4.8 Review

Review of Separator Modification Strategies: Targeting Undesired Anion Transport in Room Temperature Sodium-Sulfur/Selenium/Iodine Batteries

Related references

Note: Only part of the references are listed.
Article Materials Science, Multidisciplinary

Electronegativity-Induced Single-Ion Conducting Polymer Electrolyte for Solid-State Lithium Batteries

Tianyi Hou et al.

Summary: This study presents an iodine-driven strategy to address the issues of insufficient ionic conductivity and low Li+ transference numbers in solid polymer electrolytes (SPEs). The introduction of electronegative iodine-containing groups effectively attracts Li+ ions, facilitates Li+ transport, and promotes the dissociation of Li salts. The iodinated single-ion conducting polymer electrolyte (IPE) demonstrates excellent ionic conductivity and Li+ transference numbers, as well as high stability in Li/Li cells and Li-S batteries, achieving high-capacity retentions when matched with intercalation cathode chemistries.

ENERGY & ENVIRONMENTAL MATERIALS (2023)

Article Chemistry, Multidisciplinary

Physicochemical Synergistic Separator Coating Induces Uniform and Rapid Deposition of Li and Zn Ions

Di Yang et al.

Summary: Li and Zn metal batteries show great potential to replace Li-ion batteries, but issues such as dendrite growth caused by uneven cation deposition during charge-discharge cycles hinder their practical application. In this study, we propose a simple method of separator modification that combines physical and chemical forces to regulate uniform and rapid deposition of Li+ and Zn2+. This modified separator allows for stable cycling of Li and Zn metal anodes for over 1000 h under a large current density of 10 mA cm(-2).

NANO LETTERS (2023)

Article Materials Science, Multidisciplinary

Reasonable suppression of polysulfides/polyselenides shuttle based on MXene in Na-SeS2 batteries

Qiu-Ju Yang et al.

Summary: A dual defense system for polysulfides/polyselenides was proposed based on MXene, which effectively addresses the shuttle and poor electronic conductivity issues. The integrated Na-SeS2 battery with this design achieves higher specific capacity than its counterparts, showcasing its superiority.

RARE METALS (2023)

Review Chemistry, Physical

Covalent Organic Framework Based Lithium-Sulfur Batteries: Materials, Interfaces, and Solid-State Electrolytes

Ben Hu et al.

Summary: In this article, the application of covalent organic frameworks (COFs) in addressing the issues of sulfur hosts, modified separators, artificial solid electrolyte interphase layers, and solid-state electrolytes in lithium-sulfur batteries is summarized. The focus is on the design and chemistry of COFs for upgrading Li-S batteries. The existing difficulties, prospective remedies, and future research directions for COFs in Li-S batteries are also discussed, laying the foundation for the advancement of this fascinating class of materials.

ADVANCED ENERGY MATERIALS (2023)

Review Chemistry, Applied

Design strategies of performance-enhanced Se cathodes for Li-Se batteries and beyond

Weiling Qiu et al.

Summary: This review comprehensively summarizes and discusses the recent progress in the design strategies of functional selenium cathodes, presenting efficient functionalization strategies including covalent bonding, nanostructure construction, heteroatom doping, component hybridization, and solid solution formation. These strategies have been successfully extended to different types of selenium batteries.

JOURNAL OF ENERGY CHEMISTRY (2023)

Article Chemistry, Physical

Atomically dispersed Co-N4C2 catalytic sites for wide-temperature Na-Se batteries

Wen-Da Dong et al.

Summary: Sodium-selenium (Na-Se) batteries have been considered as potential large-scale energy storage systems due to their high volumetric energy density and natural abundance of sodium. However, issues such as slow redox kinetics, significant volume changes, and shuttle effect have negatively affected their electrochemical performance. In this study, a precompetitive coordination strategy was proposed to synthesize a Co-N4C2 catalyst for solid-state conversion in Na-Se batteries. The Co-N4C2 catalyst enhanced the redox kinetics and electroreduction of ethylene carbonate, leading to the formation of a robust cathode electrolyte interphase and preventing irreversible phase transformation. The study also identified the components of the cathode electrolyte interphase as sodium ethylene monocarbonate. The resulting Se@Co-N4C2 cathode exhibited high capacity, cycling stability, and rate capability at both room temperature and low temperature.

NANO ENERGY (2023)

Article Chemistry, Physical

Stable all-solid-state sodium-sulfur batteries for low-temperature operation enabled by sodium alloy anode and confined sulfur cathode

Li-Ji Jhang et al.

Summary: This study investigates the performance of sodium-antimony (Na-Sb) and sodium-tin (Na-Sn) alloy anodes in sodium-sulfur (Na-S) batteries and demonstrates the stability of Na3Sb alloy in the alloying/dealloying process. The combination of Na3Sb alloy anode with sulfur-carbon composites results in high specific capacity and improved rate performance.

NANO ENERGY (2023)

Review Chemistry, Physical

Strategies toward High-Loading Lithium-Sulfur Batteries

Tao Wang et al.

Summary: This review summarizes the research on lithium-sulfur batteries with high sulfur loading based on adsorption-catalysis dual promotion strategies. It covers the principle, technical challenges, electrode materials design, potential approaches, and suggestions for constructing next-generation lithium-sulfur batteries.

ACS ENERGY LETTERS (2023)

Review Chemistry, Multidisciplinary

Toward the Advanced Next-Generation Solid-State Na-S Batteries: Progress and Prospects

Jingkang Ma et al.

Summary: Although solid-state sodium-sulfur batteries (SSSSB) have the potential for higher safety and improved energy density compared to traditional liquid-based systems, they still face challenges such as poor interfacial contact, slow sulfur conversion kinetics, and sodium dendrites. Various strategies have been proposed to overcome these issues, including developing advanced cathodes and cathode/electrolyte interfaces, tailoring solid electrolytes, and designing stable anodes and anode/electrolyte interfaces. This review provides a timely and comprehensive analysis of emerging strategies to promote the development of SSSSB and offers further perspectives on stimulating their practical application.

ADVANCED FUNCTIONAL MATERIALS (2023)

Article Chemistry, Multidisciplinary

Functional Ultrathin Separators Proactively Stabilizing Zinc Anodes for Zinc-Based Energy Storage

Yang Li et al.

Summary: Functional ultrathin separators (FUSs) with a thickness of 23 μm are reported, which exhibit superb electrochemical stability of zinc anodes and outstanding long-term durability of ultrathin separators. The FUSs feature a mechanically strong nanoporous membrane substrate for fast and flux-homogenized Zn2+ transport, and a metal-organic framework (MOF)-derived C/Cu nanocomposite decoration layer for stabilizing zinc anodes and inhibiting zinc dendrites.

