Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 47, Pages 9690-9693Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc03182f
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Temperature dependent reaction products are observed when borohydride is present in aqueous solutions containing Ir3+. At temperatures of 40 degrees C and above, metallic iridium is formed while under ambient conditions of 25 degrees C, borohydride results in an alkaline environment that helps in hydrolyzing the precursor to form IrO2. The Ir foams and IrO2 are subsequently used to study their catalytic properties.
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