Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 98, Pages 17463-17466Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc07578e
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Funding
- BASF SE (Ludwigshafen, Germany)
- Center for Gas Separations Relevant to Clean Energy Technologies
- Energy Frontier Research Center (EFRC) - U.S. Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences [DE-SC0001015]
- Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-AC02-05CH11231]
- Office of Science, Office of Basic Energy Sciences, of the DOE [DE-AC02-05CH11231]
- Israel Ministry of Science and Technology
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Metal-organic frameworks (MOFs) based purely on sodium are rare, typically due to large numbers of coordinating solvent ligands. We designed a tetratopic aspartate-based linker with flexible carboxylate groups to enhance framework stability. We report two new air-stable sodium MOFs, MOF-705 and MOF-706, comprising 2D sodium oxide sheets.
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