Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 90, Pages 16194-16196Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc05675f
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Funding
- French Agence Nationale de la Recherche [ANR-08-CP2D-13-01, ANR-13-CDII-0007]
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Colloidal suspensions of monodisperse platinum nanoparticles of 2 nm diameter have been used to catalyze the hydrosilylation of 1-octene with a polymethylhydrosiloxane. The nanoparticles were found to be as efficient as Karstedt's complex, showing that colloid formation from homogeneous species during hydrosilylation reactions is not necessarily a deactivation pathway. These results also reactivated the debate on whether Karstedt's complex was truly homogeneous or colloidal during catalysis.
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