Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 52, Pages 10536-10538Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc03215f
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Funding
- National Science Foundation [CHE RUI 1401686]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1401686] Funding Source: National Science Foundation
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The preparation of rhenium based octahedral clusters containing N-heterocyclic carbenes is described. These represent the first examples of [M-6(mu(3)-Q)(8)](n+) or [M-6(mu(3)-X)(8)](n+) clusters to contain a carbene ligand of any type (NHC, Fischer or Schrock). Surprisingly, the NHC ligands attenuate their luminescent properties.
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