4.7 Article

Mechanism-based design of labile precursors for chromium(I) chemistry

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 84, Pages 15402-15405

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc05993c

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Funding

  1. DOE [DE-FG02-92ER14273]
  2. NIGMS [1 P30 GM110758-01]
  3. NSF [CHE-1229234, CRIF 1048367]
  4. Division Of Chemistry
  5. Direct For Mathematical & Physical Scien [1229234] Funding Source: National Science Foundation

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Dinitrogen complexes of the type Tp(R,R)Cr-N-2-CrTp(R,R) are not the most labile precursors for Cr(I) chemistry, as they are sterically protected from obligatory associative ligand substitution. A mononuclear alkyne complex - Tp(tBu,Me)Cr(eta(2)-C-2(SiMe3)(2)) - proved to be much more reactive.

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