Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 60, Pages 11994-11996Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc03027g
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Funding
- Department of Energy [DE-SC0004888]
- National Science Foundation Graduate Research Fellowship Program (NSF-GRFP)
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The application of a core-shell architecture allows the formation of a polymer-coated metal-organic framework (MOF) maintaining high surface area (2289-2857 m(2) g(-1)). The growth of a MOF shell from a MOF core was used to spatially localize initiators by post-synthetic modification. The confinement of initiators ensures that polymerization is restricted to the outer shell of the MOF.
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