Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 35, Pages 7486-7488Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00809c
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Funding
- Mid-Career Researcher Program - National Research Foundation (NRF) of Korea [2014R1A2A1A10051083]
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A triazole-bearing picket fence type nickel porphyrin (1) has been synthesized as a host compound for anion binding. Among the various anionic species examined, cyanide was the only one that affected a spectral change of 1. Moreover, 1 exhibited strong homotropic positive allosterism against cyanide binding due to an electronic effect as well as multiple hydrogen bonds formed between cyanide and the triazole groups.
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