Journal
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Volume 79, Issue -, Pages 508-+Publisher
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S2056989023003602
Keywords
crystal structure; hydrogen bonds; pi-pi stacking interaction; chain structure; hydrazone
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In the polymeric compound, Na+ cations are linked into a parallel chain by sharing water molecules. Each Na+ cation in the chain is bonded to a terminal water molecule and an SO3- group of the sulfonate anion. Hydrogen bonds and pi-pi interactions connect these chains into a three-dimensional network.
In the polymeric title compound, {[Na(C10H9N4O4S)(H2O)(3)]center dot 2H(2)O}(n), sixfold coordinated Na+ cations are linked into a chain parallel to [010] by sharing common water molecules. Next to the four bridging water molecules, each Na+ cation of the chain is bonded to the O atom of a terminal water molecule and an O atom of the SO3- group of the sulfonate anion. Classical O-H center dot center dot center dot O, O-H center dot center dot center dot N and N-H center dot center dot center dot O hydrogen bonds and additional pi-pi interactions connect these chains into a three-dimensional network.
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