4.7 Article

Self-organization of star-shaped columnar liquid crystals with a coaxial nanophase segregation revealed by a combined experimental and simulation approach

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 10, Pages 1811-1814

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc08602c

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Funding

  1. MINECO-FEDER funds [MAT2012-38538-CO3-01, CTQ2012-35692]
  2. Gobierno de Aragon-FSE (E04 research group)

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Fully consistent X-ray data and molecular dynamics simulations on new star-shaped liquid crystals yield two nanosegregated architectures with a coaxial stacking of two functional discotic units: tris(triazolyl)triazine and triphenylene. Analysis of lattice order along the principal axes reveals preferential staggered arrangement of the stacked molecules in the columnar assembly.

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