4.8 Article

High Performance Ternary Solid Polymer Electrolytes Based on High Dielectric Poly(vinylidene fluoride) Copolymers for Solid State Lithium-Ion Batteries

Related references

Note: Only part of the references are listed.
Article Materials Science, Multidisciplinary

Three-Component Solid Polymer Electrolytes Based on Li-Ion Exchanged Microporous Silicates and an Ionic Liquid for Solid-State Batteries

Joao C. Barbosa et al.

Summary: This study developed a three-component solid polymer electrolyte with good performance. It used poly(vinylidene fluoride-co-hexafluoropropylene) as a binder, 1-butyl-3-methylimidazolium thiocyanate ionic liquid as an ionic conductive component, and different zeolite structures to improve the ionic conductivity and electrochemical stability.

ADVANCED ENGINEERING MATERIALS (2023)

Article Materials Science, Multidisciplinary

Optimisation of conductivity of PEO/PVDF-based solid polymer electrolytes in all-solid-state Li-ion batteries

Jun Li et al.

Summary: The composition of the PEO/polyvinylidene fluoride (PVDF)-based electrolytes was optimized to enhance ionic conductivity, resulting in a successful development of all-solid-state Li-ion batteries with improved performances in terms of discharge capacity, cycling performance, and rate capability.

MATERIALS TECHNOLOGY (2022)

Article Engineering, Environmental

Porous poly(vinylidene fluoride) supported three-dimensional poly (ethylene glycol) thin solid polymer electrolyte for flexible high temperature all-solid-state lithium metal batteries

Zhiyan Wang et al.

Summary: Solid polymer electrolytes (SPEs) have great potential for use in next-generation all-solid-state batteries due to their flexibility and safety. However, challenges such as low ionic conductivity, uncontrolled lithium dendrite growth, poor cyclic performance, and high temperature intolerance still need to be addressed. In this study, a flexible and dense PVDF@PEG SPE is developed, which exhibits high ionic conductivity and excellent electrochemical stability. The designed electrolyte shows promising performance in LiFePO4 pouch cells, delivering high discharge specific capacity and excellent cycle stability at both room temperature and high temperature conditions.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Physical

Accelerated ion conduction by co-grafting of poly(ethylene glycol) and nitrile-terminated ionic liquid on poly(arylene ether sulfone) for solid electrolyte membranes for lithium ion battery

Sugyeong Kim et al.

Summary: Solid polymeric electrolytes (SPE) fabricated from poly(arylene ether sulfone)-co-poly(ethylene glycol)/ nitrile terminated ionic liquid (PAES-co-PEG/ILCN) demonstrate high Li ion conductivity and stable cyclic performance in lithium ion batteries.

JOURNAL OF POWER SOURCES (2022)

Article Chemistry, Multidisciplinary

Transference Number in Polymer Electrolytes: Mind the Reference-Frame Gap

Yunqi Shao et al.

Summary: This study investigates the transport coefficients, particularly the transference number, of electrolyte solutions and their significance in the design of electrochemical energy storage devices. It is found that the neglect of the reference frame leads to discrepancies between experimental and simulation results, but a proper reference frame transformation can greatly improve the agreement. Furthermore, the study highlights the importance of ion mass and ion-ion correlation in the occurrence of negative transference numbers.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Article Chemistry, Physical

A Polymerized-Ionic-Liquid-Based Polymer Electrolyte with High Oxidative Stability for 4 and 5 V Class Solid-State Lithium Metal Batteries

Chengyin Fu et al.

Summary: The article reports a polymer electrolyte based on a polymerized ionic liquid and an ionic liquid plasticizer, which offers high ionic conductivity and oxidative stability. The electrolyte shows promising performance in lithium metal batteries, enabling stable cycling.

ADVANCED ENERGY MATERIALS (2022)

Article Physics, Condensed Matter

Improvement in ferroelectric properties of BaTiO3 film by mn/sr doping for non-volatile memory applications

Ajit Debnath et al.

Summary: This paper presents the fabrication of a metal-ferroelectric-semiconductor (MFS) structure for non-volatile storage using BaxSr1-xTiyMn1-yO3 (BSMT) as the ferroelectric layer. The performance of the fabricated structure is evaluated by measuring its memory window, leakage current, polarization retention, and dielectric loss. The composition and structure of the ferroelectric film are verified using SEM, XRD, AFM, and XPS. The optimized concentrations of Sr and Mn in BaxSr1-xTiyMn1-yO3 improve the ferroelectric results and enable their application in non-volatile memory.

MICRO AND NANOSTRUCTURES (2022)

Article Energy & Fuels

Optimized Printed Cathode Electrodes for High Performance Batteries

Renato Goncalves et al.

