4.7 Article

Continuous synthesis of methanol: heterogeneous hydrogenation of ethylene carbonate over Cu/HMS catalysts in a fixed bed reactor system

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 72, Pages 13776-13778

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc05030h

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Funding

  1. Major State Basic Resource Development Program [2012CB224804]
  2. NSFC [21373054, 21173052]
  3. Natural Science Foundation of Shanghai Science and Technology Committee [08DZ2270500]

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Continuous fixed-bed catalytic hydrogenation of ethylene carbonate (EC) to methanol and ethylene glycol (EG), an emerging synthetic process of methanol via indirect conversion of CO2, was successfully performed over Cu/HMS catalysts prepared by the ammonia evaporation (AE) method. The catalysts possessed superb performance with a conversion of 100% and a selectivity to methanol of 74%.

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