Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 35, Pages 7532-7535Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00379b
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Funding
- NSF CAREER award [CHE-1056657]
- Research Corporation for Scientific Advancement
- Alfred P. Sloan Foundation
- Camille Dreyfus Teacher-Scholar Award from the Camille and Henry Dreyfus Foundation
- Department of Defense, Air Force Office of Scientific Research, National Defense Science and Engineering Graduate (NDSEG) Fellowship
- NSF MRSEC program [DMR-1120296]
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We examine the growth rates, activation energies, and hydrolytic stability of multiple 2D boronate ester covalent organic frameworks by turbidity measurements, observing a 200-fold range in stability. The rate-determining step in boronate ester 2D COF growth is not in-solution condensation, but rather interlayer polymer stacking through a nucleation-elongation process.
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