4.7 Article

A supramolecular keypad lock

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 13, Pages 2698-2701

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc09336d

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Funding

  1. Spanish MINECO [CTQ2011-28390]
  2. FEDER
  3. COST Action [CM1005]
  4. Portuguese FCT [REEQ/717/QUI/2005, SFRH/BD/81628/2011]

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The reversible photoswitching between an anthracene derivative and its [4+4] dimer, using the template effect of the CB8 macrocycle, was demonstrated. This example of supramolecular chemistry in water was harnessed to demonstrate the operation of a keypad lock device that is driven by means of light and chemicals as inputs.

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