Journal
ACS NANO
Volume 17, Issue 20, Pages 19767-19778Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsnano.3c03693
Keywords
smart windows; cellulose nanofibers; nanoporousnetwork; liquid crystals; emergent nematic domains; ultrahigh haziness
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Glazing products with tunable optical properties have great potential for energy efficiency and privacy features. A new approach called Haze-Switch, based on a gel material and liquid crystal, allows for low-voltage tuning of haze coefficient, meeting the stringent requirements for window products.
Being key components of the building envelope, glazing products with tunable optical properties are in great demand because of their potential for boosting energy efficiency and privacy features while enabling the main function of allowing natural light indoors. However, windows and skylights with electric switching of haze and transparency are rare and often require high voltages or electric currents, as well as not fully meet the stringent technical requirements for glazing applications. Here, by introducing a predesigned gel material we describe an approach dubbed Haze-Switch that involves low-voltage tuning of the haze coefficient in a broad range of 2-90% while maintaining high visible-range optical transmittance. The approach is based on a nanocellulose fiber gel network infiltrated by a nematic liquid crystal, which can be switched between polydomain and monodomain spatial patterns of optical axis via a dielectric coupling between the nematic domains and the applied external electric field. By utilizing a nanocellulose network of nanofibers similar to 10 nm in diameter we achieve <10 V dielectric switching and <2% haze in the clear state, as needed for applications in window products. We characterize physical properties relevant to window and smart glass technologies, like the color rendering index, haze coefficient, and switching times, demonstrating that our material and envisaged products can meet the stringent requirements of the glass industry, including applications such as privacy windows, skylights, sunroofs, and daylighting.
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