Summary: The study investigates the influence of ink preparation methods and the chemical structure of polymer binders on the performance of printed batteries. It is found that a limited amount of ethylene in the copolymer binder enhances discharge capacity, while ink preparation methods have a larger impact on cathode performance. Gradually adding active and conductive materials to the solution can result in higher cathode charge/discharge capacity compared to other dispersion methods. The optimized cathode performance is related to the improved dispersion of cathode components.

ENERGY TECHNOLOGY (2021)

Article Nanoscience & Nanotechnology

High-Performance Room Temperature Lithium-Ion Battery Solid Polymer Electrolytes Based on Poly(vinylidene fluoride-co-hexafluoropropylene) Combining Ionic Liquid and Zeolite

Joao C. Barbosa et al.

Summary: This study developed a three-component solid polymer electrolyte system based on PVDF-HFP, an ionic liquid, and clinoptilolite zeolite, showing improved room temperature ionic conductivity, thermal stability, and mechanical stability. Corresponding batteries exhibited outstanding room temperature performance with capacity retention of 76% after 50 cycles, representing a step forward in solid-state battery technology.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Chemistry, Multidisciplinary

Cellulose-Derived Flame-Retardant Solid Polymer Electrolyte for Lithium-Ion Batteries

Sayali B. Kale et al.

Summary: This study presents a thermally stable, flame-retardant, and flexible solid polymer electrolyte (PCIL) made from eco-friendly materials. The PCIL has high conductivity and thermal stability, showing improved transference number at higher temperatures, making it suitable for high-voltage lithium-ion batteries. Additionally, the synergic effect of polymeric and ionic liquid systems in the PCIL enhances charge carrier mobility, leading to easier ionic transport and improved storage capacity.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

Article Chemistry, Physical

Ionic liquid-based solid electrolytes (ionogels) for application in rechargeable lithium battery

Alok Kumar Tripathi

Summary: This article discusses the application of ionogels in lithium-ion rechargeable batteries and their advantages, as well as their impact on the performance of LIBs. It emphasizes the unique characteristics of IGs, demonstrating their potential value as solid electrolytes for next-generation rechargeable battery technologies.

MATERIALS TODAY ENERGY (2021)

Article Polymer Science

High dielectric constant poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) for capacitive pressure and bending sensors

N. Pereira et al.

Summary: Poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) samples were prepared by solvent casting with varying polymer concentration and solvent evaporation temperature. Different sample morphologies and physical-chemical properties were obtained under different processing conditions, while electroactive beta-phase content and degradation temperature remained independent of processing conditions. Pressure and bending capacitive sensors were developed with excellent response and high sensibility based on the high dielectric response of the samples.

POLYMER (2021)

Article Chemistry, Multidisciplinary

10 μm-Thick High-Strength Solid Polymer Electrolytes with Excellent Interface Compatibility for Flexible All-Solid-State Lithium-Metal Batteries

Zhiyan Wang et al.

Summary: This study presents an ultrathin solid polymer electrolyte with high ionic conductance and excellent mechanical properties, showing promising stability in various battery systems, particularly in all-solid-state lithium-metal batteries.

ADVANCED MATERIALS (2021)

Article Chemistry, Physical

Enhanced compatibility of a polymer-based electrolyte with Li-metal for stable and dendrite-free all-solid-state Li-metal batteries

Hasan Jamal et al.

Summary: Research on solid composite polymer electrolyte using YNa zeolite as a ceramic filler has shown significant improvement in the performance and stability of SS-LMBs by inhibiting lithium dendrite growth. The battery operates stably even at high current densities, with high Li-ion transference number and excellent ionic conductivity.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Chemistry, Multidisciplinary

A relaxor ferroelectric polymer with an ultrahigh dielectric constant largely promotes the dissociation of lithium salts to achieve high ionic conductivity

Yan-Fei Huang et al.

Summary: In this study, a novel approach using a relaxor ferroelectric (RFE) polymer of P(VDF-TrFE-CTFE) as the matrix of solid-state polymer electrolytes (SPEs) significantly increased the ionic conductivity in solid-state lithium metal batteries. The high dielectric constant of P(VDF-TrFE-CTFE) enabled enhanced solvation ability towards lithium ions and promoted dissociation, resulting in improved charge carrier mobility. The hybrid electrolytes with larger dielectric constant showed higher ionic conductivity, and tight interfaces of P(VDF-TrFE-CTFE) based SPEs ensured stable interfacial resistance during cycling, leading to stable cycling performance in LiFePO4/Li and LiNi0.8Co0.1Mo0.1O2/Li batteries at 25 degrees C. This work suggests a new research direction to construct SPEs with high ionic conductivity by increasing the dielectric constant of polymers.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Review Materials Science, Multidisciplinary

Metal-organic frameworks and zeolite materials as active fillers for lithium-ion battery solid polymer electrolytes

Joao C. Barbosa et al.