ADVANCED MATERIALS (2023)

Article Chemistry, Multidisciplinary

A Janus Separator based on Cation Exchange Resin and Fe Nanoparticles-decorated Single-wall Carbon Nanotubes with Triply Synergistic Effects for High-areal Capacity Zn-I2 Batteries

Yuanhong Kang et al.

Summary: A Janus separator composed of functional layers on anode/cathode sides is designed to simultaneously solve the issues of Zn dendrite growth, polyiodide shuttle effect, and sluggish I-2 redox kinetics in Zn-I-2 batteries. The cathode layer with Fe nanoparticles-decorated single-wall carbon nanotubes effectively anchors polyiodide and catalyzes the redox kinetics, while the anode layer with cation exchange resin repels detrimental ions and improves the stability of cathode/anode interfaces. The Janus separator enables outstanding cycling stability and high-areal-capacity of Zn-I-2 batteries.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

Review Chemistry, Multidisciplinary

A Review on the Status and Challenges of Cathodes in Room-Temperature Na-S Batteries

Yao-Jie Lei et al.

Summary: Cathode materials for sodium-sulfur batteries have gained significant attention due to their high capacity, non-toxicity, and cost-efficiency. However, the low Coulombic efficiency and cycling decay have hindered the practical application of these batteries. The main challenges lie in the polysulfide shuttle and sluggish kinetics. This review discusses various approaches to improving cathode performance and stability, as well as the influence of cathode choices on overall battery performance. Current research challenges and future perspectives on cathodes for sodium-sulfur batteries are also addressed.

ADVANCED FUNCTIONAL MATERIALS (2023)

Article Chemistry, Multidisciplinary

Single-Atom Vanadium Catalyst Boosting Reaction Kinetics of Polysulfides in Na-S Batteries

Yu Jiang et al.

Summary: A material called 3D-PNCV, which consists of a three-dimensional nitrogen-doped hierarchical porous carbon matrix and single-atom vanadium, is designed and fabricated to enhance the reactivity of sulfur and the performance of sodium polysulfide adsorption and catalytic conversion. The as-fabricated RT Na-S batteries based on 3D-PNCV exhibit a high reversible capacity and excellent rate capability.

ADVANCED MATERIALS (2023)

Review Chemistry, Physical

Polar Electrocatalysts for Preventing Polysulfide Migration and Accelerating Redox Kinetics in Room-Temperature Sodium-Sulfur Batteries

Peiyuan Wang et al.

Summary: Due to the limitations of dissolution, shuttle effect and sluggish conversion kinetics, researchers have developed various polar catalysts to address these issues in room-temperature sodium-sulfur batteries. Polar catalysts can not only accelerate and alter the redox process, but also inhibit the shuttle effect by adsorbing polar sodium polysulfides through polar-polar interaction. This review highlights the recent advances in the electrocatalytic effect of polar catalysts on sulfur speciation pathways in room-temperature sodium-sulfur batteries and discusses the challenges and future research directions for achieving rapid and reversible sulfur conversion.

SMALL METHODS (2023)

Review Electrochemistry

High-Energy Room-Temperature Sodium-Sulfur and Sodium-Selenium Batteries for Sustainable Energy Storage

Zefu Huang et al.

Summary: Rechargeable room-temperature sodium-sulfur (Na-S) and sodium-selenium (Na-Se) batteries have attracted extensive attention for large-scale energy storage applications due to their low cost and high theoretical energy density. The optimization of electrode materials and investigation of mechanisms are crucial for achieving high energy density and long-term cycling stability of Na-S(Se) batteries.

ELECTROCHEMICAL ENERGY REVIEWS (2023)

Article Chemistry, Physical

Cellulose nanofiber-derived carbon aerogel for advanced room-temperature sodium-sulfur batteries

Wu Yang et al.

Summary: A functional separator combining lightweight three-dimensional cellulose nanofiber-derived carbon aerogel and glass fiber separator is developed to address the challenges of polysulfide diffusion and slow reaction kinetics in room-temperature sodium-sulfur batteries. The multifunctional separator exhibits strong polysulfide anchoring capability and fast reaction kinetics, as well as acts as a barrier layer and expanded current collector to enhance sulfur utilization. Experimental and theoretical results confirm the mechanism of enhancing polysulfide anchoring capability and accelerating redox kinetics through chemisorption at hetero-doped N/S sites. The Na-S coin cells assembled with this separator show high reversible capacity and superior cycling stability, demonstrating their significant potential for high-performance energy storage systems.

CARBON ENERGY (2023)

Review Chemistry, Multidisciplinary

Recent Advances of Aqueous Rechargeable Zinc-Iodine Batteries: Challenges, Solutions, and Prospects

Dun Lin et al.

Summary: Aqueous rechargeable zinc-iodine batteries (ZIBs) are considered as promising candidates for grid-scale electrochemical energy storage due to their safety, high theoretical capacity, and energy density. However, challenges such as self-discharge, sluggish kinetics, low energy density, and unstable Zn metal anodes need to be addressed. This article reviews the electrochemistry of ZIBs, discusses the fundamental questions, and highlights the key strategies and recent accomplishments in overcoming these challenges.

ADVANCED MATERIALS (2022)

Article Chemistry, Multidisciplinary

A High-Efficiency Mo2C Electrocatalyst Promoting the Polysulfide Redox Kinetics for Na-S Batteries

Xuefeng Zhou et al.

Summary: Hierarchical porous hollow carbon polyhedrons embedded with uniform Mo2C nanoparticles were designed as a host for sulfur, resulting in improved performance of room-temperature sodium-sulfur batteries. The porous carbon material enhanced reactivity and accommodated volume changes, while Mo2C inhibited polysulfide dissolution and catalyzed reaction kinetics.

ADVANCED MATERIALS (2022)

Article Chemistry, Multidisciplinary

Multifunctional Separator Allows Stable Cycling of Potassium Metal Anodes and of Potassium Metal Batteries

Pengcheng Liu et al.

Summary: This study presents a multifunctional separator for potassium-metal batteries, utilizing tape-cast microscale AlF3 coated on polypropylene. The novel separator demonstrates excellent electrochemical performance, stability, and capacity retention in experiments.

ADVANCED MATERIALS (2022)

Article Chemistry, Multidisciplinary

Ice-Assisted Synthesis of Highly Crystallized Prussian Blue Analogues for All-Climate and Long-Calendar-Life Sodium Ion Batteries

Jian Peng et al.

