Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 82, Pages 15173-15175Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc05439g
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Funding
- Alexander von Humboldt Foundation
- Australian Research Council [DP130100152]
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DFT investigations of the redox transmetallation reaction of the diorganomercurial (Hg(C6F5)(2)) with Yb metal, yielding Yb(C6F5)(2), allowed us to define a very low energy reaction mechanism. This involves formation of a metal-metal bonded, formally Yb-I-Hg-I, intermediate valence complex, (C6F5)Yb-Hg(C6F5). The subsequent reactivity of the divalent ytterbium complex with pyrazole was also computationally investigated, indicating that r-bond metathesis occurs at divalent ytterbium.
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