C3N4 nanotubes with sheet-like graphdiyne composite were successfully prepared through a simple self-assembly method. The composite significantly improved the separation efficiency of photogenerated carriers and the conductivity of the material, leading to enhanced performance towards photocatalytic CO2 reduction. Compared with pure CNtb, the yields for CO and CH4 in the composite were increased by 18-20 times, providing a new idea for the preparation of efficient g-C3N4 photocatalysts in the future.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

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Article Materials Science, Multidisciplinary

Double transition metal atoms anchored on Graphdiyne as promising catalyst for electrochemical nitrogen reduction reaction

Lakshitha Jasin Arachchige et al.

Summary: Ammonia synthesis by electrochemical nitrogen reduction technique is an attractive alternative to traditional methods, but the development of efficient catalysts remains a challenge. Research has shown that double transition metal atoms anchored on Graphdiyne display high activity in nitrogen reduction reactions, with a synergistic effect between the catalytic sites.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2021)

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Article Chemistry, Multidisciplinary

Graphdiyne/Graphene Heterostructure: A Universal 2D Scaffold Anchoring Monodispersed Transition-Metal Phthalocyanines for Selective and Durable CO2 Electroreduction

Huoliang Gu et al.

Summary: Electrochemical CO2 reduction using a graphdiyne/graphene heterostructure as a conductive scaffold to anchor cobalt phthalocyanine shows high activity, selectivity, and durability. The strong electronic coupling between GDY and CoPc, along with graphene's properties, contributes to the distinguished electrocatalytic performance. These findings suggest the potential of this hybrid structure in designing dispersed CO2R catalysts for sustainable energy conversion.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Multidisciplinary

Interfacial sp C-O-Mo Hybridization Originated High-Current Density Hydrogen Evolution

Yuan Yao et al.

Summary: The GDY/MoO3 material demonstrates efficient hydrogen evolution reaction with high-current density through rational design of sp C-O-Mo hybridization, creating new intrinsic catalytic active sites and increasing the amount of active sites. This approach allows for outstanding HER activity in alkaline electrolyte and decent activity and stability in natural seawater.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Review Chemistry, Multidisciplinary

Novel emerging graphdiyne based two dimensional materials: Synthesis, properties and renewable energy applications

Karim Khan et al.

Summary: Graphdiyne (GDY), a novel two-dimensional carbon allotrope with unique structure and properties, has attracted increasing attention for its wide range of potential applications. Efforts have been made to develop various forms of GDY materials, but challenges remain in fully understanding growth methods, fabricating single crystal GDY films, and achieving practical applications.

NANO TODAY (2021)

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Review Chemistry, Multidisciplinary

Graphene-Based Hybrid Functional Materials

Cosimo Anichini et al.

Summary: Graphene, a 2D material with outstanding physical properties, can be combined with other nanomaterials or molecules to form hybrid functional materials, showcasing new properties and enhanced characteristics. These hybrids exhibit superior performances compared to individual components in various technological applications, such as sensing, water purification, energy storage, biomedical applications, catalysis, and optoelectronics.

SMALL (2021)

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Article Chemistry, Physical

Regulating nitrogenous adsorption and desorption on Pd clusters by the acetylene linkages of hydrogen substituted graphdiyne for efficient electrocatalytic ammonia synthesis

Ying Guo et al.

Summary: The high electron density of acetylene linkages in hydrogen substituted graphdiyne (HsGDY) can regulate nitrogen adsorption and NH3 desorption on active Pd sites, leading to impressive electrocatalytic NRR performance. The optimized Pd/HsGDY shows ultrahigh Faraday efficiency and NH3 yield, favoring a selectively facilitated electrosynthesis of NH3.

NANO ENERGY (2021)

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Article Materials Science, Multidisciplinary

Defect reduction by anthraquinone-modified graphdiyne quantum dots for efficient perovskite solar cells

Xiaofei Cao et al.

Summary: The introduction of GDY-AQ QDs significantly improves perovskite crystallization and reduces defects in the perovskite film, leading to high-quality film with excellent stability and achieving over 21% power conversion efficiency in perovskite solar cells. The strategy of molecularly designed GDY-AQ QDs doping shows great potential for enhancing the performance of PSCs.

2D MATERIALS (2021)

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Article Materials Science, Multidisciplinary

Graphdiyne enables Cu nanoparticles for highly selective electroreduction of CO2 to formate

Jing-Jing Wang et al.

Summary: The study presents a novel Cu/pyrenyl-graphdiyne composite catalyst for efficient conversion of CO2 to formate in electroreduction, exhibiting excellent selectivity and activity achieved through the combined use of metallic Cu nanoparticles and 2D Pyr-GDY support.

