4.7 Article

Enzymatic synthesis and post-functionalization of two-dimensional crystalline cellulose oligomers with surface-reactive groups

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 63, Pages 12525-12528

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc04378f

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Funding

  1. Funding Program for Next Generation World-Leading Researchers (NEXT Program)
  2. Japan Society for the Promotion of Science [26288056, 26620174]
  3. JX Nippon Oil Energy
  4. Grants-in-Aid for Scientific Research [26620174, 26288056] Funding Source: KAKEN

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Two-dimensional (2D) nanomaterials have gained considerable attention due to their unique structural and physicochemical properties. Herein, we synthesized 2D crystalline cellulose oligomers with surface-reactive azide groups through enzymatic reactions and covalently post-functionalized them with 1-ethynyl pyrene through copper(I)-catalyzed Huisgen cycloaddition reactions.

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