Related references
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Article
Chemistry, Multidisciplinary
Congcong Liu et al.
Summary: Phytic acid and phytic acid dipotassium can passivate defects in perovskite film, improving the efficiency and stability of perovskite solar cells. The addition of phytic acid dipotassium enhances the quality of perovskite film by promoting the coordination of phosphate groups and passivating halide anion defects. This study provides insights into designing multifunctional passivators for enhancing the efficiency and stability of devices.
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(2023)
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Summary: Efficient modification of the interface between metal cathode and electron transport layer using alcohol-soluble rhodamine-functionalized dodecahydro-closo-dodecaborate derivate RBH improves the performance and stability of inverted perovskite solar cells. RBH acts as an efficient cathode interlayer that overcomes the issues at the PCBM/Ag interface, resulting in a high power conversion efficiency of 21.08% and a high fill factor of 83.37%.
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(2023)
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Zhiteng Wang et al.
Summary: Research has found that halide-related surface defects on inorganic halide perovskite can lead to charge recombination and affect the long-term stability of perovskite solar cells. Using density functional theory calculation, it has been verified that iodine interstitials (I-i) have a low formation energy and are easily formed on the surface of all-inorganic perovskite. A specific passivator called 2,6-diaminopyridine (2,6-DAPy) has been screened, which successfully eliminates iodine interstitials, dissociative iodine molecules, and passivates iodine vacancies. This passivation process improves the power-conversion efficiency (PCE) and environmental stability of the perovskite solar cells.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Multidisciplinary Sciences
Wei Peng et al.
Summary: Inserting an ultrathin low-conductivity interlayer between the absorber and transport layer is an effective strategy for improving the efficiency of perovskite solar cells. However, there is a trade-off between the open-circuit voltage and fill factor. In this study, the challenge was overcome by introducing a thick insulator layer with random nanoscale openings. With this approach, an efficiency of up to 25.5% was achieved, along with reduced surface recombination and improved perovskite crystallinity.
Article
Multidisciplinary Sciences
Shuo Zhang et al.
Summary: In this study, an amphiphilic molecular hole transporter with a multifunctional cyanovinyl phosphonic acid group was used to deposit a superwetting underlayer for perovskite deposition. This enabled the formation of high-quality perovskite films with minimized defects at the buried interface. The resulting perovskite film showed excellent photoluminescence properties and achieved a certified PCE of 25.4%, demonstrating its potential for application in solar cells.
Article
Chemistry, Physical
Haoxin Wang et al.
Summary: An interfacial modification strategy using 6FPPY, a multi-fluorine organic molecule, is proposed to improve the NiOx/perovskite interface. The modified p-i-n PSCs with 6FPPY achieve a champion PCE of 24.0% and demonstrate better stability than the reference device under illumination and storage conditions.
Article
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Lijuan He et al.
Summary: A multifunctional additive, 4-amino-2,3,5,6-tetrafluorobenzoic acid (ATFBA), is used to improve the stability and performance of Sn-Pb perovskite photodetectors. ATFBA passivates surface defects and inhibits the oxidation of Sn2+ through hydrogen bonds and chelation coordination. The photodetector exhibits a high responsivity of 0.52 A W-1 and a specific detectivity of 5.34 x 10(12) Jones at 850 nm, remaining 97% of its initial responsivity over 450 days. Integrated into a pulse oximetry sensor visualization system, the photodetector accurately measures blood oxygen saturation and heart rate with less than 2% error.
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(2023)
Article
Chemistry, Multidisciplinary
Chenzhe Xu et al.
Summary: By modifying the interface molecules for CsPbI3 perovskite, the electron transfer barrier is reduced and the crystal quality is improved, resulting in a decrease of trap-assisted charge recombination and interfacial energetic loss. As a result, the devices achieve an impressive efficiency of 20.98% and a record-low V-OC deficit of 0.451 V.
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(2023)
Article
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You Ke et al.
Summary: Bright and efficient deep-red LEDs are crucial for medical therapy and biological imaging. However, achieving high brightness deep-red perovskite-based LEDs has been a challenge. This study demonstrates a lateral Cs4PbI6/FA(x)Cs(1-)(x)PbI(3) (0D/3D) heterostructure that enables highly efficient deep-red perovskite LEDs. These LEDs exhibit a peak external quantum efficiency of 21.0% at a significantly higher photon flux than previously reported.