2D MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Bimetallic Mixed Clusters Highly Loaded on Porous 2D Graphdiyne for Hydrogen Energy Conversion

Yang Gao et al.

Summary: Hydrogen energy is crucial for modern society, but efficient hydrogen production technologies are needed. The bimetallic oxide cluster electrocatalyst with unique structure reported in this study shows outstanding hydrogen evolution performance.

ADVANCED SCIENCE (2021)

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Article Nanoscience & Nanotechnology

Boosting hydrogen evolution reaction on few-layer graphdiyne by sp-N and B co-doping

Yasong Zhao et al.

Summary: This study presents a sequential approach for co-doping B and N atoms into graphdiyne, revealing the strong relationship between heteroatom configurations and doping process, and showing that the method plays a significant role in enhancing current density.

APL MATERIALS (2021)

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Article Chemistry, Physical

Ultrathin 2D/2D Graphdiyne/Bi2WO6 Heterojunction for Gas-Phase CO2 Photoreduction

Chao Yang et al.

Summary: Loading appropriate cocatalysts is an effective way to enhance photocatalytic activity. In this study, an ultrathin 2D/2D GDY/Bi2WO6 heterojunction was successfully crafted, showing enhanced photoreduction CO2 activity under simulated sunlight irradiation. The optimal sample BiGDY-3 exhibited a 4.9 times higher total CO2 conversion compared to Bi2WO6, attributed to enhanced light absorption, conductivity, and a large interfacial contact area, as well as increased specific surface area and micropores for enhanced CO2 adsorption.

ACS APPLIED ENERGY MATERIALS (2021)

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Article Nanoscience & Nanotechnology

Graphdiyne-decorated microfiber based soliton and noise-like pulse generation

Wanzhuo Ma et al.

Summary: Graphdiyne has a built-in band gap energy with great potential in ultrafast laser generation. In this work, a graphdiyne-decorated microfiber is fabricated to demonstrate saturable absorption characteristics, generating conventional solitons and noise-like pulses in an erbium-doped mode-locked fiber laser. Adjustment of pump power and polarization controller can switch the spectral bandwidth from 2.45 nm to 37.14 nm for noise-like pulses with excellent stability.

NANOPHOTONICS (2021)

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Article Chemistry, Multidisciplinary

High-performance n-type Ta4SiTe4/polyvinylidene fluoride (PVDF)/graphdiyne organic-inorganic flexible thermoelectric composites

Sanyin Qu et al.

Summary: In this study, high-performance n-type organic-inorganic flexible thermoelectric composites were successfully fabricated using semiconducting graphdiyne (GDY) instead of carbon nanotubes or graphene. The composites showed improved electrical conductivity and achieved a maximum ZT value of 0.2 at 300 K, making them among the highest reported in this field. Additionally, a prototype thermoelectric module consisting of both n-type and p-type legs demonstrated the highest normalized maximum power density compared to other organic material-based flexible thermoelectric modules.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Article Chemistry, Physical

The role of sp-hybridized boron atoms in the highly efficient photocatalytic N2 reduction activity of boron-doped triphenylene-graphdiyne

Yingcai Fan et al.

Summary: The study proposes a promising solution for efficient nitrogen reduction reaction by introducing sp-hybridized boron atoms into metal-free triphenylene-graphdiyne monolayer. The defect states induced by boron atoms enhance light absorption ability and suppress the recombination of photogenerated carriers, leading to high selectivity towards ammonia production.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Review Chemistry, Multidisciplinary

Recent advances of graphdiyne: synthesis, functionalization, and electrocatalytic applications

Xiaojie Chen et al.

Summary: Graphdiyne (GDY) with unique structure and properties shows great application prospects in various fields. Recent research has focused on the synthesis, structural modification, and practical applications of GDY, with significant progress in the field of electrocatalysis.

MATERIALS CHEMISTRY FRONTIERS (2021)

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Review Chemistry, Physical

Heteroatoms in graphdiyne for catalytic and energy-related applications

Baokun Liu et al.

Summary: The recently discovered carbon allotrope GDY with rich acetylenic bonds and unique pore structures shows great potential in tuning electronic structures and enhancing catalytic performance and energy storage efficiency by introducing heteroatoms. The modification of electronic properties by heteroatoms leads to improved diffusion barrier, adsorption energy, active sites, capacity, stability, rate performance, and longer lifespan. The topological molecular structure of GDY can be adjusted through different bottom-up synthesis methods using various monomers, offering promising prospects in energy storage devices and electrocatalytic processes.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Review Chemistry, Multidisciplinary

Nonlinear optics of graphdiyne

Chao Liu et al.

