Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 56, Pages 11286-11289Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc02539g
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- Science and Industry Endowment Fund (SIEF)
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A combined experimental and computational study has revealed the interplay between the framework pore size and functionality on the CO2 adsorption performance of zirconium-based MIL-140 frameworks. The CO2-sorbent interactions were markedly influenced by pore-confinement effects which arise from the pi-stacked arrangement of the ligands within the framework backbone.
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