4.7 Article

A four-unit [c2]daisy chain connected by hydrogen bonds

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 83, Pages 15253-15256

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc07130e

Keywords

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Funding

  1. NSFC [21102038]
  2. HSDGGJS [HSDGGJS201406]
  3. National Basic Research Programof China (973 Program) [2014CB560713]
  4. China Postdoctoral Science Foundation [2015M572110, 2014063]

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A mono-adenine-functionalized pillar[5]arene and a guest including uracil were prepared. They formed a novel four-unit [c2]daisy chain both in the solid state and in a chloroform solution. As far as we know, this [c2]daisy chain is the first one without a covalently bound linear thread. This unique assembly behavior is mainly induced by hydrogen-bond interactions between A and U in the A-U base pairs.

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