Summary: Graphdiyne, a rising star in all-carbon materials, shows great potential in nonlinear optics due to its high optical refractive index, low saturation intensity, and broadband absorption. Researchers are increasingly focusing on the application prospects of Graphdiyne in the field of nonlinear optics.

MATERIALS CHEMISTRY FRONTIERS (2021)

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Article Chemistry, Multidisciplinary

Graphdiyne-hemin-mediated catalytic system for wound disinfection and accelerated wound healing

Arbab Ali et al.

Summary: The nanocomposite GDY-hemin, with high peroxidase activity, effectively combats bacterial infections and demonstrates good biocompatibility.

MATERIALS CHEMISTRY FRONTIERS (2021)

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Article Chemistry, Physical

Taming the challenges of activity and selectivity in the electrochemical nitrogen reduction reaction using graphdiyne-supported double-atom catalysts

Yongkang Xu et al.

Summary: This study focuses on understanding and addressing the challenge of developing efficient electrocatalysts for the eNRR by using systematic DFT calculations on FeM-GDYs. The research identifies 11 FeM-GDYs with improved activity compared to the benchmark Ru(0001) stepped surface, and demonstrates three FeM-GDYs (M = Ni, Mo, and Cr) with strong ability to suppress the competitive hydrogen evolution reaction using a selectivity descriptor. The improvements in activity and selectivity are attributed to alterations in the electronic structures and coordination environments of the metal atoms upon FeM-GDY formation, indicating high potential for experimental synthesis of these catalysts.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Review Nanoscience & Nanotechnology

Recent Progress in DNA Motor-Based Functional Systems

Bini Zhou et al.

Summary: DNA motors with designability, functionalization, and diverse secondary structures allow for the construction of stimuli-responsive systems, widely used in generating mechanical power under external stimuli like pH, light, heat, and chemical signals. Recent progress in constructing and applying DNA motor-based functional systems has shown great potential in responsive nanodevices, modified surfaces, and hydrogels for applications in smart devices and materials, particularly in controllable drug delivery and reversible molecular switching.

ACS APPLIED BIO MATERIALS (2021)

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Review Chemistry, Multidisciplinary

Inorganic-Organic Nanocomposites Based on Aggregation-Induced Emission Luminogens

Yuanwei Wang et al.

Summary: The emergence of aggregation-induced emission (AIE) has greatly promoted the development of various fields including chemical sensing, bioimaging, theranostics, and photoelectric devices. Integrating AIE luminogens with functionalized supporting agents is an intriguing strategy for constructing high-performance versatile materials. Inorganic nanomaterials have attracted scientific interest in functionalizing AIE luminogens by combining their advantages.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

1D Supercapacitors for Emerging Electronics: Current Status and Future Directions

Shengli Zhai et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Physical

Graphdiyne: A new promising member of 2D all-carbon nanomaterial as robust electrochemical enzyme biosensor platform

Lingxia Wu et al.

CARBON (2020)

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Article Chemistry, Multidisciplinary

Sensitive Wearable Temperature Sensor with Seamless Monolithic Integration

Jaeho Shin et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Multidisciplinary

A-Site Management for Highly Crystalline Perovskites

Haonan Si et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Physical

C3N/blue phosphorene heterostructure as a high rate-capacity and stable anode material for lithium ion batteries: Insight from first principles calculations

He Lin et al.

APPLIED SURFACE SCIENCE (2020)

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Article Multidisciplinary Sciences

Probing the active sites of site-specific nitrogen doping in metal-free graphdiyne for electrochemical oxygen reduction reactions

Xingzhu Chen et al.

SCIENCE BULLETIN (2020)

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Article Nanoscience & Nanotechnology

Bacterial Detection and Elimination Using a Dual-Functional Porphyrin-Based Porous Organic Polymer with Peroxidase-Like and High Near-Infrared-Light-Enhanced Antibacterial Activity

Dekang Li et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Chemistry, Multidisciplinary

Graphdiyne Derivative as Multifunctional Solid Additive in Binary Organic Solar Cells with 17.3% Efficiency and High Reproductivity

Le Liu et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Analytical

Endogenous Cys-Assisted GSH@AgNCs-rGO Nanoprobe for Real-Time Monitoring of Dynamic Change in GSH Levels Regulated by Natural Drug

Yan Qin et al.

ANALYTICAL CHEMISTRY (2020)

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Article Chemistry, Multidisciplinary

Steric Mixed-Cation 2D Perovskite as a Methylammonium Locker to Stabilize MAPbI3

Xingtao Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

The Crucial Role of Charge Accumulation and Spin Polarization in Activating Carbon-Based Catalysts for Electrocatalytic Nitrogen Reduction

Yuanyuan Yang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Physical

Pyridinic nitrogen exclusively doped carbon materials as efficient oxygen reduction electrocatalysts for Zn-air batteries

Qing Lv et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

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Article Chemistry, Physical

Sensing of volatile organic compounds on two-dimensional nitrogenated holey graphene, graphdiyne, and their heterostructure

Tanveer Hussain et al.

