Journal
MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS
Volume 62, Issue -, Pages 605-613Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.msec.2016.02.004
Keywords
Magnetic mesoporous carbon; Lopid; Beta-cyclodextrin; Pericarpium granati; Human serum; Pharmaceutical wastewaters
Categories
Funding
- National Natural Science Foundations of China [21275098, 81173024, 81227802]
Ask authors/readers for more resources
Functionalized magnetic carbonaceous nanomaterials, which are important materials with many practical and research applications in biomedical, pharmaceutical and biological fields, have recently attracted much attention. In this study, a magnetic mesoporous carbon coated with beta-cyclodextrin (MMC@beta-CD) was synthesized for the first time from natural pericarpium granati (PG). The as-obtained MMC@beta-CD has high surface areas (203 m(2) g(-1)), large pore volumes (0.16 cm(3) g(-1)), relatively broad mesoporous sizes (6.8 nm) and a high saturation magnetization of 262 emu g(-1), which is sufficient for magnetic separation by an external magnetic field. The MMC@beta-CD was used as an innovative adsorbent for magnetic solid-phase extraction of lopid via host-guest interaction prior to spectrofluorometric analysis. The proposed method was successfully applied to analyze lopid in human serum and pharmaceutical wastewater samples with recoveries in the range of 85.0-103.5% for the spiked samples. Overall, this work not only provides an inexpensive and eco-friendly method to fabricate MMC@beta-CD (or MMC) from PG, but also develops a highly selective approach for capture of lopid in biological samples and environmental substances. (C) 2016 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available