Summary: Efforts to decarbonize economies by focusing on renewable energies must also develop more efficient and environmentally friendly energy storage systems. All solid-state batteries show promise due to their higher energy density and improved safety, with development of solid electrolytes key to their performance. The three-component approach for composite solid polymer electrolytes using microporous materials like metal-organic frameworks and zeolites offers advantages for improving ionic conductivity and interfacial compatibility.

MATERIALS ADVANCES (2021)

Article Chemistry, Physical

Enhancement of the ionic conductivity of a composite polymer electrolyte via surface functionalization of SSZ-13 zeolite for all-solid-state Li-metal batteries

Hasan Jamal et al.

Summary: The article discusses a superior CPE (MZ-CPE) synthesized using modified SSZ-13 (M-SSZ-13) as a ceramic filler, which significantly enhances the performance of Li-metal batteries. The composite polymer electrolyte shows potential as an alternative for solid-state Li-metal batteries.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Materials Science, Multidisciplinary

Energy harvesting from a thin polymeric film based on PVDF-HFP and PMMA blend

Kinyas Polat

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING (2020)

Article Green & Sustainable Science & Technology

Ionic liquid based Fluoropolymer solid electrolytes for Lithium-ion batteries

J. P. Serra et al.

SUSTAINABLE MATERIALS AND TECHNOLOGIES (2020)

Article Chemistry, Multidisciplinary

Composite Solid Polymer Electrolyte with Garnet Nanosheets in Poly(ethylene oxide)

Shufeng Song et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Review Energy & Fuels

Advances and issues in developing salt-concentrated battery electrolytes

Yuki Yamada et al.

NATURE ENERGY (2019)

Review Chemistry, Multidisciplinary

Review on Polymer-Based Composite Electrolytes for Lithium Batteries

Penghui Yao et al.

FRONTIERS IN CHEMISTRY (2019)

Article Materials Science, Multidisciplinary

Ionic-Liquid-Based Electroactive Polymer Composites for Muscle Tissue Engineering

R. M. Meira et al.

ACS APPLIED POLYMER MATERIALS (2019)

Article Biochemical Research Methods

Electroactive poly(vinylidene fluoride)-based structures for advanced applications

Clarisse Ribeiro et al.

NATURE PROTOCOLS (2018)

Article Nanoscience & Nanotechnology

Electrochemical Characterization of Single Lithium-Ion Conducting Polymer Electrolytes Based on sp(3) Boron and Poly(ethylene glycol) Bridges

Gregorio Guzman-Gonzalez et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

Article Chemistry, Multidisciplinary

A novel ionic liquid polymer electrolyte for quasi-solid state lithium air batteries

Junjie Bai et al.

RSC ADVANCES (2017)

Review Chemistry, Physical

Progress in electrolytes for rechargeable Li-based batteries and beyond

Qi Li et al.

GREEN ENERGY & ENVIRONMENT (2016)

Article Chemistry, Physical

Prospects and Limits of Energy Storage in Batteries

K. M. Abraham

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2015)

Article Chemistry, Physical

Ionic liquids-in-salt - a promising electrolyte concept for high-temperature lithium batteries?

Maciej J. Marczewski et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2014)

Review Polymer Science

Electroactive phases of poly(vinylidene fluoride): Determination, processing and applications

P. Martins et al.

PROGRESS IN POLYMER SCIENCE (2014)

Article Materials Science, Multidisciplinary

Influence of zeolite structure and chemistry on the electrical response and crystallization phase of poly(vinylidene fluoride)

A. C. Lopes et al.

JOURNAL OF MATERIALS SCIENCE (2013)

Article Engineering, Environmental

A review of hazards associated with primary lithium and lithium-ion batteries

Diego Lisbona et al.

PROCESS SAFETY AND ENVIRONMENTAL PROTECTION (2011)

Article Chemistry, Analytical

Electrochemical Impedance Spectroscopy

Byoung-Yong Chang et al.

ANNUAL REVIEW OF ANALYTICAL CHEMISTRY, VOL 3 (2010)

Review Chemistry, Physical

A review of conduction phenomena in Li-ion batteries

Myounggu Park et al.

JOURNAL OF POWER SOURCES (2010)

Article Materials Science, Ceramics

Microscopic origin of the high-strain mechanical response of poled and non-poled poly(vinylidene fluoride) in the β-phase

C. M. Costa et al.

JOURNAL OF NON-CRYSTALLINE SOLIDS (2008)

Article Chemistry, Multidisciplinary

Zeolites upon heating: Factors governing their thermal stability and structural changes

Giuseppe Cruciani

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2006)

Article Engineering, Manufacturing

The effect of interfacial interactions on the mechanical properties of polypropylene/natural zeolite composites

D Metin et al.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2004)