CARBON (2020)

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Article Chemistry, Physical

Light and Heat Triggering Modulation of the Electronic Performance of a Graphdiyne-Based Thin Film Transistor

Yuan Li et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2020)

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Article Chemistry, Multidisciplinary

Electron Hopping by Interfacing Semiconducting Graphdiyne Nanosheets and Redox Molecules for Selective Electrocatalysis

Shuyue Guo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Optics

Graphdiyne-Polymer Nanocomposite as a Broadband and Robust Saturable Absorber for Ultrafast Photonics

Jia Guo et al.

LASER & PHOTONICS REVIEWS (2020)

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Article Chemistry, Analytical

A sandwich-type photoelectrochemical sensor based on tremella-like graphdiyne as photoelectrochemical platform and graphdiyne oxide nanosheets as signal inhibitor

Hao Wang et al.

SENSORS AND ACTUATORS B-CHEMICAL (2020)

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Article Chemistry, Multidisciplinary

In Situ Ice Template Approach to Fabricate 3D Flexible MXene Film-Based Electrode for High Performance Supercapacitors

Peng Zhang et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Review Chemistry, Multidisciplinary

2D Porous Polymers with sp2-Carbon Connections and Sole sp2-Carbon Skeletons

Jialing Kang et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Graphdiyne-Based Flexible Photodetectors with High Responsivity and Detectivity

Ye Zhang et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Graphdiyne: Bridging SnO2 and Perovskite in Planar Solar Cells

Suicai Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

A Stable and Conductive Metallophthalocyanine Framework for Electrocatalytic Carbon Dioxide Reduction in Water

Ning Huang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Graphdiyne Interface Engineering: Highly Active and Selective Ammonia Synthesis

Yan Fang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Physical

Remarkably enhanced first hyperpolarizability and nonlinear refractive index of novel graphdiyne-based materials for promising optoelectronic applications: A first-principles study

Xiaojun Li et al.

APPLIED SURFACE SCIENCE (2020)

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Article Chemistry, Physical

2D graphdiyne loading ruthenium atoms for high efficiency water splitting

Huidi Yu et al.

NANO ENERGY (2020)

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Article Chemistry, Analytical

Graphdiyne oxides as new modifier for the simultaneous electrochemical detection of phenolic compounds

Yu Zhang et al.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2020)

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Review Chemistry, Physical

Graphdiyne: A Rising Star of Electrocatalyst Support for Energy Conversion

Bisheng Li et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Materials Science, Multidisciplinary

Graphdiyne for significant thermal conductivity enhancement at ultralow mass fraction in polymer composites

Mengjie Wang et al.

2D MATERIALS (2020)

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Article Materials Science, Multidisciplinary

Grain boundary passivation with triazine-graphdiyne to improve perovskite solar cell performance

Siqi Chen et al.

SCIENCE CHINA-MATERIALS (2020)

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Review Chemistry, Multidisciplinary

Nanopore-Supported Metal Nanocatalysts for Efficient Hydrogen Generation from Liquid-Phase Chemical Hydrogen Storage Materials

Qiming Sun et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Multidisciplinary

A Graphdiyne Oxide-Based Iron Sponge with Photothermally Enhanced Tumor-Specific Fenton Chemistry

Huan Min et al.

ADVANCED MATERIALS (2020)

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Review Chemistry, Multidisciplinary

2D Material Chemistry: Graphdiyne-based Biochemical Sensing

Jiaofu Li et al.

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES (2020)

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Article Chemistry, Multidisciplinary

Graphdiyne:Structure of Fluorescent Quantum Dots

Jie Guo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Multidisciplinary Sciences

Synergistic trifunctional electrocatalysis of pyridinic nitrogen and single transition-metal atoms anchored on pyrazine-modified graphdiyne

Siyun Qi et al.

SCIENCE BULLETIN (2020)

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Article Chemistry, Physical

Titania:Graphdiyne nanocomposites for high-performance deep ultraviolet photodetectors based on mixed-phase MgZnO

Yan Li et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2020)

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Review Chemistry, Multidisciplinary

Bridging the Gap between Reality and Ideality of Graphdiyne: The Advances of Synthetic Methodology

Ya Kong et al.

