Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 43, Pages 9042-9045Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc02226f
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Funding
- Otago Medical Research Foundation [LA307]
- Department of Chemistry, University of Otago
- University of Otago
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A metallosupramolecular [Pd2L4](4+) cage can be cleanly converted into a [Pd2L2Cl4] metallo-macrocycle upon addition of chloride ions. The process is reversible, treatment of the [Pd2L2Cl4] macrocycle with silver(I) ions regenerates the [Pd2L4](4+) cage. Additionally, it is shown that guest molecules could be released on chloride triggered cage dis-assembly and taken up anew on re-assembly.
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