Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 62, Pages 12384-12387Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc04606h
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Funding
- Spanish Ministerio de Ciencia e Innovacion and European Community Funds (FEDER) [CSD2007-00006]
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A gold(I)-catalysed hydroaminative/arylative cascade for the efficient synthesis of a variety of indole-fused skeletons has been developed. Factors controlling the catalyst loading required in these transformations involving 1,3-unsubstituted indole intermediates have been revealed, allowing isolation of an unprecedented 1,3-dimetallated 3H-indole gold complex characterized by X-ray diffraction.
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