CHEM (2020)

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Review Chemistry, Multidisciplinary

Recent Advances in Semiconducting Monoelemental Selenium Nanostructures for Device Applications

Weichun Huang et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Review Chemistry, Multidisciplinary

Recent Advances in Functional 2D MXene-Based Nanostructures for Next-Generation Devices

Weichun Huang et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Cation-Exchange Induced Precise Regulation of Single Copper Site Triggers Room-Temperature Oxidation of Benzene

Huang Zhou et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Physical

Hybrid nanostructured MnO2 nanowire/graphdiyne with enhanced lithium-ion performance promoting by interfacial storage

Yuda Lin et al.

APPLIED SURFACE SCIENCE (2020)

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Article Chemistry, Physical

Bulk-synthesis and supercapacitive energy storage applications of nanoporous triazine-based graphdiyne

Yong Yue et al.

CARBON (2020)

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Article Chemistry, Multidisciplinary

Antibacterial Activity of Graphdiyne and Graphdiyne Oxide

Zhiling Zhu et al.

SMALL (2020)

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Article Chemistry, Multidisciplinary

Graphdiyne-templated palladium-nanoparticle assembly as a robust oxygen generator to attenuate tumor hypoxia

Jiaming Liu et al.

NANO TODAY (2020)

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Article Multidisciplinary Sciences

A disordered rock salt anode for fast-charging lithium-ion batteries

Haodong Liu et al.

NATURE (2020)

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Article Chemistry, Multidisciplinary

Cu2MoS4Nanozyme with NIR-II Light Enhanced Catalytic Activity for Efficient Eradication of Multidrug-Resistant Bacteria

Jingyang Shan et al.

SMALL (2020)

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Article Multidisciplinary Sciences

Graphdiyne-modified TiO2 nanofibers with osteoinductive and enhanced photocatalytic antibacterial activities to prevent implant infection

Rui Wang et al.

NATURE COMMUNICATIONS (2020)

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Article Chemistry, Multidisciplinary

Peroxidase-Mimetic and Fenton-Like Activities of Molybdenum Oxide Quantum Dots

Sai Jin Xiao et al.

CHEMISTRYSELECT (2020)

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Article Chemistry, Multidisciplinary

Preparation of graphdiyne-doped TiO2/SiO2 composite for enhanced photocatalytic activity

Xiang Yu et al.

JOURNAL OF NANOPARTICLE RESEARCH (2020)

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Review Nanoscience & Nanotechnology

Artificial Carbon Graphdiyne: Status and Challenges in Nonlinear Photonic and Optoelectronic Applications

Jiaofu Li et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Multidisciplinary Sciences

Regulating kinetics and thermodynamics of electrochemical nitrogen reduction with metal single-atom catalysts in a pressurized electrolyser

Haiyuan Zou et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2020)

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Review Engineering, Environmental

Using graphdiyne (GDY) as a catalyst support for enhanced performance in organic pollutant degradation and hydrogen production: A review

Biao Song et al.

JOURNAL OF HAZARDOUS MATERIALS (2020)

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Article Chemistry, Physical

Investigation the application of pristine graphdiyne (GDY) and boron-doped graphdiyne (BGDY) as an electronic sensor for detection of anticancer drug

Peilong Xu et al.

COMPUTATIONAL AND THEORETICAL CHEMISTRY (2020)

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Review Materials Science, Multidisciplinary

Emerging black phosphorus analogue nanomaterials for high-performance device applications

Weichun Huang et al.

JOURNAL OF MATERIALS CHEMISTRY C (2020)

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Article Chemistry, Multidisciplinary

Photocarrier relaxation pathways in selenium quantum dots and their application in UV-Vis photodetection

Xiantao Jiang et al.

NANOSCALE (2020)

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Article Nanoscience & Nanotechnology

Preparation of N-Graphdiyne Nanosheets at Liquid/Liquid Interface for Photocatalytic NADH Regeneration

Qingyan Pan et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Chemistry, Multidisciplinary

Synthesis and Applications of Graphdiyne-Based Metal-Free Catalysts

Zicheng Zuo et al.

ADVANCED MATERIALS (2019)

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Review Chemistry, Multidisciplinary

Chemodynamic Therapy: Tumour Microenvironment-Mediated Fenton and Fenton-like Reactions

Zhongmin Tang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Analytical

Discriminative Detection of Glutathione in Cell Lysates Based on Oxidase-Like Activity of Magnetic Nanoporous Graphene

Haijuan Zhang et al.

ANALYTICAL CHEMISTRY (2019)

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Article Chemistry, Analytical

Highly Integrated, Biostable, and Self-Powered DNA Motor Enabling Autonomous Operation in Living Bodies

Jing Wang et al.