ADVANCED MATERIALS
(2023)
Review
Nanoscience & Nanotechnology
Ik Jae Park et al.
Summary: With metal halide perovskite-based solar cells achieving a photovoltaic performance of approximately 26% and approaching the theoretical Shockley-Queisser limit, researchers are now focusing on tandem solar cells that use perovskite materials to achieve high efficiency. However, interfacial issues and difficulties in fabricating solution-processed perovskite top cells pose challenges for achieving high efficiency and stability. This paper provides a summary and review of the fundamentals and strategies to overcome these issues in tandem solar cells.
Article
Engineering, Environmental
Chuanming Tian et al.
Summary: This study introduces a multifunctional additive, 2-BTFSIP, to achieve defect passivation and crystallization control in perovskite films, leading to significantly improved performance and stability of perovskite solar cells.
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(2023)
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Yitian Du et al.
Summary: Sodium bicarbonate is used as an additive in perovskite solar cells to improve the formation of perovskite film and enhance the crystallinity and grain structure, resulting in improved device efficiency and stability.
Article
Chemistry, Multidisciplinary
Zhuang Xiong et al.
Summary: In this study, a multifunctional interfacial material, BGCl, was introduced to modify the interface of perovskite solar cells. The BGCl improved electron extraction and crystal growth of perovskite by chemically linking to SnO2 and anchoring PbI2. This modification led to better energetic alignment, reduced interfacial defects, and homogeneous perovskite crystallites, resulting in highly efficient and stable performance.
ADVANCED MATERIALS
(2022)
Article
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Zhi-Wen Gao et al.
Summary: The presence of interface defects in perovskite solar cells hinders their efficiency and stability. However, a multifunctional ion-lock layer can effectively reduce these defects, adjust the work function, and improve the performance and stability of the cells.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Review
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Pilik Basumatary et al.
Summary: Compared to other solar cells, the performance of hybrid metal halide perovskite-based solar cells has shown exceptional improvement. This is attributed to the evolution of device structure, development of absorber layer materials and charge selective layers, as well as advancements in device fabrication techniques targeting the improvement of perovskite film morphology, crystallinity, composition, and interface properties.
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(2022)
Article
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Zhen Li et al.
Summary: Functionalizing the interfaces of multication and halide perovskite solar cells with an organometallic compound, ferrocenyl-bis-thiophene-2-carboxylate (FcTc(2)), enhances their efficiency and stability. The resulting devices exhibit high performance and stability, as demonstrated by tests and continuous operation.
Article
Chemistry, Multidisciplinary
Hengkai Zhang et al.
Summary: A new strategy of heterogeneous seeding-induced crystallization (hetero-SiC) is proposed in this study to assist the growth of FAPbI(3)-based perovskite, which significantly improves film quality, reduces defects, and enhances stability under light illumination. The hetero-SiC process leads to outstanding performance in perovskite solar cells, with a power conversion efficiency of 24.0% and retention of 84% of initial performance after 1400 h of light illumination.
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(2022)
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Qisen Zhou et al.
Summary: This study focuses on manipulating the surface properties of perovskites using the DMAI and TFMPHC synergistic system for improved performance of perovskite solar cells. The results demonstrate that the DMAI-TFMPHC system enhances the binding force with perovskite and improves passivation effect. Additionally, it facilitates charge extraction and reduces interfacial nonradiative recombination, leading to superior photovoltaic performance and stability.
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Changlei Wang et al.
Summary: A universal close-space annealing strategy is developed to improve the structural and optoelectronic quality of perovskite films, leading to the fabrication of efficient perovskite solar cells and all-perovskite tandem solar cells.
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Jiabang Chen et al.
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(2022)
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Junli Yin et al.
Summary: In this work, a new type of electron transporting materials (ETMs), PFBS-C12, is developed by polymerizing C60 fullerene with an aromantic linker unit. The PFBS-C12 can address the aggregation problem of PCBM in perovskite solar cells, leading to high efficiency and good device stability.
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Fengyou Wang et al.
Summary: The manipulation of grain boundaries is crucial for the performance and stability of solar cells based on perovskite materials. The traditional approach of using additives has limitations, while the introduction of a supramolecular bridging strategy with molecular binders shows great potential in improving environmental stability and power conversion efficiency of perovskite films.
CHEMICAL ENGINEERING JOURNAL
(2022)
Review
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Hongliang Liu et al.