Summary: In this study, a facile ice-assisted strategy was developed to prepare highly crystallized Prussian blue analogues (PBAs) as cathode materials for sodium-ion batteries. By suppressing structure defects, the resulting PBAs exhibited high capacity, long cycling lifespan, and significantly enhanced high/low temperature performance.

NANO LETTERS (2022)

Article Chemistry, Multidisciplinary

Robust Room-Temperature Sodium-Sulfur Batteries Enabled by a Sandwich-Structured MXene@C/Polyolefin/MXene@C Dual-functional Separator

Chaozhi Wang et al.

Summary: A commercial polyolefin separator coated with core-shell structured MXene@C nanosheets is developed for stable room-temperature sodium-sulfur (RT-Na-S) batteries, improving the battery's capacity and cycling performance.

SMALL (2022)

Article Chemistry, Physical

An ultrathin and highly efficient interlayer for lithium-sulfur batteries with high sulfur loading and lean electrolyte

Xialu Fan et al.

Summary: The ultrathin and highly efficient BN/SWCNT interlayer material shows excellent performance in lithium-sulfur batteries, improving the efficiency of sulfur loading and diluted electrolyte, and has the potential for practical applications in the future.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

Review Multidisciplinary Sciences

The promises, challenges and pathways to room-temperature sodium-sulfur batteries

Lei Wang et al.

Summary: This article discusses the advantages, challenges, and strategies of room-temperature sodium-sulfur batteries (RT-Na-S batteries), reviews recent progress, and provides a forward-looking perspective on achieving high-energy-density and robust batteries.

NATIONAL SCIENCE REVIEW (2022)

Review Chemistry, Multidisciplinary

Nanostructure Engineering Strategies of Cathode Materials for Room-Temperature Na-S Batteries

Ye Wang et al.

Summary: Room-temperature sodium-sulfur (RT Na-S) batteries are a competitive electrochemical energy storage system. Recent studies have shown that nanostructural designs can address the challenges faced by RT Na-S batteries. This review explores the advancements in nanostructure engineering strategies of S-based cathode materials in the past decade and discusses future prospects.

ACS NANO (2022)

Review Chemistry, Multidisciplinary

Advances in the Development of Single-Atom Catalysts for High-Energy-Density Lithium-Sulfur Batteries

Ziwei Liang et al.

Summary: The practical applications of lithium-sulfur batteries face limitations due to issues like lithium dendrite growth and polysulfide shuttling, but these hurdles can be mitigated by using single-atom catalysts (SACs) to enhance electrode materials performance. This review systematically summarizes recent progress in SACs for Li-metal anodes, S cathodes, and separators, highlighting their potential to improve energy-storage devices.

ADVANCED MATERIALS (2022)

Article Chemistry, Multidisciplinary

Building a Beyond Concentrated Electrolyte for High-Voltage Anode-Free Rechargeable Sodium Batteries

Ziyang Lu et al.

Summary: Low-cost and scalable sodium ion batteries are considered as a promising alternative to lithium-ion batteries. By developing a high-voltage anode-free configuration and using a specific electrolyte design, high energy density and long lifespan can be achieved.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Article Engineering, Environmental

V2O3-decorated carbon nanofibers as a robust interlayer for long-lived, high-performance, room-temperature sodium-sulfur batteries

Rakesh Saroha et al.

Summary: A new interlayer material has been developed to improve the performance of room temperature sodium-sulfur batteries. This material inhibits the shuttling of sodium polysulfides, improves active material utilization, and accelerates reaction kinetics. Compared to conventional batteries, it exhibits higher rate performance and capacity retention.

CHEMICAL ENGINEERING JOURNAL (2022)

Review Chemistry, Multidisciplinary

Review of Multifunctional Separators: Stabilizing the Cathode and the Anode for Alkali (Li, Na, and K) Metal-Sulfur and Selenium Batteries

Hongchang Hao et al.

Summary: This article provides a critical review of the state-of-the-art in functional separators and interlayers for lithium, sodium, and potassium based metal-sulfur batteries. It discusses various approaches to improve electrochemical performance and highlights the challenges in the emerging sodium and potassium based systems. The article also explores the use of functional separators in emerging alkali metal systems based on metal-selenium and metal-selenium sulfide. The review concludes with an outlook on advanced techniques for analysis of functional separator structure and recommendations for future research topics.

CHEMICAL REVIEWS (2022)

Article Materials Science, Multidisciplinary

Inhibited shuttle effect by functional separator for room-temperature sodium-sulfur batteries

Chunwei Dong et al.

Summary: According to statistics, approximately 6 trillion cigarettes are smoked each year worldwide, resulting in around 1.2 million tons of discarded cigarette butts. This study utilizes nitrogen and sulfur co-doped carbon nanofiber/carbon black (N,S-CNF/CB) composite derived from the discarded cigarette filters to modify glass fiber (GF) separator for the first time, aiming to transform waste into wealth and reduce environmental pollution. The experiment demonstrates that a RT-Na/S battery with a N,S-CNF/CB+GF separator exhibits excellent cycling stability and rate performance.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2022)

Article Chemistry, Multidisciplinary

Long-Life Aqueous Zn-I2 Battery Enabled by a Low-Cost Multifunctional Zeolite Membrane Separator

Zhengang Li et al.

Summary: The research team developed a membrane material using zeolite molecular sieve to effectively control the diffusion of soluble iodide in zinc iodide batteries. The membrane improved the Coulombic efficiency and reversibility of the battery, while also restraining self-discharge and zinc corrosion. Furthermore, the battery showed excellent cycling stability.

NANO LETTERS (2022)

Review Chemistry, Multidisciplinary

Challenge and Strategies in Room Temperature Sodium-Sulfur Batteries: A Comparison with Lithium-Sulfur Batteries

Liang Lin et al.

Summary: Metal-sulfur batteries, including sodium-sulfur (Na-S) and lithium-sulfur (Li-S) batteries, have the potential to become next-generation rechargeable batteries. Na-S batteries are more feasible for long-term development in terms of technoeconomics and geopolitics than Li-S batteries. Although Na-S systems draw inspiration from the more mature Li-S systems, the microscopic differences between the two systems present unique challenges. This review discusses these challenges and reviews strategies for Na-S batteries, providing important insights for accelerating the development of Na-S batteries based on their dissimilarities.

SMALL (2022)

Review Chemistry, Multidisciplinary

Rational Design Strategy of Novel Energy Storage Systems: Toward High-Performance Rechargeable Magnesium Batteries

Xin Lei et al.