ANALYTICAL CHEMISTRY (2019)

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Article Chemistry, Multidisciplinary

Covalently Grafting Cobalt Porphyrin onto Carbon Nanotubes for Efficient CO2 Electroreduction

Minghui Zhu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Multidisciplinary

A Single-Atom Nanozyme for Wound Disinfection Applications

Bolong Xu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Review Chemistry, Multidisciplinary

Nanozymes: Classification, Catalytic Mechanisms, Activity Regulation, and Applications

Yanyan Huang et al.

CHEMICAL REVIEWS (2019)

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Article Physics, Applied

Ab initio research of a metal-free C/N van der Waals bilayer heterostructure with graphdiyne and g-C3N4

Ye Xiao et al.

JAPANESE JOURNAL OF APPLIED PHYSICS (2019)

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Article Multidisciplinary Sciences

Perovskite-polymer composite cross-linker approach for highly-stable and efficient perovskite solar cells

Tae-Hee Han et al.

NATURE COMMUNICATIONS (2019)

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Article Chemistry, Physical

Steric Modification of a Cobalt Phthalocyanine/Graphene Catalyst To Give Enhanced and Stable Electrochemical CO2 Reduction to CO

Jaecheol Choi et al.

ACS ENERGY LETTERS (2019)

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Graphdiyne and its Assembly Architectures: Synthesis, Functionalization, and Applications

Huidi Yu et al.

ADVANCED MATERIALS (2019)

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Article Chemistry, Analytical

Glutathione Regulated Inner Filter Effect of MnO2 Nanosheets on Boron Nitride Quantum Dots for Sensitive Assay

Chao Peng et al.

ANALYTICAL CHEMISTRY (2019)

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Article Biophysics

Photoelectrochemical platform for MicroRNA let-7a detection based on graphdiyne loaded with AuNPs modified electrode coupled with alkaline phosphatase

Yanxin Li et al.

BIOSENSORS & BIOELECTRONICS (2019)

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Article Chemistry, Physical

Nanoindentation of thin graphdiyne films: Experiments and molecular dynamics simulation

Kailu Xiao et al.

CARBON (2019)

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Tumor Reoxygenation and Blood Perfusion Enhanced Photodynamic Therapy using Ultrathin Graphdiyne Oxide Nanosheets

Wei Jiang et al.

NANO LETTERS (2019)

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Article Multidisciplinary Sciences

A rigorous electrochemical ammonia synthesis protocol with quantitative isotope measurements

Suzanne Z. Andersen et al.

NATURE (2019)

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Article Optics

Surface passivation of perovskite film for efficient solar cells

Qi Jiang et al.

NATURE PHOTONICS (2019)

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Enhanced Photodetection Properties of Tellurium@Selenium Roll-to-Roll Nanotube Heterojunctions

Weichun Huang et al.

SMALL (2019)

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Enhanced Electrocatalytic N2 Reduction via Partial Anion Substitution in Titanium Oxide-Carbon Composites

Qing Qin et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Multidisciplinary

Fluorographdiyne: A Metal-Free Catalyst for Applications in Water Reduction and Oxidation

Chengyu Xing et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Multidisciplinary

Antimony-Based Composites Loaded on Phosphorus-Doped Carbon for Boosting Faradaic Efficiency of the Electrochemical Nitrogen Reduction Reaction

Xien Liu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Multidisciplinary

Highly Efficient and Selective Generation of Ammonia and Hydrogen on a Graphdiyne-Based Catalyst

Lan Hui et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Single-Atom Pd1/Graphene Catalyst Achieved by Atomic Layer Deposition: Remarkable Performance in Selective Hydrogenation of 1,3-Butadiene

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Graphdiyne for high capacity and long-life lithium storage

Changshui Huang et al.

NANO ENERGY (2015)

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Article Chemistry, Multidisciplinary

Self-Templated Formation of Uniform NiCo2O4 Hollow Spheres with Complex Interior Structures for Lithium-Ion Batteries and Supercapacitors

Laifa Shen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

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Article Chemistry, Multidisciplinary

Hierarchical NiCo2O4 Nanosheets Grown on Ni Nanofoam as High-Performance Electrodes for Supercapacitors

Guoxin Gao et al.

SMALL (2015)

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Article Chemistry, Multidisciplinary

Carbon Nanotubes Decorated with CoP Nanocrystals: A Highly Active Non-Noble-Metal Nanohybrid Electrocatalyst for Hydrogen Evolution

Qian Liu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

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Article Chemistry, Multidisciplinary

Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles**

Eric J. Popczun et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

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Review Chemistry, Multidisciplinary

Two-dimensional carbon leading to new photoconversion processes

Hongjie Tang et al.

