Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 52, Pages 10447-10450Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc03070f
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Funding
- National Science Foundation Materials Interdisciplinary Research Team (MIRT) [DMR-1122603]
- Welch Foundation [F-1254]
- Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. Department of Energy
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Herein, we report the synthesis, structure, and electrochemistry of the first Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19. The Fe-based cathode has a reversible capacity of ca. 70 mA h g(-1); ca. 1.7 Na+ ions per formula can be inserted/extracted at an average voltage of 2.5 V versus Na+/Na.
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