Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 77, Pages 14513-14515Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc05368d
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- Deutsche Forschungsgemeinschaft
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By a ring expansion reaction of boroles with nitrones a straightforward route to eight-membered O,N,B-containing ring systems was developed, which present a new structural motif in heterocyclic chemistry. Formally, these compounds can be considered as BN-analogues of eight-membered ring ethers containing three double bonds. The X-ray crystallographic data of a series of these oxazaborocine derivatives show that they adopt a boat conformation in the solid state.
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