Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 84, Pages 15402-15405Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc05993c
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Funding
- DOE [DE-FG02-92ER14273]
- NIGMS [1 P30 GM110758-01]
- NSF [CHE-1229234, CRIF 1048367]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1229234] Funding Source: National Science Foundation
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Dinitrogen complexes of the type Tp(R,R)Cr-N-2-CrTp(R,R) are not the most labile precursors for Cr(I) chemistry, as they are sterically protected from obligatory associative ligand substitution. A mononuclear alkyne complex - Tp(tBu,Me)Cr(eta(2)-C-2(SiMe3)(2)) - proved to be much more reactive.
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