CHEMICAL SOCIETY REVIEWS (2014)

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Review Chemistry, Multidisciplinary

Graphdiyne and graphyne: from theoretical predictions to practical construction

Yongjun Li et al.

CHEMICAL SOCIETY REVIEWS (2014)

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Article Chemistry, Multidisciplinary

Abnormally enhanced thermoelectric transport properties of SWNT/PANI hybrid films by the strengthened PANI molecular ordering

Qin Yao et al.

ENERGY & ENVIRONMENTAL SCIENCE (2014)

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Article Chemistry, Multidisciplinary

Sb-C nanofibers with long cycle life as an anode material for high-performance sodium-ion batteries

Lin Wu et al.

ENERGY & ENVIRONMENTAL SCIENCE (2014)

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Article Chemistry, Physical

Large thermoelectric power factor in polyaniline/graphene nanocomposite films prepared by solution-assistant dispersing method

Liming Wang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2014)

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Article Chemistry, Multidisciplinary

Photocatalytic Properties of Graphdiyne and Graphene Modified TiO2: From Theory to Experiment

Nailiang Yang et al.

ACS NANO (2013)

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Article Chemistry, Physical

Mechanical and Electronic Properties of Graphyne and Its Family under Elastic Strain: Theoretical Predictions

Qu Yue et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2013)

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Article Chemistry, Physical

Carrier Mobility in Graphyne Should Be Even Larger than That in Graphene: A Theoretical Prediction

Jianming Chen et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2013)

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Article Chemistry, Multidisciplinary

Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction

Eric J. Popczun et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

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Article Chemistry, Multidisciplinary

High responsivity, fast ultraviolet photodetector fabricated from ZnO nanoparticle-graphene core-shell structures

Dali Shao et al.

NANOSCALE (2013)

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Article Chemistry, Physical

Wet milled synthesis of an Sb/MWCNT nanocomposite for improved sodium storage

Xiaosi Zhou et al.

JOURNAL OF MATERIALS CHEMISTRY A (2013)

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Review Chemistry, Multidisciplinary

Nanocomposites and macroscopic materials: assembly of chemically modified graphene sheets

Dongqing Wu et al.

CHEMICAL SOCIETY REVIEWS (2012)

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Review Chemistry, Multidisciplinary

Graphene-based composites

Xiao Huang et al.

CHEMICAL SOCIETY REVIEWS (2012)

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Article Chemistry, Multidisciplinary

Terephthalonitrile-derived nitrogen-rich networks for high performance supercapacitors

Long Hao et al.

ENERGY & ENVIRONMENTAL SCIENCE (2012)

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Article Chemistry, Multidisciplinary

Multiwfn: A multifunctional wavefunction analyzer

Tian Lu et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2012)

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Article Chemistry, Physical

Design of a Universal Reversible Bidirectional Current Switch Based on the Fullerene-Phthalocyanine Supramlecular System

Dongdong Qi et al.

JOURNAL OF PHYSICAL CHEMISTRY A (2012)

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Article Chemistry, Multidisciplinary

Three-Dimensional Graphene-Based Macro- and Mesoporous Frameworks for High-Performance Electrochemical Capacitive Energy Storage

Zhong-Shuai Wu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

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Article Chemistry, Multidisciplinary

Structural and electronic properties of bilayer and trilayer graphdiyne

Qiye Zheng et al.

NANOSCALE (2012)

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Review Optics

The renaissance of dye-sensitized solar cells

Brian E. Hardin et al.

NATURE PHOTONICS (2012)

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Article Chemistry, Multidisciplinary

A Novel and Highly Efficient Photocatalyst Based on P25-Graphdiyne Nanocomposite

Shuo Wang et al.

SMALL (2012)

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Article Chemistry, Multidisciplinary

Highly branched Pt-Ni nanocrystals enclosed by stepped surface for methanol oxidation

Zhiqiang Niu et al.

CHEMICAL SCIENCE (2012)

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Article Nanoscience & Nanotechnology

Graphene Supported Platinum Nanoparticle Counter-Electrode for Enhanced Performance of Dye-Sensitized Solar Cells

Reeti Bajpai et al.

ACS APPLIED MATERIALS & INTERFACES (2011)

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Article Chemistry, Multidisciplinary

Electronic Structure and Carrier Mobility in Graphdiyne Sheet and Nanoribbons: Theoretical Predictions

Mengqiu Long et al.

ACS NANO (2011)

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Article Chemistry, Multidisciplinary

Functional Composite Materials Based on Chemically Converted Graphene

Hua Bai et al.

