Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 72, Pages 13822-13825Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc04987c
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Funding
- Research Grant under the SA/China Agreement on Cooperation in Science and Technology
- Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Soochow University and the Key Laboratory of Organic Synthesis of Jiangsu Province
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A Cu-catalyzed direct cyanation of terminal alkynes was reported with broad substrate generality in moderate to high yield, and AMBN (azobisisoamylonitrile)/AIBN (azobisisobutyronitrile) were used as less toxic and effective cyanating sources in open air. Interestingly, addition products were selectively achieved as the major product under the same conditions in argon.
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