Summary: This review discusses recent research progress in various magnesium-based battery systems and briefly explores the optimization of electrolyte and electrode materials for traditional RMBs. By systematically summarizing different magnesium battery systems, it provides a comprehensive understanding for future exploration and development of high-performance and practical RMBs.

SMALL (2022)

Article Chemistry, Physical

Manipulating Electrocatalytic Polysulfide Redox Kinetics by 1D Core-Shell Like Composite for Lithium-Sulfur Batteries

Chuanchuan Li et al.

Summary: In this study, core-shell MoSe2@C nanorods are proposed and investigated as an electrocatalyst to accelerate polysulfide conversion in lithium-sulfur batteries. Experimental results confirm the electrocatalytic properties of MoSe2 and its influence on lithium-ion diffusion. The Li-S batteries using MoSe2 electrocatalyst exhibit excellent performance, with high specific capacity and sulfur loading.

ADVANCED ENERGY MATERIALS (2022)

Article Chemistry, Multidisciplinary

Unraveling the Conversion Evolution on Solid-State Na-SeS2 Battery via In Situ TEM

Ziqi Zhang et al.

Summary: This study unravels the basic mechanism of how Se catalyzes the conversion reaction in Na-S batteries. Real-time analysis and in situ TEM observations reveal that the incorporation of Se significantly lowers the conversion reaction barrier. These findings can be applied to optimize other S-based active materials and improve their utilization.

ADVANCED SCIENCE (2022)

Article Chemistry, Physical

Modeling of the temporal evolution of polysulfide chains within the lithium-sulfur battery

Daniel Martin Brieske et al.

Summary: The lithium-sulfur battery, a promising post lithium-ion battery technology, has attracted attention for its high specific capacity and low price. However, its commercialization progress is slow due to low performance, capacity fading, and low coulombic efficiency. In this study, a mathematical model is developed to describe the complex mechanisms of precipitation and dissolution of individual polysulfide chains. The model is validated by experimental measurements on a prototype lithium-sulfur pouch cell.

ENERGY STORAGE MATERIALS (2022)

Review Engineering, Environmental

Towards rechargeable Na-SexSy batteries: From fundamental insights to improvement strategies

Chi Feng et al.

Summary: This article provides a comprehensive review of recent advances in advanced Na-SexSy battery system, focusing on its chemistry, materials design, and potential improvement strategies. The electrochemical mechanisms, main challenges, and cathode material design strategies for Na-SexSy batteries are discussed in detail, and promising solutions are proposed to cope with existing issues. The future prospect of Na-SexSy batteries is evaluated to guide future developmental directions.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Engineering, Environmental

V2O3/VN Catalysts Decorated Free-Standing Multifunctional Interlayer for High-Performance Li-S Battery

Jie Zhao et al.

Summary: The shuttle effect caused by soluble lithium polysulfides hinders the application of lithium-sulfur batteries, but this work successfully suppresses this effect and improves reaction kinetics using a multifunctional interlayer decorated with V2O3/VN catalysts. The micro/mesopores inside the structure facilitate ion diffusion and buffer volume change during cycling, leading to promising cycling performance and high specific capacity.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Applied

Flexible PEDOT:PSS nanopapers as ?anion-cation regulation? synergistic interlayers enabling ultra-stable aqueous zinc-iodine batteries

Ying Zhang et al.

Summary: This study presents a flexible, thin, and lightweight poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) nanopaper as an anion-cation regulation synergistic interlayer for aqueous zinc-iodine (Zn-I2) batteries. The PEDOT:PSS interlayer with a 3D nanofibrous network and uniformly distributed mesopores effectively suppresses polyiodide shuttling and promotes dendrite-free zinc plating/stripping at high current densities and high areal capacities. The Zn-I2 batteries demonstrate high capacity and ultralong lifespan even at high current densities. This work highlights the potential of multifunctional interlayers for innovation in Zn-I2 battery configurations by synergistic regulation of cations and anions at the electrodes/electrolyte interface.

JOURNAL OF ENERGY CHEMISTRY (2022)

Review Chemistry, Multidisciplinary

Understanding the Catalytic Kinetics of Polysulfide Redox Reactions on Transition Metal Compounds in Li-S Batteries

Jiao Wu et al.

Summary: Lithium-sulfur (Li-S) batteries are potential candidates for next-generation energy-storage devices due to their high energy density, low cost, and environmental friendliness. However, issues such as sluggish reaction kinetics and capacity degradation have hindered their development. The introduction of transition metal compounds (TMCs) as catalysts has overcome these challenges. The recent advances in TMC catalysts and design strategies for Li-S batteries are summarized.

ACS NANO (2022)

Article Chemistry, Multidisciplinary

Azo-Branched Covalent Organic Framework Thin Films as Active Separators for Superior Sodium-Sulfur Batteries

Congcong Yin et al.

Summary: This study successfully addresses the issues of polysulfide shuttle effect and sluggish redox kinetics in Na-S batteries by synthesizing thin films of covalent organic frameworks. It demonstrates the possibility of high-performance energy storage systems through the functionalizable framework materials.

ACS NANO (2022)

Review Chemistry, Multidisciplinary

Rechargeable Iodine Batteries: Fundamentals, Advances, and Perspectives

Shuo Yang et al.

Summary: This review provides a comprehensive overview of the fundamental chemistry of rechargeable iodine batteries (RIBs), discussing their physicochemical properties, conversion mechanism, and existing issues. It further refines optimization strategies for high-performance RIBs and compares the pros and cons of various RIBs. Ultimately, remaining challenges and perspectives for the construction of next-generation RIBs are concluded.

ACS NANO (2022)

Article Chemistry, Multidisciplinary

Hydrogen-Bonded Organic Framework for High-Performance Lithium/Sodium-Iodine Organic Batteries

Chaofei Guo et al.

Summary: A flexible hydrogen-bonded organic framework (HOF) has been developed for iodine loading, which can accelerate the reaction kinetics and improve the cycling stability of iodide-based batteries.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Review Chemistry, Physical

Sulfur Reduction Reaction in Lithium-Sulfur Batteries: Mechanisms, Catalysts, and Characterization

Lei Zhou et al.

Summary: Lithium-sulfur batteries have great potential but suffer from sluggish sulfur reduction reaction (SRR) kinetics, leading to poor sulfur utilization and impaired electrochemical performance. This review examines the critical issues of SRR in Li-S batteries, including the conversion mechanisms, reaction pathways, and recent advances in catalyst materials. Various characterization approaches for SRR are also discussed.

