Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 52, Pages 10554-10557Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc03203b
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Funding
- National Natural Science Foundation of China [21432006, 21321061, 21172151]
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The catalytic asymmetric Michael addition/desymmetrization reaction of N-(2-t-butylphenyl)maleimides with unprotected 3-substituted-2-oxindoles was successfully realized using a chiral N,N'-dioxide-Sc(III) complex, leading to succinimides with two kinds of stereogenic elements-atom chirality and axial chirality-in up to 99% yield, 99% ee and >19 : 1 d.r.
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