Journal
INORGANICS
Volume 11, Issue 2, Pages -Publisher
MDPI
DOI: 10.3390/inorganics11020082
Keywords
tungsten; metal-oxide composites; hot isostatic pressing
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This study explores the consolidation process of W-CeO2 metal matrix composites with high CeO2 concentrations. The results show that decreasing the CeO2 concentration can increase the density and Vickers hardness of the composites. The oxidation state of CeO2 is a combination of Ce3+ and Ce4+, which is believed to contribute to the porosity of the composites. The hardness of the metal-oxide composite can be improved more than 2.5 times compared to pure W processed by the same route. This work provides processing guidelines for further consolidation of oxide-doped W composites.
Metal-oxide composites are commonly used in high temperature environments for their thermal stability and high melting points. Commonly employed with refractory oxides or carbides such as ZrC and HfC, these materials may be improved with the use of a low density, high melting point ceramic such as CeO2. In this work, the consolidation of W-CeO2 metal matrix composites in the high CeO2 concentration regime is explored. The CeO2 concentrations of 50, 33, and 25 wt.%, the CeO2 particle size from nanometer to micrometer, and various hot isostatic pressing temperatures are investigated. Decreasing the CeO2 concentration is observed to increase the composite density and increase the Vickers hardness. The CeO2 oxidation state is observed to be a combination of Ce3+ and Ce4+, which is hypothesized to contribute to the porosity of the composites. The hardness of the metal-oxide composite can be improved more than 2.5 times compared to pure W processed by the same route. This work offers processing guidelines for further consolation of oxide-doped W composites.
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