Summary: This article briefly summarizes the strategies for improving the stability and photovoltaic efficiency of perovskite solar cells and presents future research directions and challenges based on references and analysis.
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Sheng Jiang et al.
Summary: In this study, solution-processed chromium multioxide was used as the charge transport layer in perovskite solar cells, resulting in increased efficiency and stability by reducing defects and adjusting the energy band gap.
Review
Materials Science, Multidisciplinary
Wei Zhou et al.
Summary: Perovskite is a promising material for next-generation solar cells due to its high efficiency, low cost, and convenient fabrication. However, the stability of perovskite solar cells remains a challenge for large-scale application. Various strategies have been developed to improve the stability of perovskite layers in solar cells, including composition regulation, crystallization control, and interface optimization.
SCIENCE CHINA-MATERIALS
(2022)
Article
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Haoyan Wang et al.
Summary: In this study, researchers strengthened the structure of perovskite solar cells (PSCs) using a compound called BDP and improved their stability. By modifying the crystallization process, passivating defects, forming a moisture-resistant layer, and inhibiting ion migration, BDP significantly enhanced the power conversion efficiency (PCE) of MAPbI3 solar cells and maintained relative stability under harsh environmental conditions.
CHEMICAL ENGINEERING JOURNAL
(2022)
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Yihui Wu et al.
Summary: The introduction of a new material, APC, has improved the performance of perovskite solar cells by enhancing the photoluminescence lifetime and carrier diffusion length, ultimately achieving high efficiency and stability.
ENERGY & ENVIRONMENTAL SCIENCE
(2022)
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Jungan Wang et al.
Summary: We propose an ion-pairing passivating agent that can convert the surface of perovskite solar cells into water-resistant compositions. This agent reduces defect density and improves photovoltage and efficiency. Additionally, it has waterproof features that significantly enhance the stability of the device.
Article
Materials Science, Multidisciplinary
Fu Zhang et al.
Summary: A programmable crystallization method was developed to obtain high-quality CsPbI2Br perovskite films, resulting in decent solar conversion efficiency in solar cells. This method demonstrates significant potential in fabricating high-efficiency inorganic perovskite solar cells.
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Erdi Akman et al.
Summary: Perovskite solar cells (PSCs) show great promise for photovoltaic applications due to their low-cost assembly, exceptional performance, and low-temperature solution processing. This study focuses on stabilizing the alpha-FAPbI(3) perovskite phase using PFBPA as a passivation agent, resulting in high-quality and stable PSCs with improved efficiency and long-term stability. The thin PFBPA passivation layer effectively protects the perovskite layer from moisture, maintaining over 90% of the original efficiency under different humidity levels after 600 hours.
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Jian Xiong et al.
Summary: By adding P3HT to the ETL of PCBM, the stability of perovskite solar cells under humid conditions can be enhanced without compromising the power conversion efficiency. A certain ratio of P3HT can improve the aggregation of PCBM, leading to improved moisture and water resistance of the ETL, maintaining device performance under various humidity levels and in water.
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Summary: The use of NaDEDTC as a processing agent has been shown to effectively improve the open-circuit voltage of methylammonium lead triiodide perovskite solar cells by reducing the crystallization rate and decreasing the nonradiative decay rate. This approach enhances the electroluminescence efficiency and, consequently, increases the open-circuit voltage of the cells.
Review
Chemistry, Multidisciplinary
Ehsan Rezaee et al.
Summary: Organic-inorganic halide perovskite solar cells have seen significant growth in power conversion efficiencies over the past decade, attributed to advances in device architecture and perovskite film fabrication. Solution-based thin film deposition techniques offer low cost and ease of manufacturing for PSCs. Solvents play a crucial role in thin film quality, impacting device performance and stability.
Article
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Alexander D. Taylor et al.
Summary: The authors report a general method for fabricating highly efficient perovskite solar cells using any antisolvent by manipulating the application rate. A detailed study of 14 different antisolvents revealed two key factors affecting film quality, leading to power conversion efficiencies exceeding 21% in devices made from a wide range of precursor chemistries.
NATURE COMMUNICATIONS
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Furkan H. Isikgor et al.
Summary: The use of molecules containing both electron-rich and electron-poor moieties, such as phenformin hydrochloride (PhenHCl), can improve stability and efficiency of perovskite/silicon tandem solar cells by satisfying the requirements of defect passivation and suppression of light-induced phase segregation.
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Yao Zhao et al.
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