ADVANCED ENERGY MATERIALS (2022)

Article Chemistry, Applied

Effect of specifically-adsorbed polysulfides on the electron transfer kinetics of sodium metal anodes

Huazhao Yang et al.

Summary: This study investigates the mechanism of sodium polysulfides on the kinetics of sodium plating/stripping in room-temperature sodium-sulfur batteries. It reveals the specific adsorption of polysulfides on the sodium electrode surface and describes the kinetics using the Marcus model. Higher-order polysulfides exhibit distinct adsorption behaviors that can either accelerate or slow down the kinetics. This competitive relationship allows low concentrations of high-order polysulfides to stimulate the kinetics.

JOURNAL OF ENERGY CHEMISTRY (2022)

Article Chemistry, Physical

Dual-functional hosts derived from metal-organic frameworks reduce dissolution of polyselenides and inhibit dendrite growth in a sodium-selenium battery

Peng Hu et al.

Summary: A novel approach using new materials for the cathode and anode of sodium-selenium batteries effectively addresses issues such as low reactivity of selenium in sodium batteries and the "shuttle effect", resulting in improved cycle stability and safety.

ENERGY STORAGE MATERIALS (2022)

Article Engineering, Environmental

Ce(NO3)4: A dual-functional electrolyte additive for room-temperature sodium-sulfur batteries

Liwei Su et al.

Summary: This study investigates the influence of a novel dual-functional additive on the performance of room-temperature sodium-sulfur batteries. The results show that the additive can inhibit side reactions and shuttle effect, thereby improving the cycle stability of the battery.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Multidisciplinary

A lignin-derived flexible porous carbon material for highly efficient polyselenide and sodium regulation

Linchao Zeng et al.

Summary: This study reveals the catalytic effect of atomic Fe on the conversion of polyselenides to Na2Se and successfully prepares a flexible carbon-based material loaded with atomic Fe as a selenium host. The research also finds that atomic Fe has a beneficial effect on the deposition of sodium at the anode.

NANOSCALE (2022)

Article Chemistry, Multidisciplinary

A flexible, ceramic-rich solid electrolyte for room-temperature sodium-sulfur batteries

Guruprasad S. Hegde et al.

Summary: A sodium superionic conductor, Na3Zr2Si2PO12 (NZSP) ceramic, has the potential to solve safety and energy density problems in sodium-based batteries. Researchers have developed a method to produce a thin and flexible polymer in ceramic type sodium ion conductor film and demonstrated its application in room temperature sodium-sulfur batteries.

CHEMICAL COMMUNICATIONS (2022)

Review Electrochemistry

Electrolyte Measures to Prevent Polysulfide Shuttle in Lithium-Sulfur Batteries

Graziano Di Donato et al.

Summary: This review discusses the role of electrolytes in Li-S batteries, focusing on the main issues and solutions for the shuttle mechanism of polysulfides and the instability of the interface with lithium metal.

BATTERIES & SUPERCAPS (2022)

Article Chemistry, Physical

Redox catalysis-promoted fast iodine kinetics for polyiodide-free Na-I2 electrochemistry

Hong Zhang et al.

Summary: This study presents a superior polyiodide-free Na-I-2 battery, utilizing a unique catalyst to achieve fast and reversible iodine conversion, resulting in improved cycling stability and rate capability.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

Article Chemistry, Physical

Bifunctional Catalyst for Liquid-Solid Redox Conversion in Room-Temperature Sodium-Sulfur Batteries

Jiahui Wu et al.

Summary: Room-temperature sodium-sulfur (RT Na-S) batteries are a promising energy storage system due to their high energy density and abundant sodium reserve. However, the poor rate performance and unsatisfactory capacity of these batteries have hindered their practical application. In this study, a bifunctional catalyst was designed to overcome these challenges by combining strong adsorption capability and high catalytic activity. The resulting sulfur cathode achieved high initial capacity, long cycling stability, and outstanding rate capability, demonstrating the potential for high-performance RT Na-S batteries.

SMALL STRUCTURES (2022)

Article Chemistry, Physical

The chain-mail Co@C electrocatalyst accelerating one-step solid-phase redox for advanced Li-Se batteries

Wen-Da Dong et al.

Summary: A novel Li-Se battery cathode material utilizing chain-mail Co@C nanoparticles embedded in porous carbon nanofibers demonstrated high capacity, cycling stability, and rate performance, addressing issues like volume variation and sluggish redox kinetics associated with traditional materials.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

Article Chemistry, Multidisciplinary

Ultrathin Conductive Interlayer with High-Density Antisite Defects for Advanced Lithium-Sulfur Batteries

Danqi He et al.

Summary: A new strategy based on intrinsic point defects of materials is proposed in this study to enhance the electrical conductivity of active material and regulate the migration of polysulfides in Li-S batteries. By utilizing ultrathin and lightweight BTS interlayers with high-density antisite defects, the battery shows improved capacity and low capacity decay rate over cycles. Defect engineering strategy along with facile method holds promise for the practical application of advanced Li-S batteries.

ADVANCED FUNCTIONAL MATERIALS (2021)

Review Chemistry, Physical

Inhibition of Polysulfide Shuttles in Li-S Batteries: Modified Separators and Solid-State Electrolytes

Shulian Li et al.

Summary: Lithium-sulfur batteries have high theoretical specific capacity, but face challenges such as the polysulfide shuttle effect. To address this issue, researchers have developed functional coatings inhibiting the migration of polysulfides and solid-state electrolytes.

ADVANCED ENERGY MATERIALS (2021)

Review Chemistry, Multidisciplinary

Advances in Natural Biopolymer-Based Electrolytes and Separators for Battery Applications

Erlantz Lizundia et al.

Summary: Rechargeable batteries are projected to play a significant role in the future energy landscape, but the strain on raw material resources poses a challenge. Researchers are exploring renewable resource derived biodegradable materials, such as natural biopolymers, as a sustainable and eco-friendly alternative for future batteries.

ADVANCED FUNCTIONAL MATERIALS (2021)

Review Chemistry, Multidisciplinary

Iodine Redox Chemistry in Rechargeable Batteries

Jizhen Ma et al.

Summary: This article discusses the potential and challenges of combining halogens with metal anodes in a single cell to develop novel rechargeable batteries, emphasizing the importance of understanding the fundamental reactions of iodine/polyiodide for designing high-performance cathodes. Special focus is placed on the basic principles of iodine redox chemistry and its correlation with structure-function relationships.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Porous Heteroatom-Doped Ti3C2Tx MXene Microspheres Enable Strong Adsorption of Sodium Polysulfides for Long-Life Room-Temperature Sodium-Sulfur Batteries

Weizhai Bao et al.

