4.7 Article

Synthesis of cyclic diborenes with unprecedented cis-configuration

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 88, Pages 15917-15920

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc07103h

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Funding

  1. Deutsche Forschungsgemeinschaft

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The first examples of cis-configured diborenes - and the first cyclic diborenes - are isolated by taking advantage of stabilisation by chelating diphosphine ligands. The diborenes are prepared by a convenient one-pot reductive procedure that circumvents the need for a pre-formed base-adduct of the boron-containing precursor.

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