4.7 Article

Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 1, Pages 85-88

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc05727a

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Funding

  1. Army Research Office [W911NF-13-1-0229]
  2. National Defense Science & Engineering Graduate Fellowship Program
  3. Institute for Sustainability and Energy at Northwestern University

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Herein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.

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