Summary: The study presents a design strategy using Ti3C2Tx MXene for encapsulation of sodium polysulfides to enhance the performance of sodium-sulfur batteries, demonstrating outstanding electrochemical performances with high reversible capacity and extended cycling stability.

ACS NANO (2021)

Review Chemistry, Multidisciplinary

Cation-Selective Separators for Addressing the Lithium-Sulfur Battery Challenges

Qing Zhao et al.

Summary: Research shows that constructing cation-selective separators is an effective strategy to control anion transport and address two critical issues in lithium-sulfur batteries simultaneously. While significant progress has been made in inhibiting the shuttle effect, addressing the problem of Li dendrite formation is still under exploration.

CHEMSUSCHEM (2021)

Article Engineering, Environmental

Hybrid thermoelectrochemical and concentration cells for harvesting low-grade waste heat

Kyunggu Kim et al.

Summary: The hybrid thermoelectrochemical and concentration cell (i-TCC) based on carbonate solvents outperforms current n-type TECs, showing high Seebeck coefficient, figure of merit, and Carnot efficiency at temperatures above 40 degrees Celsius. It provides a new perspective in harvesting low-grade waste heat.

CHEMICAL ENGINEERING JOURNAL (2021)

Review Chemistry, Physical

Boosting Energy Storage via Confining Soluble Redox Species onto Solid-Liquid Interface

Shuo Sun et al.

Summary: This review article discusses the current advances in confining soluble redox species (SRSs) in energy storage systems through solid-liquid interfacial manipulation at the atomic/molecular level. Successful examples of immobilization mechanisms of SRSs around electrode materials are highlighted, along with outlining promising research avenues and challenges in interfacial manipulations. The aim is to facilitate vertical leaps in the performance of next-generation energy storage systems.

ADVANCED ENERGY MATERIALS (2021)

Article Chemistry, Physical

Sodium-Sulfur Batteries Enabled by a Protected Inorganic/Organic Hybrid Solid Electrolyte

Yuxun Ren et al.

Summary: In this study, an in situ cross-linking reaction was used to embed sodium thioantimonate in a protective polymer host, forming a flexible hybrid electrolyte film. This hybrid solid electrolyte successfully protected the sodium metal and enabled the stable operation of a sodium-sulfur battery.

ACS ENERGY LETTERS (2021)

Article Chemistry, Physical

Frontiers for Room-Temperature Sodium-Sulfur Batteries

Shipeng Zhang et al.

Summary: Room-temperature sodium-sulfur (Na-S) systems have emerged as a promising technology in new battery technologies beyond the lithium-ion battery era. This Perspective discusses the fundamental challenges, optimization strategies, and correlation between components and electrochemistry for improved performance. Highlighted pivotal research directions provide fundamental guidelines for the practical application of RT Na-S systems.

ACS ENERGY LETTERS (2021)

Review Chemistry, Multidisciplinary

An Emerging Energy Storage System: Advanced Na-Se Batteries

Xiang Long Huang et al.

Summary: Sodium-selenium (Na-Se) batteries have attracted significant attention due to the large abundance of sodium and the high electronic conductivity and volumetric capacity of selenium. Major advancements have been made in electrode materials design, particularly in Se-based cathode materials. The challenges and strategies for improving the electrochemical performance of Na-Se batteries have been systematically summarized and discussed.

ACS NANO (2021)

Article Engineering, Environmental

Designing dual-defending system based on catalytic and kinetic iron Pyrite@C hybrid fibers for long-life room-temperature sodium-sulfur batteries

Hongmei Wang et al.

Summary: By utilizing a dual-polysulfide-defending system and hierarchical polar electrodes, the RT-Na/S battery achieves superior performance and long-term stability.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Chemistry, Multidisciplinary

Ion Selective Covalent Organic Framework Enabling Enhanced Electrochemical Performance of Lithium-Sulfur Batteries

Yu Cao et al.

Summary: The authors successfully fabricated an ion selective TpPa-SO3Li film on a commercial separator, with aligned nanochannels and continuous negatively charged sites to facilitate lithium ion conduction and suppress polysulfide diffusion. When using this novel functional layer, Li-S batteries exhibited high initial capacity and retention rate.

NANO LETTERS (2021)

Article Nanoscience & Nanotechnology

Understanding Sulfur Redox Mechanisms in Different Electrolytes for Room-Temperature Na-S Batteries

Hanwen Liu et al.

Summary: This study investigates the influence of carbonate ester and ether electrolytes on the sulfur redox reactions in room-temperature Na-S batteries. It is found that using ether electrolyte with NaNO3 additive can improve the reversible capacity of the sulfur-rich cathode, providing a new strategy for the application of high-loading sulfur cathodes.

NANO-MICRO LETTERS (2021)

Article Chemistry, Applied

Lignin derived hierarchical porous carbon with extremely suppressed polyselenide shuttling for high-capacity and long-cycle-life lithium-selenium batteries

Pengfei Lu et al.

Summary: A low-cost strategy for scalable fabrication of lignin derived hierarchical porous carbon (LHPC) as a new high-loading Se host for high-capacity and long-term cycling Li-Se batteries is reported. The resulting LHPC exhibits a three-dimensional hierarchically porous structure, high specific surface area, and hetero-atom doping, which effectively confine Se particles and offer chemical binding sites. Li-Se batteries based on Se@LHPC demonstrate high capacity and low capacity fading rate, with theoretical simulation confirming the strong affinity of selenides on LHPC sites effectively mitigating Se losing. This strategy offers new opportunities for high-capacity and long-life Li-Se batteries.

JOURNAL OF ENERGY CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Single-Atom Zinc and Anionic Framework as Janus Separator Coatings for Efficient Inhibition of Lithium Dendrites and Shuttle Effect

Chun-Lei Song et al.

Summary: This study presents a Janus separator prepared with anionic metal-organic framework and single-atom zinc catalyst, which effectively inhibits the dendrite growth and shuttle effect of Li-S batteries. The results show stable cyclic performance and outstanding protection capability, making it suitable for various types of Li-S or Li-Se batteries.

ACS NANO (2021)

Article Chemistry, Multidisciplinary

Architecting Freestanding Sulfur Cathodes for Superior Room-Temperature Na-S Batteries

Huiling Yang et al.

Summary: In this study, it is demonstrated that a chain-mail catalyst Co@PCNFs can activate sulfur and improve the reaction kinetics in room-temperature sodium-sulfur batteries. The freestanding sulfur cathode constructed with Co@PCNFs achieves high reversible capacity and superior rate capability. This is attributed to efficient electron transfer between the polysulfides and Na2S enabled by the Co@PCNFs, enhancing sulfur redox reactions.

