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Design of Amine-Containing Nanoporous Materials for Postcombustion CO2 Capture from Engineering Perspectives

Journal

ACCOUNTS OF CHEMICAL RESEARCH
Volume 56, Issue 21, Pages 2887-2897

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.accounts.3c00326

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Carbon dioxide (CO2) capture and storage (CCS) is crucial for enabling the use of fossil fuels while addressing environmental concerns. Among the CO2 capture technologies, postcombustion CO2 capture using solid adsorbents has gained attention due to its noncorrosive nature and low energy demand. However, the design of efficient and stable amine-containing adsorbents for postcombustion CO2 capture is a complex challenge. This article focuses on the development of energy-efficient adsorbents for CO2 capture via temperature swing adsorption (TSA). The key challenges include improving CO2 adsorption capacity, suppressing coadsorption of water, and enhancing the stability of the adsorbents. By combining macroporous silica hosts, alkyl-epoxide-functionalized poly(ethylenimine) (PEI), and phosphate-based oxidative stabilizers, the authors have synthesized adsorbents that exhibit low energy demands and high thermochemical stability. The discussions provide important insights for the practical design of adsorbents for CO2 capture.
Carbon dioxide (CO2) capture and storage (CCS) is a means to enable the continued use of fossil fuels in the short term. In particular, postcombustion CO2 capture has attracted considerable attention because it can be retrofitted into existing power plants and industrial plants. Among various CO2 capture technologies, the absorption of CO2 using aqueous amines has been industrially employed for decades. However, such amine scrubbing technologies have inherent limitations of environmental and health concerns due to volatile amine loss, corrosion, and high energy demands for regeneration. To overcome these limitations, CO2 adsorption using solid adsorbents has emerged as a promising alternative due to its noncorrosiveness and low energy demand. Various amine-containing adsorbents have been synthesized and investigated for postcombustion CO2 capture. These materials are prepared by physically impregnating low-vapor-pressure amine polymers or by chemically grafting amines onto nanoporous materials. A wide variety of amine guests and nanoporous hosts (e.g., SiO2, Al2O3, zeolites, MOFs, and polymers) have been combined to develop advanced CO2 adsorbents.The design of CO2 adsorbents is a multifaceted puzzle that must ultimately consider integration with large-scale CO2 capture processes. Various engineering aspects need to be carefully considered. Unfortunately, a significant proportion of previous studies has primarily focused on the use of novel materials for improving the CO2 adsorption capacity. In this Account, we describe key challenges and solutions to develop energy-efficient and stable amine-containing adsorbents for postcombustion CO2 capture via temperature swing adsorption (TSA). We found that a high CO2 working capacity, often overemphasized in the literature, does not necessarily guarantee a low energy demand for CO2 capture. Suppressing coadsorption of H2O during the CO2 adsorption in humid flue gas is also a significant factor. Amine-containing adsorbents can be degraded through various pathways, including hydrothermal degradation of nanoporous hosts and chemical degradation of amine guests via urea formation and oxidation. To inhibit such degradation pathways, it is extremely important to properly design the nanoporous structures of the hosts and the molecular structures of the amine guests. By combining macroporous silica hosts, poly(ethylenimine) (PEI) functionalized with various alkyl epoxides, and phosphate-based oxidative stabilizers, we could synthesize adsorbents exhibiting low energy demands for CO2 capture and unprecedentedly high thermochemical stability under TSA conditions. The macroporous silica host synthesized by assembling fumed silica particles via spray-drying exhibited high hydrothermal stability and enabled uniform distribution of bulky amine polymers within its pores. The functionalization of PEI with alkyl epoxides converted its primary amines into hindered secondary amines, leading to a significant reduction in energy demand for TSA cycles and a remarkable improvement in long-term stabilities. The oxidative stability of amines could be drastically improved by adding phosphate metal-binding reagents, which can poison ppm-level metal impurities that catalyze amine oxidation. The present discussions will provide important insights into designing practical adsorbents for CO2 capture from engineering perspectives.

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