ADVANCED MATERIALS (2011)

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Article Physics, Applied

Graphyne- and graphdiyne-based nanoribbons: Density functional theory calculations of electronic structures

L. D. Pan et al.

APPLIED PHYSICS LETTERS (2011)

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Article Chemistry, Multidisciplinary

Graphdiyne: a versatile nanomaterial for electronics and hydrogen purification

Yan Jiao et al.

CHEMICAL COMMUNICATIONS (2011)

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Review Chemistry, Multidisciplinary

Pyrene-functionalized oligonucleotides and locked nucleic acids (LNAs): Tools for fundamental research, diagnostics, and nanotechnology

Michael E. Ostergaard et al.

CHEMICAL SOCIETY REVIEWS (2011)

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Article Chemistry, Multidisciplinary

A general strategy toward graphene@metal oxide core-shell nanostructures for high-performance lithium storage

Weiwei Zhou et al.

ENERGY & ENVIRONMENTAL SCIENCE (2011)

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Article Chemistry, Multidisciplinary

Metal-Free Activation of Dioxygen by Graphene/g-C3N4 Nanocomposites: Functional Dyads for Selective Oxidation of Saturated Hydrocarbons

Xin-Hao Li et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

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Article Materials Science, Multidisciplinary

Quasiparticle energies and excitonic effects of the two-dimensional carbon allotrope graphdiyne: Theory and experiment

Guangfu Luo et al.

PHYSICAL REVIEW B (2011)

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Article Chemistry, Multidisciplinary

Large scale restructuring of porous Pt-Ni nanoparticle tubes for methanol oxidation: A highly reactive, stable, and restorable fuel cell catalyst

Chun-Hua Cui et al.

CHEMICAL SCIENCE (2011)

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Article Chemistry, Multidisciplinary

Improved Thermoelectric Behavior of Nanotube-Filled Polymer Composites with Poly(3,4-ethylenedioxythiophene) Poly(styrenesulfonate)

Dasaroyong Kim et al.

ACS NANO (2010)

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Article Chemistry, Multidisciplinary

Enhanced Thermoelectric Performance of Single-Walled Carbon Nanotubes/Polyaniline Hybrid Nanocomposites

Qin Yao et al.

ACS NANO (2010)

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Article Chemistry, Multidisciplinary

Peptide/Graphene Hybrid Assembly into Core/Shell Nanowires

Tae Hee Han et al.

ADVANCED MATERIALS (2010)

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Article Chemistry, Multidisciplinary

Low-Cost Hydrogen-Evolution Catalysts Based on Monolayer Platinum on Tungsten Monocarbide Substrates

Daniel V. Esposito et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

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Article Chemistry, Multidisciplinary

Architecture of graphdiyne nanoscale films

Guoxing Li et al.

CHEMICAL COMMUNICATIONS (2010)

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Review Chemistry, Multidisciplinary

Dye-Sensitized Solar Cells

Anders Hagfeldt et al.

CHEMICAL REVIEWS (2010)

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Article Chemistry, Physical

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

Stefan Grimme et al.

JOURNAL OF CHEMICAL PHYSICS (2010)

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Article Multidisciplinary Sciences

Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction

Kuanping Gong et al.

SCIENCE (2009)

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Article Chemistry, Physical

Long-range corrected hybrid density functionals with damped atom-atom dispersion corrections

Jeng-Da Chai et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2008)

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News Item Multidisciplinary Sciences

The bacteria fight back

Gary Taubes

SCIENCE (2008)

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Article Chemistry, Physical

The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals

Yan Zhao et al.

THEORETICAL CHEMISTRY ACCOUNTS (2008)

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Article Electrochemistry

Application of carbon materials as counter electrodes of dye-sensitized solar cells

Zhen Huang et al.

ELECTROCHEMISTRY COMMUNICATIONS (2007)

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Article Multidisciplinary Sciences

Electric field effect in atomically thin carbon films

KS Novoselov et al.

SCIENCE (2004)

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Article Energy & Fuels

High-performance carbon counter electrode for dye-sensitized solar cells

K Imoto et al.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2003)

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Article Chemistry, Physical

Chemical content of the kinetic energy density

HL Schmider et al.

JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM (2000)

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Article Chemistry, Inorganic & Nuclear

Single-Atom Catalysts Supported on the Graphene/Graphdiyne Heterostructure for Effective CO2 Electroreduction

Yun Yang et al.

Summary: Through density functional theory calculations, this study found that the transition metal single-atom catalyst Co-N-4@GRA/GDY anchored on nitrogen-doped graphene/graphdiyne heterostructure exhibits remarkable activity for CO2 reduction reaction, providing a potential avenue for improving catalytic performance and accelerating CO2RR.

INORGANIC CHEMISTRY

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Functional Graphdiyne for Emerging Applications: Recent Advances and Future Challenges

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