ADVANCED FUNCTIONAL MATERIALS (2021)

Review Chemistry, Multidisciplinary

Wide Working Temperature Range Rechargeable Lithium-Sulfur Batteries: A Critical Review

Zhenfang Zhou et al.

Summary: Lithium sulfur batteries, with their ultrahigh theoretical gravimetric energy density and low cost and environmental friendliness, are being further developed to operate at a wide range of temperatures. Challenges in material performance, electrolytes, lithium metal anodes, and the impact of thermal changes are key areas for future research directions in enabling lithium sulfur batteries to function effectively in extreme temperature conditions.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Chemistry, Multidisciplinary

Size Effect of Organosulfur and In Situ Formed Oligomers Enables High-Utilization Na-Organosulfur Batteries

Shuai Tang et al.

Summary: Organosulfurs exhibit promising performance in room-temperature rechargeable sodium batteries, especially with the use of sodiated Nafion membranes, leading to significantly improved performances.

ADVANCED MATERIALS (2021)

Article Multidisciplinary Sciences

Atomic-scale regulation of anionic and cationic migration in alkali metal batteries

Pan Xiong et al.

Summary: Regulating the transport of anions and cations at the atomic scale is crucial in membrane-based separation technologies and the development of high-performance alkali metal batteries. The use of negatively charged Ti0.87O2 nanosheets coated polypropylene separators can reduce the non-uniform transport of alkali metal ions and detrimental shuttling effect of anions, ensuring homogeneous ion flux and promoting fast alkali-ion diffusion.

NATURE COMMUNICATIONS (2021)

Article Multidisciplinary Sciences

Realizing high-power and high-capacity zinc/sodium metal anodes through interfacial chemistry regulation

Zhen Hou et al.

Summary: The study successfully achieved dendrite-free zinc morphologies and superior cycling stability under high current densities and large cycling capacities by regulating the separator's interfacial chemistry through tin coating. This approach suppressed dendrite initiation and ensured smooth zinc metal deposition, offering a promising route to overcome challenges associated with metal anodes.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Physical

Generating Short-Chain Sulfur Suitable for Efficient Sodium-Sulfur Batteries via Atomic Copper Sites on a N,O-Codoped Carbon Composite

Fengping Xiao et al.

Summary: A stable sulfur host with single-atom copper catalysts derived from a bimetallic Cu-Zn metal-organic framework is reported, which significantly improves the performance of sulfur-loaded carbon framework used as a cathode in sodium-sulfur batteries, exhibiting superior capacity and rate performance.

ADVANCED ENERGY MATERIALS (2021)

Review Materials Science, Multidisciplinary

Boosting electrochemical kinetics of S cathodes for room temperature Na/S batteries

Fan Jin et al.

Summary: Room temperature (RT) Na/S battery system is considered as one of the best energy storage systems due to its low cost and high energy density, but it still faces issues such as shuttle effect and low conversion efficiency. Various strategies have been adopted to enhance the electrochemical kinetics of S cathodes in RT-Na/S batteries, aiming to accelerate the redox process and mitigate the shuttle effect.

MATTER (2021)

Article Chemistry, Physical

Enabling high-performance room-temperature sodium/sulfur batteries with few-layer 2H-MoSe2 embellished nitrogen-doped hollow carbon spheres as polysulfide barriers

Chunwei Dong et al.

Summary: This study presents a functional separator to suppress the shuttle effect in Room-temperature sodium/sulfur batteries, demonstrating a promising path for high-performance RT-Na/S batteries.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Chemistry, Physical

High-performance metal-iodine batteries enabled by a bifunctional dendrite-free Li-Na alloy anode

Donglin Yu et al.

Summary: The bifunctional Li-Na alloy-CC anode developed in this research demonstrated significantly enhanced electrochemical performance and ultra-stable cycling stability in Li/Na-iodine batteries, offering new perspectives for developing dendrite-free alkali metal-iodine batteries.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Chemistry, Multidisciplinary

Remedies for Polysulfide Dissolution in Room-Temperature Sodium-Sulfur Batteries

Yun-Xiao Wang et al.

ADVANCED MATERIALS (2020)

Review Chemistry, Multidisciplinary

Lithium-Ion Battery Separators for Ionic-Liquid Electrolytes: A Review

Candice F. J. Francis et al.

ADVANCED MATERIALS (2020)

Article Chemistry, Physical

Interface Engineering of MXene Composite Separator for High-Performance Li-Se and Na-Se Batteries

Fan Zhang et al.

ADVANCED ENERGY MATERIALS (2020)

Article Chemistry, Multidisciplinary

Polyolefin-Based Janus Separator for Rechargeable Sodium Batteries

Dong Zhou et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Lewis Acid-Base Interactions between Polysulfides and Boehmite Enables Stable Room-Temperature Sodium-Sulfur Batteries

Arnab Ghosh et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

Review Chemistry, Physical

Recent advances in electrolytes for room-temperature sodium-sulfur batteries: A review

Mohanjeet Singh Syali et al.

ENERGY STORAGE MATERIALS (2020)

Review Chemistry, Multidisciplinary

Revitalising sodium-sulfur batteries for non-high-temperature operation: a crucial review

Yizhou Wang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Article Chemistry, Physical

Atomic-scale identification of influencing factors of sodium dendrite growth on different current collectors

Mengting Li et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Review Materials Science, Multidisciplinary

Two-dimensional MXenes for lithium-sulfur batteries

Chuanfang (John) Zhang et al.

INFOMAT (2020)

Article Chemistry, Multidisciplinary

Facile-Processed Nanocarbon-Promoted Sulfur Cathode for Highly Stable Sodium-Sulfur Batteries

Xiaofei Hu et al.

CELL REPORTS PHYSICAL SCIENCE (2020)

Article Chemistry, Multidisciplinary

Strong Surface Bonding of Polysulfides by Teflonized Carbon Matrix for Enhanced Performance in Room Temperature Sodium-Sulfur Battery

Ajay Piriya Vijaya Kumar Saroja et al.

ADVANCED MATERIALS INTERFACES (2019)

Article Chemistry, Multidisciplinary

A Robust, Freestanding MXene-Sulfur Conductive Paper for Long-Lifetime Li-S Batteries

Huan Tang et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

Review Chemistry, Multidisciplinary

Sodium Metal Anodes: Emerging Solutions to Dendrite Growth

Byeongyong Lee et al.

