4.7 Article

One-pot in situ redox synthesis of hexacyanoferrate/conductive polymer hybrids as lithium-ion battery cathodes

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 71, Pages 13674-13677

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc04694g

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Funding

  1. Institute of Bioengineering and Nanotechnology (Biomedical Research Council, Agency of Science Technology and Research, Singapore)

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An efficient and adaptable method is demonstrated for the synthesis of lithium hexacyanoferrate/conductive polymer hybrids for Li-ion battery cathodes. The hybrids were synthesized via a one-pot method, involving a redox-coupled reaction between pyrrole monomers and the Li3Fe(CN)(6) precursor. The hybrids showed much better cyclability relative to reported Prussian Blue (PB) analogs.

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