Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 25, Pages 5448-5451Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc10282g
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Funding
- 3 M Non-Tenured Faculty Grant
- NSF CMMI Scalable Nanomanufacturing Award [1246800]
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For the purpose of realizing inherently safe high-power Li-ion batteries, a model Li4Ti5O12/LiFePO4 rechargeable battery is investigated using the thermally responsive polymer, poly(benzyl methacrylate), in an ionic liquid. At high temperature, battery operation is inhibited as a result of increased internal resistance caused by polymer and ionic liquid phase separation. Li-ion concentration is shown to affect the phase transition temperature and the extent to which batteries are deactivated.
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