CHEMICAL REVIEWS (2019)

Article Materials Science, Multidisciplinary

High energy density lithium-selenium batteries enabled by a covalent organic framework-coated separator

Liping Si et al.

MATERIALS LETTERS (2019)

Article Multidisciplinary Sciences

A safe and non-flammable sodium metal battery based on an ionic liquid electrolyte

Hao Sun et al.

NATURE COMMUNICATIONS (2019)

Article Chemistry, Physical

Iodine encapsulated in mesoporous carbon enabling high-efficiency capacitive potassium-Ion storage

Mengmeng Qian et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2019)

Article Chemistry, Multidisciplinary

Design and Construction of Sodium Polysulfides Defense System for Room-Temperature Na-S Battery

Tingting Yang et al.

ADVANCED SCIENCE (2019)

Article Chemistry, Multidisciplinary

Repelling Polysulfides Using White Graphite Introduced Polymer Membrane as a Shielding Layer in Ambient Temperature Sodium Sulfur Battery

Ajay Piriya Vijaya Kumar Saroja et al.

ADVANCED MATERIALS INTERFACES (2019)

Article Chemistry, Physical

Jackfruit-like electrode design for advanced Na-Se batteries

Qiuju Xu et al.

JOURNAL OF POWER SOURCES (2019)

Review Chemistry, Physical

Interlayer Material Selection for Lithium-Sulfur Batteries

Linlin Fan et al.

JOULE (2019)

Article Chemistry, Physical

Rechargeable potassium-ion batteries enabled by potassium-iodine conversion chemistry

Ke Lu et al.

ENERGY STORAGE MATERIALS (2019)

Article Chemistry, Multidisciplinary

Rational Design of Nanostructured Functional Interlayer/Separator for Advanced Li-S Batteries

Yo Chan Jeong et al.

ADVANCED FUNCTIONAL MATERIALS (2018)

Article Chemistry, Multidisciplinary

A Stable Quasi-Solid-State Sodium-Sulfur Battery

Dong Zhou et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Chemistry, Physical

Remedies of capacity fading in room-temperature sodium-sulfur batteries

Y. X. Ren et al.

JOURNAL OF POWER SOURCES (2018)

Article Multidisciplinary Sciences

A room-temperature sodium-sulfur battery with high capacity and stable cycling performance

Xiaofu Xu et al.

NATURE COMMUNICATIONS (2018)

Article Chemistry, Multidisciplinary

Constructing Universal Ionic Sieves via Alignment of Two-Dimensional Covalent Organic Frameworks (COFs)

Cheng Jiang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Chemistry, Multidisciplinary

High Energy Density CNT/NaI Composite Cathodes for Sodium-Ion Batteries

Sanghyeon Kim et al.

ADVANCED MATERIALS INTERFACES (2018)

Article Chemistry, Physical

An Iodine Quantum Dots Based Rechargeable Sodium-Iodine Battery

Decai Gong et al.

ADVANCED ENERGY MATERIALS (2017)

Article Chemistry, Physical

Investigation of the Effect of Using Al2O3-Nafion Barrier on Room-Temperature Na-S Batteries

Elif Ceylan Cengiz et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2017)

Article Chemistry, Multidisciplinary

Reduced Graphene Oxide/LiI Composite Lithium Ion Battery Cathodes

Sanghyeon Kim et al.

NANO LETTERS (2017)

Article Multidisciplinary Sciences

A rechargeable iodine-carbon battery that exploits ion intercalation and iodine redox chemistry

Ke Lu et al.

NATURE COMMUNICATIONS (2017)

Review Chemistry, Multidisciplinary

Sodium-ion batteries: present and future

Jang-Yeon Hwang et al.

CHEMICAL SOCIETY REVIEWS (2017)

Article Nanoscience & Nanotechnology

Porous Carbon Paper as Interlayer to Stabilize the Lithium Anode for Lithium-Sulfur Battery

Ling-Long Kong et al.

ACS APPLIED MATERIALS & INTERFACES (2016)

Article Chemistry, Multidisciplinary

Electrochemistry of Selenium with Sodium and Lithium: Kinetics and Reaction Mechanism

Qianqian Li et al.

ACS NANO (2016)

Article Electrochemistry

Na Reactivity toward Carbonate-Based Electrolytes: The Effect of FEC as Additive

R. Dugas et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2016)

Article Multidisciplinary Sciences

A stable room-temperature sodium-sulfur battery

Shuya Wei et al.

NATURE COMMUNICATIONS (2016)

Article Chemistry, Multidisciplinary

Ambient Temperature Sodium-Sulfur Batteries

Arumugam Manthiram et al.

SMALL (2015)

Article Multidisciplinary Sciences

Ambipolar zinc-polyiodide electrolyte for a high-energy density aqueous redox flow battery

Bin Li et al.

NATURE COMMUNICATIONS (2015)

Article Chemistry, Multidisciplinary

A High-Energy Room-Temperature Sodium-Sulfur Battery

Sen Xin et al.

ADVANCED MATERIALS (2014)

Article Chemistry, Multidisciplinary

Shuttle suppression in room temperature sodium-sulfur batteries using ion selective polymer membranes

I. Bauer et al.

CHEMICAL COMMUNICATIONS (2014)

Review Chemistry, Multidisciplinary

Rechargeable Lithium-Sulfur Batteries

Arumugam Manthiram et al.

CHEMICAL REVIEWS (2014)

Article Chemistry, Physical

Highly Reversible Room-Temperature Sulfur/Long-Chain Sodium Polysulfide Batteries

Xingwen Yu et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2014)

Article Chemistry, Multidisciplinary

Selenium@Mesoporous Carbon Composite with Superior Lithium and Sodium Storage Capacity

Chao Luo et al.

ACS NANO (2013)

Article Chemistry, Multidisciplinary

Sodium-Ion Batteries

Michael D. Slater et al.

ADVANCED FUNCTIONAL MATERIALS (2013)

Review Chemistry, Multidisciplinary

Room-temperature stationary sodium-ion batteries for large-scale electric energy storage

Huilin Pan et al.

ENERGY & ENVIRONMENTAL SCIENCE (2013)

Article Chemistry, Multidisciplinary

A New Class of Lithium and Sodium Rechargeable Batteries Based on Selenium and Selenium-Sulfur as a Positive Electrode

Ali Abouimrane et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Review Multidisciplinary Sciences

Opportunities and challenges for a sustainable energy future

Steven Chu et al.

NATURE (2012)

Article Electrochemistry

Room-temperature solid-state sodium/sulfur battery

CW Park et al.

ELECTROCHEMICAL AND SOLID STATE LETTERS (2006)