4.7 Article

Thermally-activated recombination in one component of (CH3NH3) PbI3/TiO2 observed by photocurrent spectroscopy

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 34, Pages 7309-7312

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00751h

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Funding

  1. American Chemical Society Division of Inorganic Chemistry Exxon-Mobil Solid State Faculty Fellowship
  2. National Science Foundation (NSF) Division of Materials Research (DMR) CAREER [1253562]
  3. Division Of Materials Research
  4. Direct For Mathematical & Physical Scien [1253562] Funding Source: National Science Foundation

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Photocurrent measurements on devices containing perovskite (CH3NH3)PbI3 show two distinct spectral responses when deposited in a mesoporous oxide matrix, compared with one response for planar perovskite alone. With a TiO2 matrix, the shorter wavelength response has an inverted temperature response with increasing performance on cooling.

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